Design of two-dimensional perovskite solar cells with superior efficiency and stability
ABSTRACT : Pervskite solar cells have attracted extensive attention from researchers worldwide due to their rapid development and efficiency. Nevertheless, stability is still an issue that limits the advance of this technology. In this work, we present the fabrication and characterization of two-dim...
- Autores:
-
Ramírez Zora, Daniel Estiben
Jaramillo Isaza, Franklin
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2021
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/24968
- Acceso en línea:
- http://hdl.handle.net/10495/24968
https://revistas.udea.edu.co/index.php/ingenieria/article/view/344428
- Palabra clave:
- Estabilidad
Stability
Cationes
Cations
Energía solar
Solar energy
Perovskitas de haluro metal bidimensionales
Celdas solares
ationes orgánicos
http://aims.fao.org/aos/agrovoc/c_36930
http://aims.fao.org/aos/agrovoc/c_16169
http://aims.fao.org/aos/agrovoc/c_7222
- Rights
- openAccess
- License
- https://creativecommons.org/licenses/by-nc-sa/4.0/
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| dc.title.spa.fl_str_mv |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| dc.title.translated.spa.fl_str_mv |
Diseño de celdas solares de perovskitas bidimensionales con eficiencia y estabilidad mejorada |
| title |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| spellingShingle |
Design of two-dimensional perovskite solar cells with superior efficiency and stability Estabilidad Stability Cationes Cations Energía solar Solar energy Perovskitas de haluro metal bidimensionales Celdas solares ationes orgánicos http://aims.fao.org/aos/agrovoc/c_36930 http://aims.fao.org/aos/agrovoc/c_16169 http://aims.fao.org/aos/agrovoc/c_7222 |
| title_short |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| title_full |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| title_fullStr |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| title_full_unstemmed |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| title_sort |
Design of two-dimensional perovskite solar cells with superior efficiency and stability |
| dc.creator.fl_str_mv |
Ramírez Zora, Daniel Estiben Jaramillo Isaza, Franklin |
| dc.contributor.author.none.fl_str_mv |
Ramírez Zora, Daniel Estiben Jaramillo Isaza, Franklin |
| dc.contributor.researchgroup.spa.fl_str_mv |
Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT) |
| dc.subject.agrovoc.none.fl_str_mv |
Estabilidad Stability Cationes Cations Energía solar Solar energy |
| topic |
Estabilidad Stability Cationes Cations Energía solar Solar energy Perovskitas de haluro metal bidimensionales Celdas solares ationes orgánicos http://aims.fao.org/aos/agrovoc/c_36930 http://aims.fao.org/aos/agrovoc/c_16169 http://aims.fao.org/aos/agrovoc/c_7222 |
| dc.subject.proposal.spa.fl_str_mv |
Perovskitas de haluro metal bidimensionales Celdas solares ationes orgánicos |
| dc.subject.agrovocuri.none.fl_str_mv |
http://aims.fao.org/aos/agrovoc/c_36930 http://aims.fao.org/aos/agrovoc/c_16169 http://aims.fao.org/aos/agrovoc/c_7222 |
| description |
ABSTRACT : Pervskite solar cells have attracted extensive attention from researchers worldwide due to their rapid development and efficiency. Nevertheless, stability is still an issue that limits the advance of this technology. In this work, we present the fabrication and characterization of two-dimensional perovskites of the Ruddlesden-Popper’s family (A)2(MA)n−1PbnI3n+1 (three different A-site large cations were investigated: A=n-propylammonium, t-Butylammonium or Benzylammonium). The modulation of the large organic cations increased the band gap of the materials and improved moisture and thermal stability, making it possible to fabricate PSCs. Even though the organic interlayers intrinsically reduce the transport properties of the devices and therefore lower currents are obtained in the layered systems, a remarkable efficiency of 10.35% was obtained for (BUA)2(MA)2Pb3I10, with superior stability, and therefore, it was possible to retain 68% of its initial value after 1700 h for devices without encapsulation. |
| publishDate |
2021 |
| dc.date.accessioned.none.fl_str_mv |
2021-12-10T21:57:36Z |
| dc.date.available.none.fl_str_mv |
2021-12-10T21:57:36Z |
| dc.date.issued.none.fl_str_mv |
2021 |
| dc.type.spa.fl_str_mv |
Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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https://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
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Ramírez D. and Jaramillo F., “Design of two-dimensional perovskite solar cells with superior efficiency and stability”, Rev.Fac.Ing.Univ.Antioquia, no. 100, pp. 67-74, Apr. 2021. |
