Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification

The aim of this study is to evaluate the applicability of the catalytic activity (CA) of the Fe3O4 magnetic system in the adsorption/degradation of methylene blue and esterification. The thermal decomposition method allowed the preparation of Fe3O4 nanoparticles. The crystallites of the Fe3O4 struct...

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Autores:
Torrente Rocha, Juan Jose
Aragón-Muriel, Alberto
Hernández Quintero, Hernando Antonio
Castro Velásquez, Juan Camilo
Salazar-Camacho, Natalia Andrea
Pérez Alcázar, German Antonio
Tabares, Jesús Anselmo
Tipo de recurso:
Article of investigation
Fecha de publicación:
2022
Institución:
Universidad de Ibagué
Repositorio:
Repositorio Universidad de Ibagué
Idioma:
eng
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oai:repositorio.unibague.edu.co:20.500.12313/5541
Acceso en línea:
https://hdl.handle.net/20.500.12313/5541
Palabra clave:
Nanopartículas de FeO - Caracterización
Actividad catalítica
Nanopartículas de Fe₃O₄
Azul de metileno
Espectroscopía Mössbauer
Catalytic activity
Esterification
Fe3O4 nanoparticles
Methylene blue
Mössbauer spectroscopy
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openAccess
License
© 2022 by the authors.
id UNIBAGUE2_9000d35e4aace5d17cceb091df288bdf
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network_name_str Repositorio Universidad de Ibagué
repository_id_str
dc.title.eng.fl_str_mv Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
title Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
spellingShingle Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
Nanopartículas de FeO - Caracterización
Actividad catalítica
Nanopartículas de Fe₃O₄
Azul de metileno
Espectroscopía Mössbauer
Catalytic activity
Esterification
Fe3O4 nanoparticles
Methylene blue
Mössbauer spectroscopy
title_short Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
title_full Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
title_fullStr Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
title_full_unstemmed Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
title_sort Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification
dc.creator.fl_str_mv Torrente Rocha, Juan Jose
Aragón-Muriel, Alberto
Hernández Quintero, Hernando Antonio
Castro Velásquez, Juan Camilo
Salazar-Camacho, Natalia Andrea
Pérez Alcázar, German Antonio
Tabares, Jesús Anselmo
dc.contributor.author.none.fl_str_mv Torrente Rocha, Juan Jose
Aragón-Muriel, Alberto
Hernández Quintero, Hernando Antonio
Castro Velásquez, Juan Camilo
Salazar-Camacho, Natalia Andrea
Pérez Alcázar, German Antonio
Tabares, Jesús Anselmo
dc.subject.armarc.none.fl_str_mv Nanopartículas de FeO - Caracterización
Actividad catalítica
Nanopartículas de Fe₃O₄
Azul de metileno
Espectroscopía Mössbauer
topic Nanopartículas de FeO - Caracterización
Actividad catalítica
Nanopartículas de Fe₃O₄
Azul de metileno
Espectroscopía Mössbauer
Catalytic activity
Esterification
Fe3O4 nanoparticles
Methylene blue
Mössbauer spectroscopy
dc.subject.proposal.eng.fl_str_mv Catalytic activity
Esterification
Fe3O4 nanoparticles
Methylene blue
Mössbauer spectroscopy
description The aim of this study is to evaluate the applicability of the catalytic activity (CA) of the Fe3O4 magnetic system in the adsorption/degradation of methylene blue and esterification. The thermal decomposition method allowed the preparation of Fe3O4 nanoparticles. The crystallites of the Fe3O4 structural phase present an acicular form confirmed by X-ray diffraction. Transmission electron microscopy results identified the acicular shape and agglomeration of the nanoparticles. Mössbauer spectroscopy showed that the spectrum is composed of five components at room temperature, a hyperfine magnetic field distribution (HMFD), two sextets, a doublet, and a singlet. The presence of the HMFD means that a particle size distribution is present. Fluorescence spectroscopy studied the CA of the nanoparticles with methylene blue and found adsorption/degradation properties of the dye. The catalytic activity of the nanoparticles was evaluated in the esterification reaction by comparing the results in the presence and absence of catalyst for the reaction with isobutanol and octanol, where it is observed that the selectivity for the products MIBP and MNOP is favored in the first three hours of reaction.
