Mineralization enhancement of a recalcitrant pharmaceutical pollutant in water by advanced oxidation hybrid processes

ABSTRACT: Degradation of the biorecalcitrant pharmaceutical micropollutant ibuprofen (IBP) was carried out by means of several advanced oxidation hybrid configurations. TiO2 photocatalysis, photo-Fenton and sonolysis – all of them under solar simulated illumination – were tested in the hybrid systems: sonophoto-Fenton (FS), sonophotocatalysis (TS) and TiO2/Fe2+/sonolysis (TFS). In the case of the sonophoto-Fenton process, the IBP degradation (95%) and mineralization (60%) were attained with photo-Fenton (FH). The presence of ultrasonic irradiation slightly improves the iron catalytic activity. On the other hand, total removal of IBP and elimination of more than 50% of dissolved organic carbon (DOC) were observed by photocatalysis with TiO2 in the presence of ultrasound irradiation (TS). In contrast only 26% of mineralization was observed by photocatalysis with H2O2 (TH) in the absence of ultrasound irradiation. Additional results showed that, in the TFS system, 92% of DOC removal and complete degradation of IBP were obtained within 240 min of treatment. The advanced oxidation hybrid systems seems to be a promising alternative for full elimination/mineralization for the recalcitrant micro-contaminant IBP.

• Autores: Méndez Arriaga, Fabiola; Pétrier, Christian; Pulgarín, César; Esplugas, Santiago; Gimenez, Jaime
• Tipo de recurso: Article of investigation
• Fecha de publicación: 2009
• Institución: Universidad de Antioquia
• Repositorio: Repositorio UdeA
• Idioma: eng
• OAI Identifier: oai:bibliotecadigital.udea.edu.co:10495/11906
• Acceso en línea: http://hdl.handle.net/10495/11906
• Palabra clave: Oxidación; Ibuprofeno; Advanced oxidation process; Hybrid systems; Photo-Fenton; Sonolysis; TiO2
• Rights: openAccess
• License: http://creativecommons.org/licenses/by-nc-nd/2.5/co/