Investigating the Detection and Role of Cocrystals in Metal-mediated C–H Activation Through Mechanochemistry

Mechanochemical, metal-mediated activation and functionalization of C–H bonds have demonstrated methodological advantages that surpass those of traditional solution-based protocols. 1 Despite these advancements, the mechanisms governing C–H bond activation under mechanochemical conditions are still not well understood. This presentation will describe recent findings in the mechanochemical synthesis of metallacycles via ball milling of organic substrates and half-sandwich organometallic complexes including the detection and involvement of cocrystal intermediates between the reactants (Figure). 2,3,4

• Autores: Hernández Barajas, José Gregorio
• Tipo de recurso: Conferencia (Ponencia)
• Fecha de publicación: 2025
• Institución: Universidad de Antioquia
• Repositorio: Repositorio UdeA
• Idioma: eng
• OAI Identifier: oai:bibliotecadigital.udea.edu.co:10495/47532
• Acceso en línea: https://hdl.handle.net/10495/47532
• Palabra clave: Química mecánica; Mechanical chemistry; Cocristales; Cocrystals; http://id.loc.gov/authorities/subjects/sh85082752; ODS 9: Industria, innovación e infraestructura. Construir infraestructuras resilientes, promover la industrialización inclusiva y sostenible y fomentar la innovación
• Rights: openAccess
• License: http://creativecommons.org/licenses/by-nc-sa/4.0/