Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment
ABSTRACT: In this work optical properties of titanium dioxide nanoparticles were studied. Titanium dioxide nanoparticles were synthesized by the sol-gel method followed by a hydrothermal treatment using tetraisopropyl orthotitanate (TIOT) and 2-propanol. The synthesized samples were characterized by...
- Autores:
-
Marín Sepúlveda, Juan Miguel
Restrepo Vásquez, Gloria María
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2010
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/7689
- Acceso en línea:
- http://hdl.handle.net/10495/7689
- Palabra clave:
- Band gap
Hydrothermal treatment
Sol-gel method
Titanium dioxide
- Rights
- openAccess
- License
- https://creativecommons.org/licenses/by/4.0/
| id |
UDEA2_91e11cb04435045e37784524fecd6c8a |
|---|---|
| oai_identifier_str |
oai:bibliotecadigital.udea.edu.co:10495/7689 |
| network_acronym_str |
UDEA2 |
| network_name_str |
Repositorio UdeA |
| repository_id_str |
|
| dc.title.spa.fl_str_mv |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| title |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| spellingShingle |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment Band gap Hydrothermal treatment Sol-gel method Titanium dioxide |
| title_short |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| title_full |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| title_fullStr |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| title_full_unstemmed |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| title_sort |
Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment |
| dc.creator.fl_str_mv |
Marín Sepúlveda, Juan Miguel Restrepo Vásquez, Gloria María |
| dc.contributor.author.none.fl_str_mv |
Marín Sepúlveda, Juan Miguel Restrepo Vásquez, Gloria María |
| dc.contributor.researchgroup.spa.fl_str_mv |
Procesos FisicoquÍmicos Aplicados (PFA) |
| dc.subject.none.fl_str_mv |
Band gap Hydrothermal treatment Sol-gel method Titanium dioxide |
| topic |
Band gap Hydrothermal treatment Sol-gel method Titanium dioxide |
| description |
ABSTRACT: In this work optical properties of titanium dioxide nanoparticles were studied. Titanium dioxide nanoparticles were synthesized by the sol-gel method followed by a hydrothermal treatment using tetraisopropyl orthotitanate (TIOT) and 2-propanol. The synthesized samples were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV/DRS) and nitrogen adsorption-desorption methods. The bandgap energy was obtained using the Kubelka-Munk reemission function. The catalyst synthesized with a molar ratio of R1 (water/TIOT) = 3.5 and R2 (2-propanol/TIOT) = 15 has a predominately anatase phase. It also has a high photo degradation of methyl orange compared to TiO2 Degussa P-25. A shift band gap energy of 3.27 was observed. |
| publishDate |
2010 |
| dc.date.issued.none.fl_str_mv |
2010 |
| dc.date.accessioned.none.fl_str_mv |
2017-07-17T20:00:39Z |
| dc.date.available.none.fl_str_mv |
2017-07-17T20:00:39Z |
| dc.type.spa.fl_str_mv |
Artículo de investigación |
| dc.type.coar.spa.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.redcol.spa.fl_str_mv |
