TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions
This study focused on investigating the adhesion and tribological properties of niobium-doped titanium nitride (TiNbN) coatings deposited on D2 steel substrates at various substrate temperatures (Ts) under simulated cutting conditions. X-ray diffraction confirmed the presence of coatings with an FCC...
- Autores:
-
Gonzalez-Carmona, Juan Manuel
Mambuscay Lozano, Claudia Lorena
Ortega-Portilla, Carolina
Hurtado-Macias, Abel
Piamba, Jeferson Fernando
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2023
- Institución:
- Universidad de Ibagué
- Repositorio:
- Repositorio Universidad de Ibagué
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.unibague.edu.co:20.500.12313/5560
- Palabra clave:
- TiNbN - Revestimiento
Adhesion
Arc PVD
Tribology
Wear
- Rights
- openAccess
- License
- © 2023 by the authors.
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| dc.title.eng.fl_str_mv |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| title |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| spellingShingle |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions TiNbN - Revestimiento Adhesion Arc PVD Tribology Wear |
| title_short |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| title_full |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| title_fullStr |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| title_full_unstemmed |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| title_sort |
TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions |
| dc.creator.fl_str_mv |
Gonzalez-Carmona, Juan Manuel Mambuscay Lozano, Claudia Lorena Ortega-Portilla, Carolina Hurtado-Macias, Abel Piamba, Jeferson Fernando |
| dc.contributor.author.none.fl_str_mv |
Gonzalez-Carmona, Juan Manuel Mambuscay Lozano, Claudia Lorena Ortega-Portilla, Carolina Hurtado-Macias, Abel Piamba, Jeferson Fernando |
| dc.subject.armarc.none.fl_str_mv |
TiNbN - Revestimiento |
| topic |
TiNbN - Revestimiento Adhesion Arc PVD Tribology Wear |
| dc.subject.proposal.eng.fl_str_mv |
Adhesion Arc PVD Tribology Wear |
| description |
This study focused on investigating the adhesion and tribological properties of niobium-doped titanium nitride (TiNbN) coatings deposited on D2 steel substrates at various substrate temperatures (Ts) under simulated cutting conditions. X-ray diffraction confirmed the presence of coatings with an FCC crystalline structure, where Nb substitutes Ti atoms in the TiN lattice. With increasing Ts, the lattice parameter decreased, and the crystallite material transitioned from flat-like to spherical shapes. Nanoindentation tests revealed an increase in hardness (H) with Ts, while a decrease in the elastic modulus (E) resulted in an improved elastic strain limit for failure (H/E) and plastic deformation resistance (H3/E2), thereby enhancing stiffness and contact elasticity. Adhesion analysis showed critical loads of ~50 N at Ts of 200 and 400 °C, and ~38 N at Ts of 600 °C. Cohesive failures were associated with lateral cracking, while adhesive failures were attributed to chipping spallation. The tribological behavior was evaluated using a pin-on-disk test, which indicated an increase in friction coefficients with Ts, although they remained lower than those of the substrate. Friction and wear were influenced by the surface morphology, facilitating the formation of abrasive particles. However, the absence of coating detachment in the wear tracks suggested that the films were capable of withstanding the load and wear |
| publishDate |
2023 |
| dc.date.issued.none.fl_str_mv |
2023-07 |
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2025-08-29T14:16:03Z |
| dc.date.available.none.fl_str_mv |
2025-08-29T14:16:03Z |
| dc.type.none.fl_str_mv |