publishDate 2022
dc.date.issued.none.fl_str_mv 2022-12
dc.date.accessioned.none.fl_str_mv 2025-08-25T16:44:52Z
dc.date.available.none.fl_str_mv 2025-08-25T16:44:52Z
dc.type.none.fl_str_mv Artículo de revista
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dc.identifier.citation.none.fl_str_mv Hernandez, J., Aragón-Muriel, A., Corrales, W., Castro, J., Salazar-Camacho, N., Pérez, A. y Tabares, J. (2022). Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification. Molecules, 27(4), 8976. DOI: 10.3390/molecules27248976
dc.identifier.doi.none.fl_str_mv 10.3390/molecules27248976
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/20.500.12313/5541
identifier_str_mv Hernandez, J., Aragón-Muriel, A., Corrales, W., Castro, J., Salazar-Camacho, N., Pérez, A. y Tabares, J. (2022). Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification. Molecules, 27(4), 8976. DOI: 10.3390/molecules27248976
10.3390/molecules27248976
url https://hdl.handle.net/20.500.12313/5541
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.citationissue.none.fl_str_mv 4
dc.relation.citationstartpage.none.fl_str_mv 8976
dc.relation.citationvolume.none.fl_str_mv 27
dc.relation.ispartofjournal.none.fl_str_mv Molecules
dc.relation.references.none.fl_str_mv Mohajerani, A.; Burnett, L.; Smith, J.V.; Kurmus, H.; Milas, J.; Arulrajah, A.; Horpibulsuk, S.; Kadir, A.A. Nanoparticles in Construction Materials and Other Applications, and Implications of Nanoparticle Use. Materials 2019, 12, 3052. [
Ali, A.; Zafar, H.; Zia, M.; ul Haq, I.; Phull, A.R.; Ali, J.S.; Hussain, A. Synthesis, Characterization, Applications, and Challenges of Iron Oxide Nanoparticles. Nanotechnol. Sci. Appl. 2016, 9, 49–67.
Andra, S.; Balu, S.K.; Jeevanandham, J.; Muthalagu, M.; Vidyavathy, M.; Chan, Y.S.; Danquah, M.K. Phytosynthesized Metal Oxide Nanoparticles for Pharmaceutical Applications. Naunyn Schmiedebergs Arch. Pharmacol. 2019, 392, 755–771.
Radoń, A.; Łoński, Y.; Warski, T.; Babilas, R.; Tański, T.; Dudziak, M.; Łukowiec, D. Catalytic Activity of Non-Spherical Shaped Magnetite Nanoparticles in Degradation of Sudan I, Rhodamine B and Methylene Blue Dyes. Appl. Surf. Sci. 2019, 487, 1018–1025.
Schwaminger, S.P.; Bauer, D.; Fraga-García, P.; Wagner, F.E.; Berensmeier, S. Oxidation of Magnetite Nanoparticles: Impact on Surface and Crystal Properties. CrystEngComm 2017, 19, 246–255.
Bhole, R.; Gonsalves, D.; Murugesan, G.; Narasimhan, M.K.; Srinivasan, N.R.; Dave, N.; Varadavenkatesan, T.; Vinayagam, R.; Govarthanan, M.; Selvaraj, R. Superparamagnetic Spherical Magnetite Nanoparticles: Synthesis, Characterization and Catalytic Potential. Appl. Nanosci. 2022, 12, 1–12.
Giraldo, L.; Erto, A.; Moreno-Piraján, J.C. Magnetite Nanoparticles for Removal of Heavy Metals from Aqueous Solutions: Synthesis and Characterization. Adsorption 2013, 19, 465–475.
Fato, F.P.; Li, D.W.; Zhao, L.J.; Qiu, K.; Long, Y.T. Simultaneous Removal of Multiple Heavy Metal Ions from River Water Using Ultrafine Mesoporous Magnetite Nanoparticles. ACS Omega 2019, 4, 7543–7549.
Mahdavi, S.; Jalali, M.; Afkhami, A. Removal of Heavy Metals from Aqueous Solutions Using Fe3O 4, ZnO, and CuO Nanoparticles. J. Nanopart. Res. 2012, 14, 846.