https://purl.org/redcol/resource_type/ART |
| dc.type.coarversion.spa.fl_str_mv |
http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.version.spa.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
| format |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| status_str |
publishedVersion |
| dc.identifier.citation.spa.fl_str_mv |
Valencia Hurtado, S. H., Marín Sepúlveda, J. M., & Restrepo Vásquez, G. M. (2010). Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment. The Open Materials Science Journal. 4, 9-14. DOI: 10.2174/1874088X01004010009 |
| dc.identifier.issn.none.fl_str_mv |
1874-088X |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/7689 |
| dc.identifier.doi.none.fl_str_mv |
10.2174/1874088X01004010009 |
| identifier_str_mv |
Valencia Hurtado, S. H., Marín Sepúlveda, J. M., & Restrepo Vásquez, G. M. (2010). Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment. The Open Materials Science Journal. 4, 9-14. DOI: 10.2174/1874088X01004010009 1874-088X 10.2174/1874088X01004010009 |
| url |
http://hdl.handle.net/10495/7689 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.citationendpage.spa.fl_str_mv |
14 |
| dc.relation.citationstartpage.spa.fl_str_mv |
9 |
| dc.relation.citationvolume.spa.fl_str_mv |
4 |
| dc.relation.ispartofjournal.spa.fl_str_mv |
The Open Materials Science Journal |
| dc.rights.uri.spa.fl_str_mv |
https://creativecommons.org/licenses/by/4.0/ |
| dc.rights.uri.*.fl_str_mv |
https://creativecommons.org/licenses/by/2.5/co/ |
| dc.rights.accessrights.*.fl_str_mv |
Atribución 2.5 Colombia (CC BY 2.5 CO) |
| dc.rights.accessrights.spa.fl_str_mv |
info:eu-repo/semantics/openAccess |
| dc.rights.coar.spa.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0/ https://creativecommons.org/licenses/by/2.5/co/ Atribución 2.5 Colombia (CC BY 2.5 CO) http://purl.org/coar/access_right/c_abf2 |
| eu_rights_str_mv |
openAccess |
| dc.format.extent.spa.fl_str_mv |
5 |
| dc.format.mimetype.spa.fl_str_mv |
application/pdf |
| dc.publisher.spa.fl_str_mv |
Bentham Science |
| dc.publisher.place.spa.fl_str_mv |
Emiratos Arabes |
| institution |
Universidad de Antioquia |
| bitstream.url.fl_str_mv |
https://bibliotecadigital.udea.edu.co/bitstreams/1f026256-55a0-4f47-b4f2-5481c72c418f/download https://bibliotecadigital.udea.edu.co/bitstreams/26629147-7b4c-4123-9909-729f0253bae1/download https://bibliotecadigital.udea.edu.co/bitstreams/8fe86525-0873-455a-80fd-e8543f1bdea6/download https://bibliotecadigital.udea.edu.co/bitstreams/30900176-d05c-4d02-9649-8e9f6709a3d7/download https://bibliotecadigital.udea.edu.co/bitstreams/bd1d5df6-7898-405f-9edd-a11969e3301c/download https://bibliotecadigital.udea.edu.co/bitstreams/cd73b66d-33af-473d-94d5-64eabcf5e02d/download https://bibliotecadigital.udea.edu.co/bitstreams/145bc389-ea33-45fb-ba3d-0fcd8e871ba7/download |
| bitstream.checksum.fl_str_mv |
d725524c81245bf415f4f1df64ba2735 4afdbb8c545fd630ea7db775da747b2f d41d8cd98f00b204e9800998ecf8427e d41d8cd98f00b204e9800998ecf8427e 8a4605be74aa9ea9d79846c1fba20a33 09b5118d5d53023df04d21096844fa6b d8ffab79bf2b34ce796fbac31a1ebace |
