Electrochemical assessment of magnetite anticorrosive paints

With the purpose of deepening in the understanding of the mechanisms of protection of anticorrosive pigments based on iron oxides, this work has been carried out on the production of pure magnetite, and copper and chromium doped magnetite, which were evaluated by different characterization technique...

Full description

Autores:
Escobar Sierra, Diana Marcela
Arroyave Posada, Carlos Enrique
Jaramillo Isaza, Franklin
Calderón Gutiérrez, Jorge Andrés
Rosa Mattos, Oscar
Pereira Margarit, Isabel Cristina
Tipo de recurso:
Article of investigation
Fecha de publicación:
2003
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/46586
Acceso en línea:
https://hdl.handle.net/10495/46586
Palabra clave:
Magnetita
Magnetite
Hematita
Hematite
Corrosión y anticorrosivos
Corrosion and anti-corrosives
Permeabilidad
Permeability
Permeability
Impedancia
Impedance
http://aims.fao.org/aos/agrovoc/c_3f2b6d3f
http://id.loc.gov/authorities/subjects/sh85079771
http://id.loc.gov/authorities/subjects/sh85060122
ODS 9: Industria, innovación e infraestructura. Construir infraestructuras resilientes, promover la industrialización inclusiva y sostenible y fomentar la innovación
Rights
openAccess
License
http://creativecommons.org/licenses/by-nc/4.0/
Description
Summary:With the purpose of deepening in the understanding of the mechanisms of protection of anticorrosive pigments based on iron oxides, this work has been carried out on the production of pure magnetite, and copper and chromium doped magnetite, which were evaluated by different characterization techniques. The paints were prepared with a solvent less epoxy resin maintaining the Pigment Volume Content near the Practical Critical value (CPVC), established for each pigment. The paints were applied on polished steel and monitored with electrochemical techniques at total immersion conditions. Permeability and impedance measurements of free films were also done. Impedance data were simulated with the Boukamp software. Results show that the paints pigmented with doped magnetite present better behavior than a paint prepared with commercial hematite.