Ali, S.M.; Galal, A.; Atta, N.F.; Shammakh, Y. Toxic Heavy Metal Ions Removal from Wastewater by Nano-Magnetite: Case Study Nile River Water. Egypt. J. Chem. 2017, 60, 601–612.
Pirsaheb, M.; Moradi, N. A Systematic Review of the Sonophotocatalytic Process for the Decolorization of Dyes in Aqueous Solution: Synergistic Mechanisms, Degradation Pathways, and Process Optimization. J. Water Process Eng. 2021, 44, 102314.
Panda, S.K.; Prasad, L. Fe3O4 Based Nanoparticles as a Catalyst in Degradation of Dyes: A Short Review. Int. J. Adv. Res. Sci. Commun. Technol. 2020, 11, 34–42.
dos Santos-Durndell, V.C.; Peruzzolo, T.M.; Ucoski, G.M.; Ramos, L.P.; Nakagaki, S. Magnetically Recyclable Nanocatalysts Based on Magnetite: An Environmentally Friendly and Recyclable Catalyst for Esterification Reactions. Biofuel Res. J. 2018, 5, 806–812.
Nizam, A.; Warrier, V.G.; Devasia, J.; Ganganagappa, N. Magnetic Iron Oxide Nanoparticles Immobilized on Microporous Molecular Sieves as Efficient Porous Catalyst for Photodegradation, Transesterification and Esterification Reactions. J. Porous Mater. 2022, 29, 119–129.
Cai, H.; An, X.; Cui, J.; Li, J.; Wen, S.; Li, K.; Shen, M.; Zheng, L.; Zhang, G.; Shi, X. Facile Hydrothermal Synthesis and Surface Functionalization of Polyethyleneimine-Coated Iron Oxide Nanoparticles for Biomedical Applications. Mater. Interfaces 2013, 5, 1722–1731.
Veisi, H.; Moradi, S.B.; Saljooqi, A.; Safarimehr, P. Silver Nanoparticle-Decorated on Tannic Acid-Modified Magnetite Nanoparticles (Fe3O4@TA/Ag) for Highly Active Catalytic Reduction of 4-Nitrophenol, Rhodamine B and Methylene Blue. Mater. Sci. Eng. C 2019, 100, 445–452.
Trujillo Hernandez, J.S.; Aragón Muriel, A.; Tabares, J.A.; Pérez Alcázar, G.A.; Bolaños, A. Preparation of Fe3O4 nanoparticles and removal of methylene blue through adsorption. J. Phys. Conf. Ser. 2015, 614, 012007.
Elazab, H.A.; El-Idreesy, T.T. Optimization of the Catalytic Performance of Pd/Fe3O4 Nanoparticles Prepared via Microwave-Assisted Synthesis for Pharmaceutical and Catalysis Applications. Biointerface Res. Appl. Chem. 2019, 9, 3794–3799.
Johnson, C.E.; Johnson, J.A.; Hah, H.Y.; Cole, M.; Gray, S.; Kolesnichenko, V.; Kucheryavy, P.; Goloverda, G. Mössbauer studies of stoichiometry of Fe3O4: Characterization of nanoparticles for biomedical applications. Hyperfine Interact. 2016, 237, 27.
Kamzin, A.S. Mössbauer Investigations of Fe and Fe3O4 Magnetic Nanoparticles for Hyperthermia Applications. Phys. Solid State 2016, 58, 532–539.
Wareppam, B.; Kuzmann, E.; Garg, V.K.; Singh, L.H. Mössbauer spectroscopic investigations on iron oxides and modified nanostructures: A review. J. Mater. Res. 2022, 37, 1–21.
Hossain, M.; Hossain, M.; Begum, M.; Shahjahan, M.; Islam, M.; Saha, B. Magnetite (Fe3O4) Nanoparticles for Chromium Removal. Bangladesh J. Sci. Ind. Res. 2018, 53, 219–224.
Arévalo, P.; Isasi, J.; Caballero, A.C.; Marco, J.F.; Martín-Hernández, F. Magnetic and Structural Studies of Fe3O4 Nanoparticles Synthesized via Coprecipitation and Dispersed in Different Surfactants. Ceram. Int. 2017, 43, 10333–10340.
