Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2

El Furfural es un compuesto de gran interés industrial debido a su uso como solvente, en la producción de resinas, y como intermediario en la síntesis de productos químicos más complejos. El presente estudio evalúa la producción de furfural a partir de xilosa, utilizando VW/SiO2 como catalizador het...

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Autores:: Barreto Quintero , Deissy Juliana
Feria Cacais, Mariana Alejandra

Tipo de recurso:: https://purl.org/coar/resource_type/c_7a1f

Fecha de publicación:: 2024

Institución:: Universidad El Bosque

Repositorio:: Repositorio U. El Bosque

Idioma:: spa

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dc.title.none.fl_str_mv	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
dc.title.translated.none.fl_str_mv	Production of furfural from xylose using VW/SiO2 catalysts
title	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
spellingShingle	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2 Furfural Xilosa Catalizador heterogéneo Temperatura Tiempo Cromatografía líquida de alta eficiencia 615.19 Furfural Xylose Heterogeneous catalyst Temperature Time High performance liquid chromatography
title_short	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
title_full	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
title_fullStr	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
title_full_unstemmed	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
title_sort	Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2
dc.creator.fl_str_mv	Barreto Quintero , Deissy Juliana Feria Cacais, Mariana Alejandra
dc.contributor.advisor.none.fl_str_mv	Cortés Ortiz, William Giovanni
dc.contributor.author.none.fl_str_mv	Barreto Quintero , Deissy Juliana Feria Cacais, Mariana Alejandra
dc.subject.none.fl_str_mv	Furfural Xilosa Catalizador heterogéneo Temperatura Tiempo Cromatografía líquida de alta eficiencia
topic	Furfural Xilosa Catalizador heterogéneo Temperatura Tiempo Cromatografía líquida de alta eficiencia 615.19 Furfural Xylose Heterogeneous catalyst Temperature Time High performance liquid chromatography
dc.subject.ddc.none.fl_str_mv	615.19
dc.subject.keywords.none.fl_str_mv	Furfural Xylose Heterogeneous catalyst Temperature Time High performance liquid chromatography
description	El Furfural es un compuesto de gran interés industrial debido a su uso como solvente, en la producción de resinas, y como intermediario en la síntesis de productos químicos más complejos. El presente estudio evalúa la producción de furfural a partir de xilosa, utilizando VW/SiO2 como catalizador heterogéneo, evaluando la temperatura y tiempo de reacción. Para esto se planteó un diseño factorial 2 a la 2 donde se evalúo la influencia de las variables, temperatura (170 o 200 °C) y el tiempo de reacción (1 o 2 horas) en términos de conversión, selectividad y rendimiento a furfural. Para llevar a cabo la reacción, se utilizó un reactor tipo Batch, y el producto resultante se cuantificó mediante cromatografía líquida de alta eficiencia (HPLC) utilizando el método de patrón interno. Los rendimientos obtenidos fueron del 13,6 %, 12,8 %, 18,5 % y 17,8 %, siendo el mejor resultado alcanzado a 200 °C durante 1 hora. A partir de los resultados obtenidos y tras realizar un análisis estadístico, se confirma que las variables temperatura y tiempo influyen significativamente en el rendimiento del proceso de reacción.
publishDate	2024
dc.date.issued.none.fl_str_mv	2024-11
dc.date.accessioned.none.fl_str_mv	2025-05-19T16:52:48Z
dc.date.available.none.fl_str_mv	2025-05-19T16:52:48Z
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dc.type.local.none.fl_str_mv	Tesis/Trabajo de grado - Monografía - Pregrado
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dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/bachelorThesis
