Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air

ABSTRACT: In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The efect of copper addition on the FeSiBP base alloy was studied in the system (Fe0.77Si0.08B0.1P0.05)100-xCux with x=0, 0.25, 0.5, 0.75...

Full description

Autores:
Perea Cabarcas, Darling
Echeverría Echeverría, Félix
Bolívar Osorio, Francisco Javier
Parra Vargas, Carlos Arturo
Tipo de recurso:
Article of investigation
Fecha de publicación:
2023
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/39821
Acceso en línea:
https://hdl.handle.net/10495/39821
Palabra clave:
Metallic glasses
Aleaciones magnéticas
Magnetic alloys
Materiales magnéticos
Magnetic materials
Vidrio
Glass
Propiedades magnéticas
Magnetics properties
http://id.loc.gov/authorities/subjects/sh85084121
Rights
openAccess
License
http://creativecommons.org/licenses/by/2.5/co/
id UDEA2_5f47cfb149db5ea669c4e3d8caedce93
oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/39821
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
title Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
spellingShingle Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
Metallic glasses
Aleaciones magnéticas
Magnetic alloys
Materiales magnéticos
Magnetic materials
Vidrio
Glass
Propiedades magnéticas
Magnetics properties
http://id.loc.gov/authorities/subjects/sh85084121
title_short Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
title_full Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
title_fullStr Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
title_full_unstemmed Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
title_sort Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air
dc.creator.fl_str_mv Perea Cabarcas, Darling
Echeverría Echeverría, Félix
Bolívar Osorio, Francisco Javier
Parra Vargas, Carlos Arturo
dc.contributor.author.none.fl_str_mv Perea Cabarcas, Darling
Echeverría Echeverría, Félix
Bolívar Osorio, Francisco Javier
Parra Vargas, Carlos Arturo
dc.contributor.researchgroup.spa.fl_str_mv Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)
dc.subject.lcsh.none.fl_str_mv Metallic glasses
topic Metallic glasses
Aleaciones magnéticas
Magnetic alloys
Materiales magnéticos
Magnetic materials
Vidrio
Glass
Propiedades magnéticas
Magnetics properties
http://id.loc.gov/authorities/subjects/sh85084121
dc.subject.lemb.none.fl_str_mv Aleaciones magnéticas
Magnetic alloys
Materiales magnéticos
Magnetic materials
Vidrio
Glass
Propiedades magnéticas
Magnetics properties
dc.subject.lcshuri.none.fl_str_mv http://id.loc.gov/authorities/subjects/sh85084121
description ABSTRACT: In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The efect of copper addition on the FeSiBP base alloy was studied in the system (Fe0.77Si0.08B0.1P0.05)100-xCux with x=0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe2B and Fe3(B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the frst crystallization event were calculated using the Kissinger method. The research fndings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance.
publishDate 2023
dc.date.issued.none.fl_str_mv 2023
dc.date.accessioned.none.fl_str_mv 2024-06-09T16:06:06Z
dc.date.available.none.fl_str_mv 2024-06-09T16:06:06Z
dc.type.spa.fl_str_mv Artículo de investigación
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.redcol.spa.fl_str_mv https://purl.org/redcol/resource_type/ART
dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/publishedVersion
format http://purl.org/coar/resource_type/c_2df8fbb1
status_str publishedVersion
dc.identifier.citation.spa.fl_str_mv Perea C., Darling & Vargas, C. & Echeverría, F. & Osorio, F.. (2023). Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air. Journal of Materials Research. 38. 10.1557/s43578-023-01055-0. In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The effect of copper addition on the FeSiBP base alloy was studied in the system (Fe 0.77 Si 0.08 B 0.1 P 0.05 ) 100-x Cu x with x = 0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe 2 B and Fe 3 (B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the first crystallization event were calculated using the Kissinger method. The research findings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance. Graphical abstract
dc.identifier.issn.none.fl_str_mv 0884-2914
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/10495/39821
dc.identifier.doi.none.fl_str_mv 10.1557/s43578-023-01055-0
dc.identifier.eissn.none.fl_str_mv 2044-5326
identifier_str_mv Perea C., Darling & Vargas, C. & Echeverría, F. & Osorio, F.. (2023). Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air. Journal of Materials Research. 38. 10.1557/s43578-023-01055-0. In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The effect of copper addition on the FeSiBP base alloy was studied in the system (Fe 0.77 Si 0.08 B 0.1 P 0.05 ) 100-x Cu x with x = 0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe 2 B and Fe 3 (B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the first crystallization event were calculated using the Kissinger method. The research findings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance. Graphical abstract
0884-2914
10.1557/s43578-023-01055-0
2044-5326
url https://hdl.handle.net/10495/39821
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv J. Mater. Res.
dc.relation.citationendpage.spa.fl_str_mv 9
dc.relation.citationissue.spa.fl_str_mv 14
dc.relation.citationstartpage.spa.fl_str_mv 1
dc.relation.citationvolume.spa.fl_str_mv 38
dc.relation.ispartofjournal.spa.fl_str_mv Journal of Materials Research
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by/2.5/co/
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