Giri, S.K.; Das, N.N.; Pradhan, G.C. Synthesis and Characterization of Magnetite Nanoparticles Using Waste Iron Ore Tailings for Adsorptive Removal of Dyes from Aqueous Solution. Colloids Surf. A Physicochem. Eng. Asp. 2011, 389, 43–49.
Mikhaylova, M.; Kim, D.K.; Bobrysheva, N.; Osmolowsky, M.; Semenov, V.; Tsakalakos, T.; Muhammed, M. Superparamagnetism of Magnetite Nanoparticles: Dependence on Surface Modification. Langmuir 2004, 20, 2472–2477.
Yang, C.; Dong, W.; Cui, G.; Zhao, Y.; Shi, X.; Xia, X.; Tang, B.; Wang, W. Highly efficient photocatalytic degradation of methylene blue by P2ABSA-modified TiO2 nanocomposite due to the photosensitization synergetic effect of TiO2 and P2ABSA. RSC Adv. 2017, 7, 23699–23708.
Chen, C.Y.; Liu, Y.R. Robust and Enhanced Photocatalytic Performance of Coupled CdSe/TiO2 Photocatalysts. Sci. Adv. Mater. 2015, 7, 1053–1057.
Giovannetti, R.; Rommozzi, E.; D’Amato, C.A.; Zannotti, M. Kinetic Model for Simultaneous Adsorption/Photodegradation Process of Alizarin Red S in Water Solution by Nano-TiO2 under Visible Light. Catalysts 2016, 6, 84.
Giovannetti, R.; D’ Amato, C.A.; Zannotti, M.; Rommozzi, E.; Gunnella, R.; Minicucci, M.; Di Cicco, A. Visible light photoactivity of Polypropylene coated Nano-TiO2 for dyes degradation in water. Sci. Rep. 2015, 5, 17801.
Chen, C.Y.; Hsu, L.J. Kinetic study of self-assembly of Ni(II)-doped TiO2 nanocatalysts for the photodegradation of azo pollutants. RSC Adv. 2015, 5, 88266–88271.
Woo, K.; Hong, J.; Choi, S.; Lee, H.; Ahn, J.; Kim, C.S.; Lee, S.W. Easy Synthesis and Magnetic Properties of Iron Oxide Nanoparticles. Chem. Mater 2004, 16, 2814–2818.
Toby, B.H.; von Dreele, R.B. GSAS-II: The genesis of a modern open-source all purpose crystallography software package. J. Appl. Cryst. 2013, 46, 544–549.
Varret, F.; (University of Le Mans, Le Mans, France); Greneche, J.-M.; (University of Le Mans, Le Mans, France). Unpublished work. 1994.
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spelling Torrente Rocha, Juan Josef495c010-d77d-4bef-bfc7-bb59287717d7600Aragón-Muriel, Alberto218f56c5-9bfa-4dc5-95bf-f69a592ca70f-1Hernández Quintero, Hernando Antonio9f2316ff-fd3d-49aa-80c3-18bb30857fe7600Castro Velásquez, Juan Camilo456467a6-47bf-4f1a-bcf7-8eeab608a42a-1Salazar-Camacho, Natalia Andreafd7c28f0-484f-4ea3-b34d-c7f3f67a06a3-1Pérez Alcázar, German Antonio568fb5c3-c63b-4a92-885f-b909d8b9e974-1Tabares, Jesús Anselmod2493ba1-3da1-4060-bfae-5f9bb4b06235-12025-08-25T16:44:52Z2025-08-25T16:44:52Z2022-12The aim of this study is to evaluate the applicability of the catalytic activity (CA) of the Fe3O4 magnetic system in the adsorption/degradation of methylene blue and esterification. The thermal decomposition method allowed the preparation of Fe3O4 nanoparticles. The crystallites of the Fe3O4 structural phase present an acicular form confirmed by X-ray diffraction. Transmission electron microscopy results identified the acicular shape and agglomeration of the nanoparticles. Mössbauer spectroscopy showed that the spectrum is composed of five components at room temperature, a hyperfine magnetic field distribution (HMFD), two sextets, a doublet, and a singlet. The presence of the HMFD means that a particle size