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dc.identifier.instname.spa.fl_str_mv	Universidad El Bosque
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identifier_str_mv	Universidad El Bosque reponame:Repositorio Institucional Universidad El Bosque repourl:https://repositorio.unbosque.edu.co
dc.language.iso.fl_str_mv	spa
language	spa
dc.relation.references.none.fl_str_mv	1. L. Zhang, H. Yu, P. Wang, and Y. Li, “Production of furfural from xylose, xylan and corncob in gamma valerolactone using FeCl3·6H2O as catalyst,” Bioresour Technol, vol. 151, pp. 355–360, Jan. 2014, doi: 10.1016/J.BIORTECH.2013.10.099. 2. Determinacion de Furfural - VSIP.INFO.Accessed: Apr. 30, 2023. [Online]. Available: https://vsip.info/determinacion-de-furfural-pdf-free.html 3. W. Yang, P. Li, D. Bo, and H. Chang, “The optimization of formic acid hydrolysis of xylose in furfural production,” Carbohydr Res, vol. 357, pp. 53–61, Aug. 2012, doi: 10.1016/J.CARRES.2012.05.020. 4. M. Del Carmen and D. Serrano, “Química verde: un nuevo enfoque para el cuidado del medio ambiente,” Educación química, vol. 20, no. 4, pp. 412–420, 2009, Accessed: Apr. 30, 2023. [Online]. Available: http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0187-893X2009000400004&lng=es&nrm=iso&tlng=es 5. P. Anastas and N. Eghbali, “Green Chemistry: Principles and Practice,” Chem Soc Rev, vol. 39, no. 1, pp. 301–312, Dec. 2010, doi: 10.1039/B918763B. 6. Green Chemistry - Current and Future Issues, Pol J Environ Stud, vol. 14, no. 4, pp. 389–395, Accessed: Apr. 28, 2023. [Online]. Available: http://www.pjoes.com/Green-Chemistry-Current-and-Future-Issues,87771,0,2.html 7. A. Aghababai Beni and H. Jabbari, “Nanomaterials for Environmental Applications,” Results in Engineering, vol. 15, Sep. 2022, doi: 10.1016/J.RINENG.2022.100467. 8. T. Tongtummachat, A. Jaree, and N. Akkarawatkhoosith, “Continuous hydrothermal furfural production from xylose in a microreactor with dual-acid catalysts,” RSC Adv, vol. 12, no. 36, pp. 23366–23378, Aug. 2022, doi: 10.1039/D2RA03609F. 9. M. Baron et al., “Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria,” Angewandte Chemie International Edition, vol. 48, no. 43, pp. 8006–8009, Oct. 2009, doi: 10.1002/ANIE.200903085. 10. S. Xu et al., “Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems,” Fuel Processing Technology, vol. 175, pp. 90–96, Jun. 2018, doi: 10.1016/J.FUPROC.2018.04.005. 11. A. Deng et al., “A feasible process for furfural production from the pre-hydrolysis liquor of corncob via biochar catalysts in a new biphasic system,” Bioresour Technol, vol. 216, pp. 754–760, Sep. 2016, doi: 10.1016/J.BIORTECH.2016.06.002. 12. L. Zhu, “Surface Temperature Excess in Heterogeneous Catalysis ,” 2005. 13. K. Zheng, G. Yang, W. Shen, Q. Xu, F. Hu, and Z. Li, “Preparation and Denitration Performance of V-W/TiO2-SiO2 Nanotube Catalysts,” Water Air Soil Pollut, vol. 229, no. 4, Apr. 2018, doi: 10.1007/S11270-018-3768-3. 14. B. Wang, Y. Bian, S. Feng, S. Q. Wang, and B. X. Shen, “Modification of the V2O5-WO3/TiO2 catalyst with Nb to reduce its activity for SO2 oxidation during the selective catalytic reduction of NOx,” Journal of Fuel Chemistry and Technology, vol. 50, no. 4, pp. 503–512, Apr. 2022, doi: 10.1016/S1872-5813(21)60177-9. 15. A. Marberger, D. Ferri, D. Rentsch, F. Krumeich, M. Elsener, and O. Kröcher, “Effect of SiO2 on co-impregnated V2O5/WO3/TiO2 catalysts for the selective catalytic reduction of NO with NH3,” Catal Today, vol. 320, pp. 123–132, Jan. 2019, doi: 10.1016/J.CATTOD.2017.11.037. 16. X. Zhang, P. Zhu, Q. Li, and H. Xia, “Recent Advances in the Catalytic Conversion of Biomass to Furfural in Deep Eutectic Solvents,” Front Chem, vol. 10, p. 911674, May 2022, doi: 10.3389/FCHEM.2022.911674/BIBTEX. 17. L. Zhang, L. Tian, R. Sun, C. Liu, Q. Kou, and H. Zuo, “Transformation of corncob into furfural by a bifunctional solid acid catalyst,” Bioresour Technol, vol. 276, pp. 60–64, Mar. 2019, doi: 10.1016/J.BIORTECH.2018.12.094. 