| dc.identifier.issn.none.fl_str_mv |
0120-6230 |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10495/24968 |
| dc.identifier.doi.none.fl_str_mv |
10.17533/udea.redin.20210424 |
| dc.identifier.eissn.none.fl_str_mv |
2422-2844 |
| dc.identifier.url.spa.fl_str_mv |
https://revistas.udea.edu.co/index.php/ingenieria/article/view/344428 |
| identifier_str_mv |
Ramírez D. and Jaramillo F., “Design of two-dimensional perovskite solar cells with superior efficiency and stability”, Rev.Fac.Ing.Univ.Antioquia, no. 100, pp. 67-74, Apr. 2021. 0120-6230 10.17533/udea.redin.20210424 2422-2844 |
| url |
http://hdl.handle.net/10495/24968 https://revistas.udea.edu.co/index.php/ingenieria/article/view/344428 |
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eng |
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eng |
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Rev. Fac. Ing. Univ. Antioquia |
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74 |
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100 |
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67 |
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Revista Facultad de Ingeniería Universidad de Antioquia |
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Medellín, Colombia |
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Ramírez Zora, Daniel EstibenJaramillo Isaza, FranklinCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)2021-12-10T21:57:36Z2021-12-10T21:57:36Z2021Ramírez D. and Jaramillo F., “Design of two-dimensional perovskite solar cells with superior efficiency and stability”, Rev.Fac.Ing.Univ.Antioquia, no. 100, pp. 67-74, Apr. 2021.0120-6230http://hdl.handle.net/10495/2496810.17533/udea.redin.202104242422-2844https://revistas.udea.edu.co/index.php/ingenieria/article/view/344428ABSTRACT : Pervskite solar cells have attracted extensive attention from researchers worldwide due to their rapid development and efficiency. Nevertheless, stability is still an issue that limits the advance of this technology. In this work, we present the fabrication and characterization of two-dimensional perovskites of the Ruddlesden-Popper’s family (A)2(MA)n−1PbnI3n+1 (three different A-site large cations were investigated: A=n-propylammonium, t-Butylammonium or Benzylammonium). The modulation of the large organic cations increased the band gap of the materials and improved moisture and thermal stability, making it possible to fabricate PSCs. Even though the organic interlayers intrinsically reduce the transport properties of the devices and therefore lower currents are obtained in the layered systems, a remarkable efficiency of 10.35% was obtained for (BUA)2(MA)2Pb3I10, with superior stability, and therefore, it was possible to retain 68% of its initial value after 1700 h for devices without encapsulation.RESUMEN : Las celdas solares de Perovskita han atraído la atención de la comunidad científica en los últimos años debido a los avances significativos en su eficiencia. Sin embargo, su estabilidad es todavía un problema que limita el avance de esta tecnología. En este trabajo se presenta la fabricación y caracterización de pervoskitas bidimiensionales pertenecientes a la familia Ruddlesden-Poppery (A)2(MA)n−1PbnI3n+1 (se estudiaron 3 cationes grandes en la posición A: n-propilamonio, t-Butilamonio o Bencilamonio). La modulación de estos cationes que promueven la formación de una estructura bidimensional, generó un incremento en el bandgap de los materiales, así como una mejora en su estabilidad térmica y a la humedad. Aunque naturalmente la introducción de estos cationes genera una disminución en las propiedades de transporte, reduciendo la corriente de los dispositivos, se lograron obtener dispositivos con eficiencias de 10,35% para (BUA)2(MA)2Pb3I10, que, presentando una estabilidad mejorada, lograron retener el 68% de valor inicial luego de 1700h sin encapsulamiento.COL00079278application/pdfengUniversidad de Antioquia, Facultad de IngenieríaMedellín, Colombiahttps://creativecommons.org/licenses/by-nc-sa/4.0/http://creativecommons.org/licenses/by-nc-sa/2.5/co/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Design of two-dimensional perovskite solar cells with superior efficiency and stabilityDiseño de celdas solares de perovskitas bidimensionales con eficiencia y estabilidad mejoradaArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionEstabilidadStabilityCationesCationsEnergía solarSolar energyPerovskitas de haluro metal bidimensionalesCeldas solaresationes orgánicoshttp://aims.fao.org/aos/agrovoc/c_36930http://aims.fao.org/aos/agrovoc/c_16169http://aims.fao.org/aos/agrovoc/c_7222Rev. Fac. Ing. Univ. 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