An X-ray diffraction study of corrosion products from low carbon steel

ABSTRACT: It was found in earlier work a decrease in the corrosion rate from low carbon steel when it was subjected to the action of a combined pollutant concentration (S04^~ = 10"^ M + Cl" = 1.5 X 10~^ M). It was also found that large magnetite content of the rust was related to higher co...

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Autores:
Morales Aramburo, Álvaro Luis
Tipo de recurso:
Article of investigation
Fecha de publicación:
2003
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/27113
Acceso en línea:
http://hdl.handle.net/10495/27113
Palabra clave:
Difracción de rayos X
X-rays - diffraction
Acero
Steel
Espectroscopía de Mossbauer
Mossbauer spectroscopy
Iones
Ions
Sulfatos
Sulphates
Corrosión
Corrosion
Cloruro
http://aims.fao.org/aos/agrovoc/c_24011
Rights
openAccess
License
http://creativecommons.org/licenses/by/2.5/co/
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oai_identifier_str oai:bibliotecadigital.udea.edu.co:10495/27113
network_acronym_str UDEA2
network_name_str Repositorio UdeA
repository_id_str
dc.title.spa.fl_str_mv An X-ray diffraction study of corrosion products from low carbon steel
dc.title.translated.spa.fl_str_mv Estudio por difracción de rayos X de los productos de corrosión del acero al carbono
title An X-ray diffraction study of corrosion products from low carbon steel
spellingShingle An X-ray diffraction study of corrosion products from low carbon steel
Difracción de rayos X
X-rays - diffraction
Acero
Steel
Espectroscopía de Mossbauer
Mossbauer spectroscopy
Iones
Ions
Sulfatos
Sulphates
Corrosión
Corrosion
Cloruro
http://aims.fao.org/aos/agrovoc/c_24011
title_short An X-ray diffraction study of corrosion products from low carbon steel
title_full An X-ray diffraction study of corrosion products from low carbon steel
title_fullStr An X-ray diffraction study of corrosion products from low carbon steel
title_full_unstemmed An X-ray diffraction study of corrosion products from low carbon steel
title_sort An X-ray diffraction study of corrosion products from low carbon steel
dc.creator.fl_str_mv Morales Aramburo, Álvaro Luis
dc.contributor.author.none.fl_str_mv Morales Aramburo, Álvaro Luis
dc.contributor.researchgroup.spa.fl_str_mv Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)
dc.subject.lemb.none.fl_str_mv Difracción de rayos X
X-rays - diffraction
Acero
Steel
Espectroscopía de Mossbauer
Mossbauer spectroscopy
Iones
Ions
Sulfatos
Sulphates
topic Difracción de rayos X
X-rays - diffraction
Acero
Steel
Espectroscopía de Mossbauer
Mossbauer spectroscopy
Iones
Ions
Sulfatos
Sulphates
Corrosión
Corrosion
Cloruro
http://aims.fao.org/aos/agrovoc/c_24011
dc.subject.agrovoc.none.fl_str_mv Corrosión
Corrosion
dc.subject.proposal.spa.fl_str_mv Cloruro
dc.subject.agrovocuri.none.fl_str_mv http://aims.fao.org/aos/agrovoc/c_24011
description ABSTRACT: It was found in earlier work a decrease in the corrosion rate from low carbon steel when it was subjected to the action of a combined pollutant concentration (S04^~ = 10"^ M + Cl" = 1.5 X 10~^ M). It was also found that large magnetite content of the rust was related to higher corrosion rates. In the present study corrosion products are further analyzed by means of X-ray diffraction to account for composition changes during the corrosion process. It is found that lepidocrocite and goethite are the dominant components for the short-term corrosion in all batches considered while for log-term corrosion lepidocrite and goethite dominates if the corrosion rate is low and magnetite dominates if the corrosion rate is high. The mechanism for decreasing the corrosion rate is related to the inhibition of magnetite production at this particular concentration.