18. Kevin René Suárez Suárez, “Obtención de furfural a partir de residuos del cultivo de café empleando materiales catalíticos de hierro soportado en óxido de silicio,” 2023. Accessed: Sep. 18, 2024. [Online]. Available: https://repositorio.unal.edu.co/bitstream/handle/unal/84882/1031127909.2023.pdf?sequence=2 19. S. Arias-Giraldo and D. M. López-Velasco, “Reacciones químicas de los azúcares simples empleados en la industria alimentaria,” Lámpsakos (revista descontinuada), no. 22, pp. 123–135, Nov. 2019, doi: 10.21501/21454086.3252. 20. Choudhary, S. I. Sandler, and D. G. Vlachos, “Conversión de xilosa a furfural utilizando catalizadores ácidos de Lewis y Brønsted en medios acuosos,” Catálisis ACS, vol. 2, no. 9, pp. 2022–2028, doi: 10.1021/cs300265d. 21. K. Yan, G. Wu, T. Lafleur, and C. Jarvis, “Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals,” Renewable and Sustainable Energy Reviews, vol. 38, pp. 663–676, Oct. 2014, doi: 10.1016/J.RSER.2014.07.003. 22. I. Muylaert and P. Van Der Voort, “Supported vanadium oxide in heterogeneous catalysis: elucidating the structure–activity relationship with spectroscopy,” Physical Chemistry Chemical Physics, vol. 11, no. 16, pp. 2826–2832, Apr. 2009, doi: 10.1039/B819808J. 23. D. C. Crans, D. Gambino, and S. B. Etcheverry, “Vanadium science: chemistry, catalysis, materials, biological and medicinal studies,” New Journal of Chemistry, vol. 43, no. 45, pp. 17535–17537, Nov. 2019, doi: 10.1039/C9NJ90156F. 24. Q. Zhang, C. Wang, J. Mao, S. Ramaswamy, X. Zhang, and F. Xu, “Insights on the efficiency of bifunctional solid organocatalysts in converting xylose and biomass into furfural in a GVL-water solvent,” Ind Crops Prod, vol. 138, p. 111454, Oct. 2019, doi: 10.1016/J.INDCROP.2019.06.017. 25. D. Padovan, K. Nakajima, and E. J. M. Hensen, “Metal Oxide Catalysts for the Valorization of Biomass-Derived Sugars,” Crystalline Metal Oxide Catalysts, pp. 325–347, Jan. 2022, doi: 10.1007/978-981-19-5013-1_11. 26. M. Sajid, M. Rizwan Dilshad, M. Saif Ur Rehman, D. Liu, and X. Zhao, “Catalytic Conversion of Xylose to Furfural by p-Toluenesulfonic Acid (pTSA) and Chlorides: Process Optimization and Kinetic Modeling,” Molecules, vol. 26, no. 8, Apr. 2021, doi: 10.3390/MOLECULES26082208. 27. G. Xu, Z. Tu, X. Hu, M. Li, X. Zhang, and Y. Wu, “Ionic buffering biphase systems as catalysts and solvents for efficient dehydration of xylose and hemicellulose to furfural,” J Mol Liq, vol. 381, p. 121836, Jul. 2023, doi: 10.1016/J.MOLLIQ.2023.121836. 28. Conversión catalítica de xilosa a furfural empleando catalizadores V/SiO2, W/SiO2 y VW/SiO2 sintetizados por el método sol-gel asistido por microondas. Accessed: Sep. 18, 2024. [Online]. Available: https://www.abq.org.br/cbq/2022/trabalhos/12/368-675.html 29. Residual Sum of Squares (RSS): What It Is and How to Calculate It. Accessed: Sep. 19, 2024. [Online]. Available: https://www.investopedia.com/terms/r/residual-sum-of-squares.asp 30. S. Xu et al., “Efficient production of furfural from xylose and wheat straw by bifunctional chromium phosphate catalyst in biphasic systems,” Fuel Processing Technology, vol. 175, pp. 90–96, Jun. 2018, doi: 10.1016/J.FUPROC.2018.04.005. 31. E. Lam, E. Majid, A. C. W. Leung, J. H. Chong, K. A. Mahmoud, and J. H. T. Luong, “Synthesis of Furfural from Xylose by Heterogeneous and Reusable Nafion Catalysts,” ChemSusChem, vol. 4, no. 4, pp. 535–541, Apr. 2011, doi: 10.1002/CSSC.201100023. 32. J. Zhang, L. Lin, and S. Liu, “Efficient Production of Furan Derivatives from a Sugar Mixture by Catalytic Process,” Energy and Fuels, vol. 26, no. 7, pp. 4560–4567, Jul. 2012, doi: 10.1021/EF300606V. 33. R. Weingarten, J. Cho, W. C. Conner, and G. W. Huber, “Kinetics of furfural production by dehydration of xylose in a biphasic reactor with microwave heating,” Green Chemistry, vol. 12, no. 8, pp. 1423–1429, Aug. 2010, doi: 10.1039/C003459B. 34. C. Sener, A. H. Motagamwala, D. M. Alonso, and J. A. Dumesic, “Enhanced Furfural Yields from Xylose Dehydration in the γ-Valerolactone/Water Solvent System at Elevated Temperatures,” ChemSusChem, vol. 11, no. 14, pp. 2321–2331, Jul. 2018, doi: 10.1002/CSSC.201800730. 