Artículo de revista |
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Text |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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Gonzalez-Carmona, J., Mambuscay, C., Ortega-Portilla, C., Hurtado-Macias, A. y Piamba, J. (2023). TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions. Materials, 16(13). DOI: 10.3390/ma16134531 |
| dc.identifier.doi.none.fl_str_mv |
10.3390/ma16134531 |
| dc.identifier.issn.none.fl_str_mv |
19961944 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/20.500.12313/5560 |
| dc.identifier.url.none.fl_str_mv |
https://www.mdpi.com/1996-1944/16/13/4531 |
| identifier_str_mv |
Gonzalez-Carmona, J., Mambuscay, C., Ortega-Portilla, C., Hurtado-Macias, A. y Piamba, J. (2023). TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions. Materials, 16(13). DOI: 10.3390/ma16134531 10.3390/ma16134531 19961944 |
| url |
https://hdl.handle.net/20.500.12313/5560 https://www.mdpi.com/1996-1944/16/13/4531 |
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eng |
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eng |
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13 |
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4531 |
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16 |
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Materials |
| dc.relation.references.none.fl_str_mv |
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Actuators B Chem. 2010, 148, 126–134. Zhao, J.; Liu, Z.; Wang, B.; Hu, J.; Wan, Y. Tool coating effects on cutting temperature during metal cutting processes: Comprehensive review and future research directions. Mech. Syst. Signal Process. 2021, 150, 107302. Zambrano, D.F.; Hernandez-Bravo, R.; Ruden, A.; Espinosa-Arbelaez, D.G.; Gonzalez-Carmona, J.M.; Mujica, V. Mechanical, tribological and electrochemical behavior of Zr-based ceramic thin films for dental implants. Ceram. Int. 2023, 49, 2102–2114. Seinmann, P.A.; Tardy, Y.; Hintermann, H.E. Adhesion testing by the scratch test method: The influence of intrinsic and extrinsic parameters on the critical load. Thin Solid Film. 1987, 154, 333–349. Mondragon-Rodríguez, G.C.; Hernandez-Mendoza, J.L.; Gomez-Ovalle, A.E.; Gonzalez-Carmona, J.M.; Ortega-Portilla, C.; Camacho, N.; Hurtado-Macías, A.; Espinosa-Arbelaez, D.G. Alvarado-Orozco, High-temperature tribology of Hf doped c-Al0.64Ti0.36N cathodic arc PVD coatings deposited on M2 tool steel. Surf. Coat. Technol. 2021, 422, 127516. Gregorio, A.; Santos, T.; Rossi, R.; Jesus, A.M.P.; Outeiro, J.C.; Rosa, P.A.R. Tribology of metal cutting: Newly formed underside of chip. Procedia CIRP 2019, 82, 136–141. Grigoriev, S.; Vereschaka, A.; Milovich, F.; Migranov, M.; An-dreev, N.; Bublikov, J.; Sitnikov, N.; Oganyan, G. Investigation of the tribological properties of Ti-TiN-(Ti,Al,Nb,Zr)N composite coating and its efficiency in increasing wear resistance of metal cutting tools. Tribol. Int. 2021, 164, 107236. Zhu, J.-J.; Jiang, L.; Zhai, L.-H.; Zhou, J.-M.; Ding, X.-B.; Li, Z.-J. Effect of TiN inclusions on oxidation behavior of austenitic stainless steels. Mater. Lett. 2023, 335, 133761. Olaya, J.J.; Rodil, S.E.; Muhl, S. Comparative study of niobium nitride coatings deposited by unbalanced and balanced magnetron sputtering. Thin Solid Film. 2008, 516, 8319–8326. Brčka, J.; Hotový, I. Processes on the target, discharge and NbN film behaviour in reactive dc magnetron deposition. Vacuum 1995, 46, 1407–1412. Hotový, I.; Huran, J.; Búc, D.; Srnánek, R. Thermal stability of NbN films deposited on GaAs substrates. Vacuum 1998, 50, 45–48. Pogrebnjak, A.D.; Rogoz, V.M.; Bondar, O.V.; Erdybaeva, N.K.; Plotnikov, S. Vr Structure and physicomechanical properties of NbN-based protective nanocomposite coatings: A review. Prot. Met. Phys. Chem. Surf. 2016, 52, 802–813. Hotovy, I.; Buc, D.; Brcka, J.; Srnanek, R. Study of Niobium Nitride Films Produced by DC Reactive Magnetron Sputtering. Phys. Stat. Sol. 1997, 161, 97–104. Lopez, S.; Wong, M.; Sproul, W.D. Thermal behavior of carbon nitride and TiN/NbN superlattice films. J. Vac. Sci. Technol. A Vac. Surf. Film. 1995, 13, 1644–1648. Hultman, L.; Engström, C.; Odén, M. Mechanical and thermal stability of TiN/NbN superlattice thin films. Surf. Coat. Technol. 