| bitstream.checksumAlgorithm.fl_str_mv |
MD5 MD5 MD5 MD5 MD5 MD5 MD5 |
| repository.name.fl_str_mv |
Repositorio Institucional de la Universidad de Antioquia |
| repository.mail.fl_str_mv |
aplicacionbibliotecadigitalbiblioteca@udea.edu.co |
| _version_ |
1851052121382715392 |
| spelling |
Marín Sepúlveda, Juan MiguelRestrepo Vásquez, Gloria MaríaProcesos FisicoquÍmicos Aplicados (PFA)2017-07-17T20:00:39Z2017-07-17T20:00:39Z2010Valencia Hurtado, S. H., Marín Sepúlveda, J. M., & Restrepo Vásquez, G. M. (2010). Study of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal Treatment. The Open Materials Science Journal. 4, 9-14. DOI: 10.2174/1874088X010040100091874-088Xhttp://hdl.handle.net/10495/768910.2174/1874088X01004010009ABSTRACT: In this work optical properties of titanium dioxide nanoparticles were studied. Titanium dioxide nanoparticles were synthesized by the sol-gel method followed by a hydrothermal treatment using tetraisopropyl orthotitanate (TIOT) and 2-propanol. The synthesized samples were characterized by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (UV/DRS) and nitrogen adsorption-desorption methods. The bandgap energy was obtained using the Kubelka-Munk reemission function. The catalyst synthesized with a molar ratio of R1 (water/TIOT) = 3.5 and R2 (2-propanol/TIOT) = 15 has a predominately anatase phase. It also has a high photo degradation of methyl orange compared to TiO2 Degussa P-25. A shift band gap energy of 3.27 was observed.5application/pdfengBentham ScienceEmiratos Arabeshttps://creativecommons.org/licenses/by/4.0/https://creativecommons.org/licenses/by/2.5/co/Atribución 2.5 Colombia (CC BY 2.5 CO)info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Band gapHydrothermal treatmentSol-gel methodTitanium dioxideStudy of the Bandgap of Synthesized Titanium Dioxide Nanoparticules Using the Sol-Gel Method and a Hydrothermal TreatmentArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion1494The Open Materials Science JournalPublicationORIGINALMarinJuan_2010_StudyBandgapSynthesized.pdfMarinJuan_2010_StudyBandgapSynthesized.pdfArtículo de investigaciónapplication/pdf1423513https://bibliotecadigital.udea.edu.co/bitstreams/1f026256-55a0-4f47-b4f2-5481c72c418f/downloadd725524c81245bf415f4f1df64ba2735MD51trueAnonymousREADCC-LICENSElicense_urllicense_urltext/plain; charset=utf-849https://bibliotecadigital.udea.edu.co/bitstreams/26629147-7b4c-4123-9909-729f0253bae1/download4afdbb8c545fd630ea7db775da747b2fMD52falseAnonymousREADlicense_textlicense_texttext/html; charset=utf-80https://bibliotecadigital.udea.edu.co/bitstreams/8fe86525-0873-455a-80fd-e8543f1bdea6/downloadd41d8cd98f00b204e9800998ecf8427eMD53falseAnonymousREADlicense_rdflicense_rdfapplication/rdf+xml; charset=utf-80https://bibliotecadigital.udea.edu.co/bitstreams/30900176-d05c-4d02-9649-8e9f6709a3d7/downloadd41d8cd98f00b204e9800998ecf8427eMD54falseAnonymousREADLICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://bibliotecadigital.udea.edu.co/bitstreams/bd1d5df6-7898-405f-9edd-a11969e3301c/download8a4605be74aa9ea9d79846c1fba20a33MD55falseAnonymousREADTEXTMarinJuan_2010_StudyBandgapSynthesized.pdf.txtMarinJuan_2010_StudyBandgapSynthesized.pdf.txtExtracted