35. T. Huang et al., “Preparation of Furfural From Xylose Catalyzed by Diimidazole Hexafluorophosphate in Microwave,” Front Chem, vol. 9, p. 727382, Sep. 2021, doi: 10.3389/FCHEM.2021.727382/BIBTEX. 36. E. Rakić, A. Kostyniuk, N. Nikačević, and B. Likozar, “Reaction microkinetic model of xylose dehydration to furfural over beta zeolite catalyst,” Biomass Convers Biorefin, vol. 1, pp. 1–15, Oct. 2023, doi: 10.1007/S13399-023-04969-1/TABLES/2. 37.A. F. Siegel and M. R. Wagner, “ANOVA: Testing for Differences Among Many Samples and Much More,” Practical Business Statistics, pp. 485–510, Jan. 2022, doi: 10.1016/B978-0-12-820025-4.00015-4. 38. G. Gómez Millán, Z. El Assal, K. Nieminen, S. Hellsten, J. Llorca, and H. Sixta, “Fast furfural formation from xylose using solid acid catalysts assisted by a microwave reactor,” Fuel Processing Technology, vol. 182, pp. 56–67, Dec. 2018, doi: 10.1016/J.FUPROC.2018.10.013. 39. Selective Conversion of Biomass Hemicellulose to Furfural Using Maleic Acid with Microwave Heating. Energy & Fuels, 26(2), 1298–1304 \| 10.1021/ef2014106.” Accessed: Apr. 02, 2023. [Online]. Available: https://pubs.acs.org/doi/abs/10.1021/ef2014106 40. W. Cortés and A. María Campos Rosario, “CONVERSION OF D-XYLOSE INTO FURFURAL WITH ALUMINUM AND HAFNIUM PILLARED CLAYS AS CATALYST CONVERSION DE D-XILOSA A FURFURAL CON ARCILLAS PILARIZADAS CON ALUMINIO Y HAFNIO COMO CATALIZADORES YINETH PIÑEROS-CASTRO,” vol. 80, pp. 105–112, 2013, Accessed: Aug. 14, 2024. [Online]. Available: http://www.redalyc.org/articulo.oa?id=49627455015 41. C. Xiouras, N. Radacsi, G. Sturm, and G. D. Stefanidis, “Furfural synthesis from D-xylose in the presence of sodium chloride: Microwave versus conventional heating,” ChemSusChem, vol. 9, no. 16, pp. 2159–2166, Aug. 2016, doi: 10.1002/cssc.201600446. 42. L. Ye, Y. Han, X. Wang, X. Lu, X. Qi, and H. Yu, “Recent progress in furfural production from hemicellulose and its derivatives: Conversion mechanism, catalytic system, solvent selection,” Molecular Catalysis, vol. 515, p. 111899, Oct. 2021, doi: 10.1016/J.MCAT.2021.111899. 43. C. P. Jiménez-Gómez, “Gas-phase hydrogenation of furfural over Cu/CeO2 catalysts”.
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spelling	Cortés Ortiz, William GiovanniBarreto Quintero , Deissy JulianaFeria Cacais, Mariana Alejandra2025-05-19T16:52:48Z2025-05-19T16:52:48Z2024-11https://hdl.handle.net/20.500.12495/14390Universidad El Bosquereponame:Repositorio Institucional Universidad El Bosquerepourl:https://repositorio.unbosque.edu.coEl Furfural es un compuesto de gran interés industrial debido a su uso como solvente, en la producción de resinas, y como intermediario en la síntesis de productos químicos más complejos. El presente estudio evalúa la producción de furfural a partir de xilosa, utilizando VW/SiO2 como catalizador heterogéneo, evaluando la temperatura y tiempo de reacción. Para esto se planteó un diseño factorial 2 a la 2 donde se evalúo la influencia de las variables, temperatura (170 o 200 °C) y el tiempo de reacción (1 o 2 horas) en términos de conversión, selectividad y rendimiento a furfural. Para llevar a cabo la reacción, se utilizó un reactor tipo Batch, y el producto resultante se cuantificó mediante cromatografía líquida de alta eficiencia (HPLC) utilizando el método de patrón interno. Los rendimientos obtenidos fueron del 13,6 %, 12,8 %, 18,5 % y 17,8 %, siendo el mejor resultado alcanzado a 200 °C durante 1 hora. A partir de los resultados obtenidos y tras realizar un análisis estadístico, se confirma que las variables temperatura y tiempo influyen significativamente en el rendimiento del proceso de reacción.PregradoQuímico