Synthesis of 5-phenyl-1,8-naphthalic anhydrides: An exercise in acenaphthene chemistry

ABSTRACT: The synthesis of phenylnaphthalic anhydrides, including substitution patterns typically found in the Haemodoraceae and Pontederiacea family of plants, was explored using Suzuki and Ullmann-type aromatic substitutions on acenaphthene. Synthetic challenges were surmounted by tactical changes...

Full description

Autores:
Prieto Mesa, Ana María
Otálvaro Tamayo, Felipe
Paetz, Christian
Schneider, Bernd
Tipo de recurso:
Article of investigation
Fecha de publicación:
2024
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/37988
Acceso en línea:
https://hdl.handle.net/10495/37988
Palabra clave:
Phenylnaphthalic anhydrides
Acenaphthene chemistry
Suzuki coupling
Ullman-type substitution
Rights
openAccess
License
http://creativecommons.org/licenses/by-nc-nd/2.5/co/
Description
Summary:ABSTRACT: The synthesis of phenylnaphthalic anhydrides, including substitution patterns typically found in the Haemodoraceae and Pontederiacea family of plants, was explored using Suzuki and Ullmann-type aromatic substitutions on acenaphthene. Synthetic challenges were surmounted by tactical changes to determine the order of events.