texttext/plain25443https://bibliotecadigital.udea.edu.co/bitstreams/cd73b66d-33af-473d-94d5-64eabcf5e02d/download09b5118d5d53023df04d21096844fa6bMD510falseAnonymousREADTHUMBNAILMarinJuan_2010_StudyBandgapSynthesized.pdf.jpgMarinJuan_2010_StudyBandgapSynthesized.pdf.jpgGenerated Thumbnailimage/jpeg17432https://bibliotecadigital.udea.edu.co/bitstreams/145bc389-ea33-45fb-ba3d-0fcd8e871ba7/downloadd8ffab79bf2b34ce796fbac31a1ebaceMD511falseAnonymousREAD10495/7689oai:bibliotecadigital.udea.edu.co:10495/76892025-03-26 17:17:24.14https://creativecommons.org/licenses/by/4.0/open.accesshttps://bibliotecadigital.udea.edu.coRepositorio Institucional de la Universidad de Antioquiaaplicacionbibliotecadigitalbiblioteca@udea.edu.coTk9URTogUExBQ0UgWU9VUiBPV04gTElDRU5TRSBIRVJFClRoaXMgc2FtcGxlIGxpY2Vuc2UgaXMgcHJvdmlkZWQgZm9yIGluZm9ybWF0aW9uYWwgcHVycG9zZXMgb25seS4KCk5PTi1FWENMVVNJVkUgRElTVFJJQlVUSU9OIExJQ0VOU0UKCkJ5IHNpZ25pbmcgYW5kIHN1Ym1pdHRpbmcgdGhpcyBsaWNlbnNlLCB5b3UgKHRoZSBhdXRob3Iocykgb3IgY29weXJpZ2h0Cm93bmVyKSBncmFudHMgdG8gRFNwYWNlIFVuaXZlcnNpdHkgKERTVSkgdGhlIG5vbi1leGNsdXNpdmUgcmlnaHQgdG8gcmVwcm9kdWNlLAp0cmFuc2xhdGUgKGFzIGRlZmluZWQgYmVsb3cpLCBhbmQvb3IgZGlzdHJpYnV0ZSB5b3VyIHN1Ym1pc3Npb24gKGluY2x1ZGluZwp0aGUgYWJzdHJhY3QpIHdvcmxkd2lkZSBpbiBwcmludCBhbmQgZWxlY3Ryb25pYyBmb3JtYXQgYW5kIGluIGFueSBtZWRpdW0sCmluY2x1ZGluZyBidXQgbm90IGxpbWl0ZWQgdG8gYXVkaW8gb3IgdmlkZW8uCgpZb3UgYWdyZWUgdGhhdCBEU1UgbWF5LCB3aXRob3V0IGNoYW5naW5nIHRoZSBjb250ZW50LCB0cmFuc2xhdGUgdGhlCnN1Ym1pc3Npb24gdG8gYW55IG1lZGl1bSBvciBmb3JtYXQgZm9yIHRoZSBwdXJwb3NlIG9mIHByZXNlcnZhdGlvbi4KCllvdSBhbHNvIGFncmVlIHRoYXQgRFNVIG1heSBrZWVwIG1vcmUgdGhhbiBvbmUgY29weSBvZiB0aGlzIHN1Ym1pc3Npb24gZm9yCnB1cnBvc2VzIG9mIHNlY3VyaXR5LCBiYWNrLXVwIGFuZCBwcmVzZXJ2YXRpb24uCgpZb3UgcmVwcmVzZW50IHRoYXQgdGhlIHN1Ym1pc3Npb24gaXMgeW91ciBvcmlnaW5hbCB3b3JrLCBhbmQgdGhhdCB5b3UgaGF2ZQp0aGUgcmlnaHQgdG8gZ3JhbnQgdGhlIHJpZ2h0cyBjb250YWluZWQgaW4gdGhpcyBsaWNlbnNlLiBZb3UgYWxzbyByZXByZXNlbnQKdGhhdCB5b3VyIHN1Ym1pc3Npb24gZG9lcyBub3QsIHRvIHRoZSBiZXN0IG9mIHlvdXIga25vd2xlZGdlLCBpbmZyaW5nZSB1cG9uCmFueW9uZSdzIGNvcHlyaWdodC4KCklmIHRoZSBzdWJtaXNzaW9uIGNvbnRhaW5zIG1hdGVyaWFsIGZvciB3aGljaCB5b3UgZG8gbm90IGhvbGQgY29weXJpZ2h0LAp5b3UgcmVwcmVzZW50IHRoYXQgeW91IGhhdmUgb2J0YWluZWQgdGhlIHVucmVzdHJpY3RlZCBwZXJtaXNzaW9uIG9mIHRoZQpjb3B5cmlnaHQgb3duZXIgdG8gZ3JhbnQgRFNVIHRoZSByaWdodHMgcmVxdWlyZWQgYnkgdGhpcyBsaWNlbnNlLCBhbmQgdGhhdApzdWNoIHRoaXJkLXBhcnR5IG93bmVkIG1hdGVyaWFsIGlzIGNsZWFybHkgaWRlbnRpZmllZCBhbmQgYWNrbm93bGVkZ2VkCndpdGhpbiB0aGUgdGV4dCBvciBjb250ZW50IG9mIHRoZSBzdWJtaXNzaW9uLgoKSUYgVEhFIFNVQk1JU1NJT04gSVMgQkFTRUQgVVBPTiBXT1JLIFRIQVQgSEFTIEJFRU4gU1BPTlNPUkVEIE9SIFNVUFBPUlRFRApCWSBBTiBBR0VOQ1kgT1IgT1JHQU5JWkFUSU9OIE9USEVSIFRIQU4gRFNVLCBZT1UgUkVQUkVTRU5UIFRIQVQgWU9VIEhBVkUKRlVMRklMTEVEIEFOWSBSSUdIVCBPRiBSRVZJRVcgT1IgT1RIRVIgT0JMSUdBVElPTlMgUkVRVUlSRUQgQlkgU1VDSApDT05UUkFDVCBPUiBBR1JFRU1FTlQuCgpEU1Ugd2lsbCBjbGVhcmx5IGlkZW50aWZ5IHlvdXIgbmFtZShzKSBhcyB0aGUgYXV0aG9yKHMpIG9yIG93bmVyKHMpIG9mIHRoZQpzdWJtaXNzaW9uLCBhbmQgd2lsbCBub3QgbWFrZSBhbnkgYWx0ZXJhdGlvbiwgb3RoZXIgdGhhbiBhcyBhbGxvd2VkIGJ5IHRoaXMKbGljZW5zZSwgdG8geW91ciBzdWJtaXNzaW9uLgo= |