publishDate 2003
dc.date.issued.none.fl_str_mv 2003
dc.date.accessioned.none.fl_str_mv 2022-03-29T20:48:53Z
dc.date.available.none.fl_str_mv 2022-03-29T20:48:53Z
dc.type.spa.fl_str_mv Artículo de investigación
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
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dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
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dc.identifier.issn.none.fl_str_mv 0034-8570
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/27113
dc.identifier.doi.none.fl_str_mv 10.3989/revmetalm.2003.v39.iExtra.1092
dc.identifier.eissn.none.fl_str_mv 1988-4222
identifier_str_mv 0034-8570
10.3989/revmetalm.2003.v39.iExtra.1092
1988-4222
url http://hdl.handle.net/10495/27113
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Rev. Metal.
dc.relation.citationendpage.spa.fl_str_mv 31
dc.relation.citationissue.spa.fl_str_mv Extra
dc.relation.citationstartpage.spa.fl_str_mv 28
dc.relation.citationvolume.spa.fl_str_mv 39
dc.relation.ispartofjournal.spa.fl_str_mv Revista de Metalurgia
dc.rights.uri.*.fl_str_mv http://creativecommons.org/licenses/by/2.5/co/
dc.rights.uri.spa.fl_str_mv https://creativecommons.org/licenses/by/4.0/
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dc.publisher.spa.fl_str_mv Consejo Superior de Investigaciones Científicas; Centro Nacional de Investigaciones Metalúrgicas
dc.publisher.place.spa.fl_str_mv Madrid, España
institution Universidad de Antioquia
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spelling Morales Aramburo, Álvaro LuisCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)2022-03-29T20:48:53Z2022-03-29T20:48:53Z20030034-8570http://hdl.handle.net/10495/2711310.3989/revmetalm.2003.v39.iExtra.10921988-4222ABSTRACT: It was found in earlier work a decrease in the corrosion rate from low carbon steel when it was subjected to the action of a combined pollutant concentration (S04^~ = 10"^ M + Cl" = 1.5 X 10~^ M). It was also found that large magnetite content of the rust was related to higher corrosion rates. In the present study corrosion products are further analyzed by means of X-ray diffraction to account for composition changes during the corrosion process. It is found that lepidocrocite and goethite are the dominant components for the short-term corrosion in all batches considered while for log-term corrosion lepidocrite and goethite dominates if the corrosion rate is low and magnetite dominates if the corrosion rate is high. The mechanism for decreasing the corrosion rate is related to the inhibition of magnetite production at this particular concentration.RESUMEN: En un estudio anterior se encontró que la tasa de corrosión, de un acero al carbono, decrecía cuando se le sometía al efecto combinado de una mezcla de contaminantes (SO4-2 = 10-4 M + Cl- = 1,5 x 10-3 M). También, se concluyó que altos contenidos de magnetita en la herrumbre estaban asociados a altas tasas de corrosión. En este trabajo se retoman estas herrumbres para analizarlas por difractometría de rayos X para tomar en cuenta los cambios en composición durante el proceso corrosivo. Se encuentra que goethita y lepidocrocita son las componentes dominantes durante la etapa inicial del proceso en todos los experimentos. En cambio para tiempos largos de exposición, y si la tasa de corrosión es alta, la magnetita es el producto de corrosión dominante. El mecanismo que reduce la tasa de corrosión, en la mezcla mencionada anteriormente, está relacionado con la inhibición del proceso de producción de la magnetita en estas condiciones.COL00996984application/pdfengConsejo Superior de Investigaciones Científicas; Centro Nacional de Investigaciones MetalúrgicasMadrid, Españahttp://creativecommons.org/licenses/by/2.5/co/https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2An X-ray diffraction study of corrosion products from low carbon steelEstudio por difracción de rayos X de los productos de corrosión del acero al carbonoArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionDifracción de rayos XX-rays - diffractionAceroSteelEspectroscopía de MossbauerMossbauer spectroscopyIonesIonsSulfatosSulphatesCorrosiónCorrosionClorurohttp://aims.fao.org/aos/agrovoc/c_24011Rev. 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