FarmacéuticoFurfural is a compound of great industrial interest due to its use as a solvent, in the production of resins, and as an intermediate in the synthesis of more complex chemical products. The present study evaluates the production of furfural from xylose, using VW/SiO2 as heterogeneous catalyst, evaluating the temperature and reaction time. A 2 to 2 factorial design was used to evaluate the influence of the variables temperature (170 or 200 °C) and reaction time (1 or 2 hours) in terms of conversion, selectivity and furfural yield. A batch reactor was used to carry out the reaction, and the resulting product was quantified by high performance liquid chromatography (HPLC) using the internal standard method. The yields obtained were 13.6 %, 12.8 %, 18.5 % and 17.8 %, the best result being achieved at 200 °C for 1 hour. From the results obtained and after performing a statistical analysis, it is confirmed that the variables temperature and time have a significant influence on the yield of the reaction process.application/pdfAttribution-NonCommercial-ShareAlike 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-sa/4.0/Acceso abiertohttps://purl.org/coar/access_right/c_abf2http://purl.org/coar/access_right/c_abf2FurfuralXilosaCatalizador heterogéneoTemperaturaTiempoCromatografía líquida de alta eficiencia615.19FurfuralXyloseHeterogeneous catalystTemperatureTimeHigh performance liquid chromatographyProducción de furfural a partir de xilosa empleando catalizadores de VW/SiO2Production of furfural from xylose using VW/SiO2 catalystsQuímica FarmacéuticaUniversidad El BosqueFacultad de CienciasTesis/Trabajo de grado - Monografía - Pregradohttps://purl.org/coar/resource_type/c_7a1fhttp://purl.org/coar/resource_type/c_7a1finfo:eu-repo/semantics/bachelorThesishttps://purl.org/coar/version/c_ab4af688f83e57aa1. L. Zhang, H. Yu, P. Wang, and Y. Li, “Production of furfural from xylose, xylan and corncob in gamma valerolactone using FeCl3·6H2O as catalyst,” Bioresour Technol, vol. 151, pp. 355–360, Jan. 2014, doi: 10.1016/J.BIORTECH.2013.10.099.2. Determinacion de Furfural - VSIP.INFO.Accessed: Apr. 30, 2023. [Online]. Available: https://vsip.info/determinacion-de-furfural-pdf-free.html3. W. Yang, P. Li, D. Bo, and H. Chang, “The optimization of formic acid hydrolysis of xylose in furfural production,” Carbohydr Res, vol. 357, pp. 53–61, Aug. 2012, doi: 10.1016/J.CARRES.2012.05.020.4. M. Del Carmen and D. Serrano, “Química verde: un nuevo enfoque para el cuidado del medio ambiente,” Educación química, vol. 20, no. 4, pp. 412–420, 2009, Accessed: Apr. 30, 2023. [Online]. Available: http://www.scielo.org.mx/scielo.php?script=sci_arttext&pid=S0187-893X2009000400004&lng=es&nrm=iso&tlng=es5. P. Anastas and N. Eghbali, “Green Chemistry: Principles and Practice,” Chem Soc Rev, vol. 39, no. 1, pp. 301–312, Dec. 2010, doi: 10.1039/B918763B.6. Green Chemistry - Current and Future Issues, Pol J Environ Stud, vol. 14, no. 4, pp. 389–395, Accessed: Apr. 28, 2023. [Online]. Available: http://www.pjoes.com/Green-Chemistry-Current-and-Future-Issues,87771,0,2.html7. A. Aghababai Beni and H. Jabbari, “Nanomaterials for Environmental Applications,” Results in Engineering, vol. 15, Sep. 2022, doi: 10.1016/J.RINENG.2022.100467.8. T. Tongtummachat, A. Jaree, and N. Akkarawatkhoosith, “Continuous hydrothermal furfural production from xylose in a microreactor with dual-acid catalysts,” RSC Adv, vol. 12, no. 36, pp. 23366–23378, Aug. 2022, doi: 10.1039/D2RA03609F.9. M. Baron et al., “Resolving the Atomic Structure of Vanadia Monolayer Catalysts: Monomers, Trimers, and Oligomers on Ceria,” Angewandte Chemie International Edition, vol. 48, no. 43, pp. 8006–8009, Oct. 2009, doi: 10.1002/ANIE.200903085.10. S. 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Producción de furfural a partir de xilosa empleando catalizadores de VW/SiO2

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