distribution is present. Fluorescence spectroscopy studied the CA of the nanoparticles with methylene blue and found adsorption/degradation properties of the dye. The catalytic activity of the nanoparticles was evaluated in the esterification reaction by comparing the results in the presence and absence of catalyst for the reaction with isobutanol and octanol, where it is observed that the selectivity for the products MIBP and MNOP is favored in the first three hours of reaction.application/pdfHernandez, J., Aragón-Muriel, A., Corrales, W., Castro, J., Salazar-Camacho, N., Pérez, A. y Tabares, J. (2022). Characterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and Esterification. Molecules, 27(4), 8976. DOI: 10.3390/molecules2724897610.3390/molecules27248976https://hdl.handle.net/20.500.12313/5541engMDPISuiza4897627MoleculesMohajerani, A.; Burnett, L.; Smith, J.V.; Kurmus, H.; Milas, J.; Arulrajah, A.; Horpibulsuk, S.; Kadir, A.A. Nanoparticles in Construction Materials and Other Applications, and Implications of Nanoparticle Use. Materials 2019, 12, 3052. [Ali, A.; Zafar, H.; Zia, M.; ul Haq, I.; Phull, A.R.; Ali, J.S.; Hussain, A. Synthesis, Characterization, Applications, and Challenges of Iron Oxide Nanoparticles. Nanotechnol. Sci. Appl. 2016, 9, 49–67.Andra, S.; Balu, S.K.; Jeevanandham, J.; Muthalagu, M.; Vidyavathy, M.; Chan, Y.S.; Danquah, M.K. Phytosynthesized Metal Oxide Nanoparticles for Pharmaceutical Applications. Naunyn Schmiedebergs Arch. Pharmacol. 2019, 392, 755–771.Radoń, A.; Łoński, Y.; Warski, T.; Babilas, R.; Tański, T.; Dudziak, M.; Łukowiec, D. Catalytic Activity of Non-Spherical Shaped Magnetite Nanoparticles in Degradation of Sudan I, Rhodamine B and Methylene Blue Dyes. Appl. Surf. Sci. 2019, 487, 1018–1025.Schwaminger, S.P.; Bauer, D.; Fraga-García, P.; Wagner, F.E.; Berensmeier, S. Oxidation of Magnetite Nanoparticles: Impact on Surface and Crystal Properties. CrystEngComm 2017, 19, 246–255.Bhole, R.; Gonsalves, D.; Murugesan, G.; Narasimhan, M.K.; Srinivasan, N.R.; Dave, N.; Varadavenkatesan, T.; Vinayagam, R.; Govarthanan, M.; Selvaraj, R. Superparamagnetic Spherical Magnetite Nanoparticles: Synthesis, Characterization and Catalytic Potential. Appl. Nanosci. 2022, 12, 1–12.Giraldo, L.; Erto, A.; Moreno-Piraján, J.C. Magnetite Nanoparticles for Removal of Heavy Metals from Aqueous Solutions: Synthesis and Characterization. Adsorption 2013, 19, 465–475.Fato, F.P.; Li, D.W.; Zhao, L.J.; Qiu, K.; Long, Y.T. Simultaneous Removal of Multiple Heavy Metal Ions from River Water Using Ultrafine Mesoporous Magnetite Nanoparticles. ACS Omega 2019, 4, 7543–7549.Mahdavi, S.; Jalali, M.; Afkhami, A. Removal of Heavy Metals from Aqueous Solutions Using Fe3O 4, ZnO, and CuO Nanoparticles. J. Nanopart. Res. 2012, 14, 846.Ali, S.M.; Galal, A.; Atta, N.F.; Shammakh, Y. Toxic Heavy Metal Ions Removal from Wastewater by Nano-Magnetite: Case Study Nile River Water. Egypt. J. Chem. 2017, 60, 601–612.Pirsaheb, M.; Moradi, N. A Systematic Review of the Sonophotocatalytic Process for the Decolorization of Dyes in Aqueous Solution: Synergistic Mechanisms, Degradation Pathways, and Process Optimization. J. Water Process Eng. 2021, 44, 102314.Panda, S.K.; Prasad, L. Fe3O4 Based Nanoparticles as a Catalyst in Degradation of Dyes: A Short Review. Int. J. Adv. Res. Sci. Commun. Technol. 