dc.rights.accessrights.spa.fl_str_mv info:eu-repo/semantics/openAccess
dc.rights.coar.spa.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv http://creativecommons.org/licenses/by/2.5/co/
https://creativecommons.org/licenses/by/4.0/
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.extent.spa.fl_str_mv 9 páginas
dc.format.mimetype.spa.fl_str_mv application/pdf
dc.publisher.spa.fl_str_mv Springer
dc.publisher.place.spa.fl_str_mv Nueva York, Estados Unidos
institution Universidad de Antioquia
bitstream.url.fl_str_mv https://bibliotecadigital.udea.edu.co/bitstreams/27eb149b-d86e-4533-b9fc-916d0cfafb95/download
https://bibliotecadigital.udea.edu.co/bitstreams/c21695e2-05dc-4cec-a5a7-caf2c36b5d29/download
https://bibliotecadigital.udea.edu.co/bitstreams/26cf5213-7bd6-4bf8-ba6b-7a82692e937d/download
https://bibliotecadigital.udea.edu.co/bitstreams/c484f551-0bb4-48c6-b2cd-1baad40ef5e5/download
https://bibliotecadigital.udea.edu.co/bitstreams/6b7c5f52-ce26-44fa-8c59-7103d8c70803/download
bitstream.checksum.fl_str_mv 04cf774c5b990923ea0ce79cb333ccc8
1646d1f6b96dbbbc38035efc9239ac9c
8a4605be74aa9ea9d79846c1fba20a33
642cf875f897e35c6469f273007bf8fa
0ad469d65f9f1a63e3d1068bdbf885c2
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositorio Institucional de la Universidad de Antioquia
repository.mail.fl_str_mv aplicacionbibliotecadigitalbiblioteca@udea.edu.co
_version_ 1851052223500386304
spelling Perea Cabarcas, DarlingEcheverría Echeverría, FélixBolívar Osorio, Francisco JavierParra Vargas, Carlos ArturoCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)2024-06-09T16:06:06Z2024-06-09T16:06:06Z2023Perea C., Darling & Vargas, C. & Echeverría, F. & Osorio, F.. (2023). Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in air. Journal of Materials Research. 38. 10.1557/s43578-023-01055-0. In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The effect of copper addition on the FeSiBP base alloy was studied in the system (Fe 0.77 Si 0.08 B 0.1 P 0.05 ) 100-x Cu x with x = 0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe 2 B and Fe 3 (B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the first crystallization event were calculated using the Kissinger method. The research findings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance. Graphical abstract0884-2914https://hdl.handle.net/10495/3982110.1557/s43578-023-01055-02044-5326ABSTRACT: In the current work, a new variation of the FeSiBPCu system with good glass forming ability and soft magnetic properties was developed and investigated. The efect of copper addition on the FeSiBP base alloy was studied in the system (Fe0.77Si0.08B0.1P0.05)100-xCux with x=0, 0.25, 0.5, 0.75 and 1.0 at%. Microstructural evolution upon the annealing process was evaluated by XRD and TEM, revealing the formation of α-Fe(Si), Fe2B and Fe3(B,P) crystalline phases. VSM allowed to determine that the combination of chemical composition and microstructure with the best soft magnetic properties after the annealing corresponds with the alloy with 0.75% Cu. In addition, activation energy for glass transition and the frst crystallization event were calculated using the Kissinger method. The research fndings demonstrated that maintaining the relationship between the main elements, it is possible to keep the good glass forming ability with the possibility of developing a nanocrystalline structure with soft magnetic performance.COL00079279 páginasapplication/pdfengSpringerNueva York, Estados Unidoshttp://creativecommons.org/licenses/by/2.5/co/https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Metallic glassesAleaciones magnéticasMagnetic alloysMateriales magnéticosMagnetic materialsVidrioGlassPropiedades magnéticasMagnetics propertieshttp://id.loc.gov/authorities/subjects/sh85084121Phase transformation, thermal behavior, and magnetic study of new (FeSiBP)100-XCuX glassy alloys obtained by melt-spinning in airArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionJ. Mater. Res.914138Journal of Materials ResearchPublicationORIGINALPereaDarling_2023_PhaseTransformationThermal.pdfPereaDarling_2023_PhaseTransformationThermal.pdfArtículo de investigaciónapplication/pdf2769727https://bibliotecadigital.udea.edu.co/bitstreams/27eb149b-d86e-4533-b9fc-916d0cfafb95/download04cf774c5b990923ea0ce79cb333ccc8MD51trueAnonymousREADCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8927https://bibliotecadigital.udea.edu.co/bitstreams/c21695e2-05dc-4cec-a5a7-caf2c36b5d29/download1646d1f6b96dbbbc38035efc9239ac9cMD52falseAnonymousREADLICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://bibliotecadigital.udea.edu.co/bitstreams/26cf5213-7bd6-4bf8-ba6b-7a82692e937d/download8a4605be74aa9ea9d79846c1fba20a33MD53falseAnonymousREADTEXTPereaDarling_2023_PhaseTransformationThermal.pdf.txtPereaDarling_2023_PhaseTransformationThermal.pdf.txtExtracted texttext/plain32589https://bibliotecadigital.udea.edu.co/bitstreams/c484f551-0bb4-48c6-b2cd-1baad40ef5e5/download642cf875f897e35c6469f273007bf8faMD54falseAnonymousREADTHUMBNAILPereaDarling_2023_PhaseTransformationThermal.pdf.jpgPereaDarling_2023_PhaseTransformationThermal.pdf.jpgGenerated Thumbnailimage/jpeg15222https://bibliotecadigital.udea.edu.co/bitstreams/6b7c5f52-ce26-44fa-8c59-7103d8c70803/download0ad469d65f9f1a63e3d1068bdbf885c2MD55falseAnonymousREAD10495/39821oai:bibliotecadigital.udea.edu.co:10495/398212025-03-26 18:53:12.276http://creativecommons.org/licenses/by/2.5/co/open.accesshttps://bibliotecadigital.udea.edu.coRepositorio Institucional de la Universidad de Antioquiaaplicacionbibliotecadigitalbiblioteca@udea.edu.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