2000, 133, 227–233. Rutherford, K.L.; Hatto, P.W.; Davies, C.; Hutchings, I.M. Abrasive wear resistance of TiN/NbN multi-layers: Measurement and neural network modelling. Surf. Coat. Technol. 1996, 86, 472–479. Cicek, H.; Baran, O.; Keles, A.; Totik, Y.; Efeoglu, I. A comparative study of fatigue properties of TiVN and TiNbN thin films deposited on different substrates. Surf. Coat. Technol. 2017, 332, 296–303. Sheppard, L.R.; Zhang, H.; Liu, R.; Macartney, S.; Murphy, T.; Wainer, P.; Wuhrer, R. Reactive sputtered TixNbyNz coatings. II. Effect of common deposition parameters. Mater. Chem. Phys. 2019, 224, 320–327. Sheppard, L.R.; Zhang, H.; Liu, R.; Macartney, S.; Murphy, T.; Wuhrer, R. Reactive sputtered TiXNYNZ thin films. I. Basic processing relationships. Mater. Chem. Phys. 2019, 224, 308–313. Grimberg, I.; Zhitomirsky, V.M.; Boxman, R.L.; Goldsmith, S.; Weiss, B.Z. Multicomponent Ti-Zr-N and Ti-Nb-N coatings deposited by vacuum arc. Surf. Coat. Technol. 1998, 108, 154–159. Baran, Ö.; Keleş, A.; Çiçek, H.; Totik, Y.; Efeoğlu, İ. The mechanical and tribological properties of Ti [Nb, V] N films on the Al-2024 alloy. Surf. Coat. Technol. 2017, 332, 312–318. Bull, S.J.; Berasetegui, E.G.; Page, T.F. Modelling of the indentation response of coatings and surface treatments. Wear 2004, 256, 857–866. Keleş, A.; Çiçek, H.; Baran, Ö.; Totik, Y.; Efeoğlu, İ. Determining the critical loads of V and Nb doped ternary TiN-based coatings deposited using CFUBMS on steels. Surf. Coat. Technol. 2017, 332, 168–173. Nasab, S.A.; Manafi, S.; Ghahremani, D. Preparation of mullite/NbN composites through spark plasma sintering. Mater. Chem. Phys. 2022, 285, 126126. ASTM E3-11; Standard Guide for Preparation of Metallographic Specimens. ASTM International: West Conshohocken, PA, USA, 1 January 2017. ASTM E92-17; Standard Test Methods for Vickers Hardness and Knoop Hardness of Metallic Materials. ASTM International: West Conshohocken, PA, USA, 1 May 2017. ASTM C1624-05; Standard Test Method for Adhesion Strength and Mechanical Failure Modes of Ceramic Coatings by Quantitative Single Point Scratch Testing. ASTM International: West Conshohocken, PA, USA, 31 December 2010. ASTM G99-17; Standard Test Method for Wear Testing with a Pin-on-Disk Apparatus. ASTM International: West Conshohocken, PA, USA, 1 January 2017. Ajenifuja, E.; Popoola, A.P.I.; Popoola, O.M. Thickness dependent chemical and microstructural properties of DC reactive magnetron sputtered titanium nitride thin films on low carbon steel cross-section. J. Mater. Res. Technol. 2019, 8, 377–384. Kalal, S.; Gupta, M.; Rawat, R. N concentration effects on structure and superconductivity of NbN thin films. J. Alloys Compd. 2021, 851, 149–154. Arockiasamy, M.L.S.; Sundareswari, M.; Rajagopalan, M. Ductility behaviour of cubic titanium niobium nitride ternary alloy: A first-principles study. Indian J. 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Grigoriev, S.; Vereschaka, A.; Milovich, F.; Sitnikov, N.; Andreev, N.; Bublikov, J.; Sotova, C.; Sadov, I. Investigation of the Influence of Microdroplets on the Coatings Nanolayer Structure. Coatings 2020, 10, 1204 Shah, A.; Izman, S.; Abdul-Kadir, M.R.; Mas-Ayu, H. Influence of substrate temperature on adhesion strength of TiN coating of biomedical Ti–13Zr–13Nb alloy. Arab. J. Sci. Eng. 2017, 42, 4737–4742. Brown, I.G. Cathodic arc deposition of films. Annu. Rev. Mater. Sci. 1998, 28, 243–269. Sanders, D.M.; Anders, A. Review of cathodic arc deposition technology at the start of the new millennium. Surf. Coat. Technol. 