2020, 11, 34–42.dos Santos-Durndell, V.C.; Peruzzolo, T.M.; Ucoski, G.M.; Ramos, L.P.; Nakagaki, S. Magnetically Recyclable Nanocatalysts Based on Magnetite: An Environmentally Friendly and Recyclable Catalyst for Esterification Reactions. Biofuel Res. J. 2018, 5, 806–812.Nizam, A.; Warrier, V.G.; Devasia, J.; Ganganagappa, N. Magnetic Iron Oxide Nanoparticles Immobilized on Microporous Molecular Sieves as Efficient Porous Catalyst for Photodegradation, Transesterification and Esterification Reactions. J. Porous Mater. 2022, 29, 119–129.Cai, H.; An, X.; Cui, J.; Li, J.; Wen, S.; Li, K.; Shen, M.; Zheng, L.; Zhang, G.; Shi, X. Facile Hydrothermal Synthesis and Surface Functionalization of Polyethyleneimine-Coated Iron Oxide Nanoparticles for Biomedical Applications. Mater. Interfaces 2013, 5, 1722–1731.Veisi, H.; Moradi, S.B.; Saljooqi, A.; Safarimehr, P. Silver Nanoparticle-Decorated on Tannic Acid-Modified Magnetite Nanoparticles (Fe3O4@TA/Ag) for Highly Active Catalytic Reduction of 4-Nitrophenol, Rhodamine B and Methylene Blue. Mater. Sci. Eng. C 2019, 100, 445–452.Trujillo Hernandez, J.S.; Aragón Muriel, A.; Tabares, J.A.; Pérez Alcázar, G.A.; Bolaños, A. Preparation of Fe3O4 nanoparticles and removal of methylene blue through adsorption. J. Phys. Conf. Ser. 2015, 614, 012007.Elazab, H.A.; El-Idreesy, T.T. Optimization of the Catalytic Performance of Pd/Fe3O4 Nanoparticles Prepared via Microwave-Assisted Synthesis for Pharmaceutical and Catalysis Applications. Biointerface Res. Appl. Chem. 2019, 9, 3794–3799.Johnson, C.E.; Johnson, J.A.; Hah, H.Y.; Cole, M.; Gray, S.; Kolesnichenko, V.; Kucheryavy, P.; Goloverda, G. Mössbauer studies of stoichiometry of Fe3O4: Characterization of nanoparticles for biomedical applications. Hyperfine Interact. 2016, 237, 27.Kamzin, A.S. Mössbauer Investigations of Fe and Fe3O4 Magnetic Nanoparticles for Hyperthermia Applications. Phys. Solid State 2016, 58, 532–539.Wareppam, B.; Kuzmann, E.; Garg, V.K.; Singh, L.H. Mössbauer spectroscopic investigations on iron oxides and modified nanostructures: A review. J. Mater. Res. 2022, 37, 1–21.Hossain, M.; Hossain, M.; Begum, M.; Shahjahan, M.; Islam, M.; Saha, B. Magnetite (Fe3O4) Nanoparticles for Chromium Removal. Bangladesh J. Sci. Ind. Res. 2018, 53, 219–224.Arévalo, P.; Isasi, J.; Caballero, A.C.; Marco, J.F.; Martín-Hernández, F. Magnetic and Structural Studies of Fe3O4 Nanoparticles Synthesized via Coprecipitation and Dispersed in Different Surfactants. Ceram. Int. 2017, 43, 10333–10340.Giri, S.K.; Das, N.N.; Pradhan, G.C. Synthesis and Characterization of Magnetite Nanoparticles Using Waste Iron Ore Tailings for Adsorptive Removal of Dyes from Aqueous Solution. Colloids Surf. A Physicochem. Eng. Asp. 2011, 389, 43–49.Mikhaylova, M.; Kim, D.K.; Bobrysheva, N.; Osmolowsky, M.; Semenov, V.; Tsakalakos, T.; Muhammed, M. Superparamagnetism of Magnetite Nanoparticles: Dependence on Surface Modification. Langmuir 2004, 20, 2472–2477.Yang, C.; Dong, W.; Cui, G.; Zhao, Y.; Shi, X.; Xia, X.; Tang, B.; Wang, W. Highly efficient photocatalytic degradation of methylene blue by P2ABSA-modified TiO2 nanocomposite due to the photosensitization synergetic effect of TiO2 and P2ABSA. RSC Adv. 2017, 7, 23699–23708.Chen, C.Y.; Liu, Y.R. Robust and Enhanced Photocatalytic Performance of Coupled CdSe/TiO2 Photocatalysts. Sci. Adv. Mater. 2015, 7, 1053–1057.Giovannetti, R.; Rommozzi, E.; D’Amato, C.A.; Zannotti, M. Kinetic Model for Simultaneous Adsorption/Photodegradation Process of Alizarin Red S in Water Solution by Nano-TiO2 under Visible Light. Catalysts 2016, 6, 84.Giovannetti, R.; D’ Amato, C.A.; Zannotti, M.; Rommozzi, E.; Gunnella, R.; Minicucci, M.; Di Cicco, A. Visible light photoactivity of Polypropylene coated Nano-TiO2 for dyes degradation in water. Sci. Rep. 2015, 5, 17801.Chen, C.Y.; Hsu, L.J. Kinetic study of self-assembly of Ni(II)-doped TiO2 nanocatalysts for the photodegradation of azo pollutants. RSC Adv. 2015, 5, 88266–88271.Woo, K.; Hong, J.; Choi, S.; Lee, H.; Ahn, J.; Kim, C.S.; Lee, S.W. Easy Synthesis and Magnetic Properties of Iron Oxide Nanoparticles. Chem. Mater 2004, 16, 2814–2818.Toby, B.H.; von Dreele, R.B. GSAS-II: The genesis of a modern open-source all purpose crystallography software package. J. Appl. Cryst. 2013, 46, 544–549.Varret, F.; (University of Le Mans, Le Mans, France); Greneche, J.-M.; (University of Le Mans, Le Mans, France). Unpublished work. 1994.© 2022 by the authors.info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)https://creativecommons.org/licenses/by-nc/4.0/https://www.mdpi.com/1420-3049/27/24/8976Nanopartículas de FeO - CaracterizaciónActividad catalíticaNanopartículas de Fe₃O₄Azul de metilenoEspectroscopía MössbauerCatalytic activityEsterificationFe3O4 nanoparticlesMethylene blueMössbauer spectroscopyCharacterization of Fe3O4 Nanoparticles for Applications in Catalytic Activity in the Adsorption/Degradation of Methylene Blue and EsterificationArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Textinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionPublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-8134https://repositorio.unibague.edu.co/bitstreams/36fa284e-bd65-4d43-ae13-845313ce7bdc/download2fa3e590786b9c0f3ceba1b9656b7ac3MD51ORIGINALArtículo.pdfArtículo.pdfapplication/pdf172656https://repositorio.unibague.edu.co/bitstreams/c3433c1c-a35a-4980-82e4-66e009fb529e/downloadcd1a6533b975dc3f976e101af4fca01dMD52TEXTArtículo.pdf.txtArtículo.pdf.txtExtracted texttext/plain5196https://repositorio.unibague.edu.co/bitstreams/0a8e69db-8d43-4f36-b5d5-d3c3ac4a03c0/download1455f6f72bfe0ffac9a2360a104d5403MD53THUMBNAILArtículo.pdf.jpgArtículo.pdf.jpgIM Thumbnailimage/jpeg24325https://repositorio.unibague.edu.co/bitstreams/b8f21ba2-7718-48e3-ae53-aac217e102fa/download1d67a590c4952549877f1ae7544fbb03MD5420.500.12313/5541oai:repositorio.unibague.edu.co:20.500.12313/55412025-08-26 03:01:09.925https://creativecommons.org/licenses/by-nc/4.0/© 2022 by the authors.https://repositorio.unibague.edu.coRepositorio Institucional Universidad de Ibaguébdigital@metabiblioteca.comQ3JlYXRpdmUgQ29tbW9ucyBBdHRyaWJ1dGlvbi1Ob25Db21tZXJjaWFsLU5vRGVyaXZhdGl2ZXMgNC4wIEludGVybmF0aW9uYWwgTGljZW5zZQ0KaHR0cHM6Ly9jcmVhdGl2ZWNvbW1vbnMub3JnL2xpY2Vuc2VzL2J5LW5jLW5kLzQuMC8=

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