2000, 133, 78–90. Hainsworth, S.V.; McGurk, M.R.; Page, T.F. The effect of coating cracking on the indentation response of thin hard-coated systems. Surf. Coat. Technol. 1998, 102, 97–107. Hainsworth, S.V.; Chandler, H.W.; Page, T.F. Analysis of nanoindentation load-displacement loading curves. J. Mater. Res. 1996, 11, 1987–1995. Hou, M.; Mou, W.; Yan, G.; Song, G.; Wu, Y.; Ji, W.; Jiang, Z.; Wang, W.; Qian, C.; Cai, Z. Effects of different distribution of residual stresses in the depth direction on cutting performance of TiAlN coated WC-10wt%Co tools in milling Ti-6Al-4V. Surf. Coat. Technol. 2020, 397, 125972. Guemmaz, M.; Moraitis, G.; Mosser, A.; Khan, M.A.; Parlebas, J.C. Electronic structure of sub-stoichiometric titanium carbides, nitrides and carbonitrides: Comparison of TB-LMTO calculations and valence XPS spectra. J. Alloys Compd. 1997, 262, 397–401. Tsai, D.-C.; Huang, Y.-L.; Lin, S.-R.; Liang, S.-C.; Shieu, F.-S. Effect of nitrogen flow ratios on the structure and mechanical properties of (TiVCrZrY)N coatings prepared by reactive magnetron sputtering. Appl. Surf. Sci. 2010, 257, 1361–1367. Petrov, I.; Barna, P.B.; Hultman, L.; Greene, J.E. Microstructural evolution during film growth. J. Vac. Sci. Technol. A Vac. Surf. Film. 2003, 21, S117–S128. 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Effect of substrate temperature on the mechanical and tribological properties of W/WC produced by DC magnetron sputtering. Ceram. Int. 2014, 40, 7037–7042. Wang, Y.; He, N.; Wang, C.; Li, J.; Guo, W.; Sui, Y.; Lan, J. Microstructure and tribological performance of (AlCrWTiMo)N film controlled by substrate temperature. Appl. Surf. Sci. 2022, 574, 151677. Subramanian, B.; Ananthakumar, R.; Jayachandran, M. Structural and tribological properties of DC reactive magnetron sputtered titani-um/titanium nitride (Ti/TiN) multilayered coatings. Surf. Coat. Technol. 2011, 205, 3485–3492. Xian, G.; Xiong, J.; Fan, H.; Jiang, F.; Guo, Z.; Zhao, H.; Xian, L.; Jing, Z.; Liao, J.; Liu, Y. Investigations on microstructure, mechanical and tribological properties of TiN coat-ings deposited on three different tool materials. Int. J. Refract. Met. Hard Mater. 2022, 102, 105700. Hong, D.; Niu, Y.; Li, H.; Zhong, X.; Tu, W.; Zheng, X.; Sun, J. Comparison of microstructure and tribological properties of plasma-sprayed TiN, TiC and TiB2 coatings. Surf. Coat. Technol. 2019, 374, 181–188. Deng, J.; Liu, A. Dry sliding wear behavior of PVD TiN, Ti55Al45N, and Ti35Al65N coatings at temperatures up to 600 °C. Int. J. Refract. Met. Hard Mater. 2013, 41, 241–249. Ben, D. Beake, Nano- and Micro-Scale Impact Testing of Hard Coatings: A Review. Coatings 2022, 12, 793. Li, W.; Zhang, L.; Wu, C.; Cui, Z.; Niu, C. Influence of Tool and Workpiece Properties on the Wear of the Counterparts in Contact Sliding. J. Tribol. 2022, 144, 021702. |
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Gonzalez-Carmona, Juan Manuel110bf547-831e-4382-a336-5d447618fea6-1Mambuscay Lozano, Claudia Lorena9fe189a9-1c36-483d-b437-5feb3e425554600Ortega-Portilla, Carolina782a067f-b121-4e48-9d99-bd4b890c5268-1Hurtado-Macias, Abel4c9a5bb9-8e94-498b-ae18-ed92320f5b47-1Piamba, Jeferson Fernando4ce91b6d-87c1-4a1b-9fb3-be355b73f221-12025-08-29T14:16:03Z2025-08-29T14:16:03Z2023-07This study focused on investigating the adhesion and tribological properties of niobium-doped titanium nitride (TiNbN) coatings deposited on D2 steel substrates at various substrate temperatures (Ts) under simulated cutting conditions. X-ray diffraction confirmed the presence of coatings with an FCC crystalline structure, where Nb substitutes Ti atoms in the TiN lattice. With increasing Ts, the lattice parameter decreased, and the crystallite material transitioned from flat-like to spherical shapes. Nanoindentation tests revealed an increase in hardness (H) with Ts, while a decrease in the elastic modulus (E) resulted in an improved elastic strain limit for failure (H/E) and plastic deformation resistance (H3/E2), thereby enhancing stiffness and contact elasticity. Adhesion analysis showed critical loads of ~50 N at Ts of 200 and 400 °C, and ~38 N at Ts of 600 °C. Cohesive failures were associated with lateral cracking, while adhesive failures were attributed to chipping spallation. The tribological behavior was evaluated using a pin-on-disk test, which indicated an increase in friction coefficients with Ts, although they remained lower than those of the substrate. Friction and wear were influenced by the surface morphology, facilitating the formation of abrasive particles. However, the absence of coating detachment in the wear tracks suggested that the films were capable of withstanding the load and wearapplication/pdfGonzalez-Carmona, J., Mambuscay, C., Ortega-Portilla, C., Hurtado-Macias, A. y Piamba, J. (2023). TiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting Conditions. Materials, 16(13). DOI: 10.3390/ma1613453110.3390/ma1613453119961944https://hdl.handle.net/20.500.12313/5560https://www.mdpi.com/1996-1944/16/13/4531engMultidisciplinary Digital Publishing Institute (MDPI)Suiza13453116MaterialsGe, Y.; Cheng, J.; Zhang, B.; Xue, L.; Hong, S.; Wu, Y.; Liang, X.; Zhang, Z.; Zhang, X. Sliding wear behaviors of the AlNiTi amorphous coatings: Effect of temperatures. J. Mater. Res. Technol. 2022, 21, 2362–2374.Yeo, N.C.Y.; Pepin, H.; Yang, S.S. Revolutionizing Technology Adoption for the Remanufacturing Industry. 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Tribol. 2022, 144, 021702.© 2023 by the authors.info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Atribución-NoComercial 4.0 Internacional (CC BY-NC 4.0)https://creativecommons.org/licenses/by-nc/4.0/https://www.mdpi.com/1996-1944/16/13/4531TiNbN - RevestimientoAdhesionArc PVDTribologyWearTiNbN Hard Coating Deposited at Varied Substrate Temperature by Cathodic Arc: Tribological Performance under Simulated Cutting ConditionsArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Textinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionPublicationTEXTArtículo.pdf.txtArtículo.pdf.txtExtracted texttext/plain2982https://repositorio.unibague.edu.co/bitstreams/94637edb-a355-4f6c-aaf9-ae1c35e182b6/downloada55414a6913359007c6a7ee4e47acbd9MD53THUMBNAILArtículo.pdf.jpgArtículo.pdf.jpgIM Thumbnailimage/jpeg26864https://repositorio.unibague.edu.co/bitstreams/05c1d9bc-6afa-47bc-af18-85972707ca7c/download5c72fab72ee3b9a589a7b1c3e0af3815MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-8134https://repositorio.unibague.edu.co/bitstreams/c8277be4-a70f-4636-976f-5a08677514b4/download2fa3e590786b9c0f3ceba1b9656b7ac3MD51ORIGINALArtículo.pdfArtículo.pdfapplication/pdf106598https://repositorio.unibague.edu.co/bitstreams/b0a3bd5e-8c75-474d-abb2-da9129d127e3/downloadf82157e976c75d44bf272cafa5be18a3MD5220.500.12313/5560oai:repositorio.unibague.edu.co:20.500.12313/55602025-09-12 12:09:41.265https://creativecommons.org/licenses/by-nc/4.0/© 2023 by the authors.https://repositorio.unibague.edu.coRepositorio Institucional Universidad de Ibaguébdigital@metabiblioteca.comQ3JlYXRpdmUgQ29tbW9ucyBBdHRyaWJ1dGlvbi1Ob25Db21tZXJjaWFsLU5vRGVyaXZhdGl2ZXMgNC4wIEludGVybmF0aW9uYWwgTGljZW5zZQ0KaHR0cHM6Ly9jcmVhdGl2ZWNvbW1vbnMub3JnL2xpY2Vuc2VzL2J5LW5jLW5kLzQuMC8= |
