Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications
ABSTRACT: Magnesium’s high storage capacity, with a theoretical value of about 7.6 wt.%, makes it a via- ble candidate for hydrogen storage. However, slow kinetics and strong thermodynamic stability lead to a rather high desorption temperature, usually above 350 °C. It has been demonstrated that nan...
- Autores:
-
Aguirre Ocampo, Robinson
Arias Velandia, Julián
Lenis Rodas, Julián Andrés
Bolívar Osorio, Francisco Javier
Echeverría Echeverría, Félix
Correa, Esteban
Zuleta Gil, Alejandro Alberto
Bello, Sindy
Arrieta, Carlos
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2025
- Institución:
- Universidad de Antioquia
- Repositorio:
- Repositorio UdeA
- Idioma:
- eng
- OAI Identifier:
- oai:bibliotecadigital.udea.edu.co:10495/45121
- Acceso en línea:
- https://hdl.handle.net/10495/45121
- Palabra clave:
- Nanopartículas
Nanoparticles
Microondas
Microwaves
Magnesium hydride
Hydrogen storage
Particle synthesis
https://id.nlm.nih.gov/mesh/D053758
https://id.nlm.nih.gov/mesh/D008872
- Rights
- openAccess
- License
- https://creativecommons.org/licenses/by/4.0/
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| dc.title.spa.fl_str_mv |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| title |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| spellingShingle |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications Nanopartículas Nanoparticles Microondas Microwaves Magnesium hydride Hydrogen storage Particle synthesis https://id.nlm.nih.gov/mesh/D053758 https://id.nlm.nih.gov/mesh/D008872 |
| title_short |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| title_full |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| title_fullStr |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| title_full_unstemmed |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| title_sort |
Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applications |
| dc.creator.fl_str_mv |
Aguirre Ocampo, Robinson Arias Velandia, Julián Lenis Rodas, Julián Andrés Bolívar Osorio, Francisco Javier Echeverría Echeverría, Félix Correa, Esteban Zuleta Gil, Alejandro Alberto Bello, Sindy Arrieta, Carlos |
| dc.contributor.author.none.fl_str_mv |
Aguirre Ocampo, Robinson Arias Velandia, Julián Lenis Rodas, Julián Andrés Bolívar Osorio, Francisco Javier Echeverría Echeverría, Félix Correa, Esteban Zuleta Gil, Alejandro Alberto Bello, Sindy Arrieta, Carlos |
| dc.contributor.researchgroup.spa.fl_str_mv |
Centro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT) |
| dc.subject.decs.none.fl_str_mv |
Nanopartículas Nanoparticles Microondas Microwaves |
| topic |
Nanopartículas Nanoparticles Microondas Microwaves Magnesium hydride Hydrogen storage Particle synthesis https://id.nlm.nih.gov/mesh/D053758 https://id.nlm.nih.gov/mesh/D008872 |
| dc.subject.proposal.spa.fl_str_mv |
Magnesium hydride Hydrogen storage Particle synthesis |
| dc.subject.meshuri.none.fl_str_mv |
https://id.nlm.nih.gov/mesh/D053758 https://id.nlm.nih.gov/mesh/D008872 |
| description |
ABSTRACT: Magnesium’s high storage capacity, with a theoretical value of about 7.6 wt.%, makes it a via- ble candidate for hydrogen storage. However, slow kinetics and strong thermodynamic stability lead to a rather high desorption temperature, usually above 350 °C. It has been demonstrated that nanosizing magnesium-based materials is a successful strategy for simultaneously improving the kinetic and ther- modynamic characteristics of MgH2 during hydrogen absorption and desorption. MgH2 nanoparticles were obtained by microwave assisted synthesis. To the best of our knowledge, synthesis of MgH2 nanoparticles by this method has not been reported. It was possible to produce MgH2 nanoparticles smaller than 20 nm. MgO and Mg(OH)2 were also present in the produced nanoparticles, although these compounds may enhance the processes involved in the release and absorption of hydrogen. |
| publishDate |
2025 |
| dc.date.accessioned.none.fl_str_mv |
2025-02-21T17:01:33Z |
| dc.date.available.none.fl_str_mv |
2025-02-21T17:01:33Z |
| dc.date.issued.none.fl_str_mv |
2025 |
| dc.type.spa.fl_str_mv |
Artículo de investigación |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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https://purl.org/redcol/resource_type/ART |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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| dc.identifier.citation.spa.fl_str_mv |
Ocampo, R.A., Arias-Velandia, J., Lenis, J.A. et al. Microwave-assisted synthesis of MgH2 nanoparticles for hydrogen storage applications. J Nanopart Res 27, 52 (2025). https://doi.org/10.1007/s11051-025-06217-1 |
| dc.identifier.issn.none.fl_str_mv |
1388-0764 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/10495/45121 |
| dc.identifier.doi.none.fl_str_mv |
10.1007/s11051-025-06217-1 |
| dc.identifier.eissn.none.fl_str_mv |
1572-896X |
| identifier_str_mv |
Ocampo, R.A., Arias-Velandia, J., Lenis, J.A. et al. Microwave-assisted synthesis of MgH2 nanoparticles for hydrogen storage applications. J Nanopart Res 27, 52 (2025). https://doi.org/10.1007/s11051-025-06217-1 1388-0764 10.1007/s11051-025-06217-1 1572-896X |
| url |
https://hdl.handle.net/10495/45121 |
| dc.language.iso.spa.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournalabbrev.spa.fl_str_mv |
J. Nanopart. Res. |
| dc.relation.citationendpage.spa.fl_str_mv |
14 |
| dc.relation.citationissue.spa.fl_str_mv |
52 |
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1 |
| dc.relation.citationvolume.spa.fl_str_mv |
27 |
| dc.relation.ispartofjournal.spa.fl_str_mv |
Journal of Nanoparticle Research |
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https://creativecommons.org/licenses/by/4.0/ |
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http://creativecommons.org/licenses/by/2.5/co/ |
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openAccess |
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14 páginas |
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application/pdf |
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Springer |
| dc.publisher.place.spa.fl_str_mv |
Reino Unido |
| institution |
Universidad de Antioquia |
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Aguirre Ocampo, RobinsonArias Velandia, JuliánLenis Rodas, Julián AndrésBolívar Osorio, Francisco JavierEcheverría Echeverría, FélixCorrea, EstebanZuleta Gil, Alejandro AlbertoBello, SindyArrieta, CarlosCentro de Investigación Innovación y Desarrollo de Materiales (CIDEMAT)2025-02-21T17:01:33Z2025-02-21T17:01:33Z2025Ocampo, R.A., Arias-Velandia, J., Lenis, J.A. et al. Microwave-assisted synthesis of MgH2 nanoparticles for hydrogen storage applications. J Nanopart Res 27, 52 (2025). https://doi.org/10.1007/s11051-025-06217-11388-0764https://hdl.handle.net/10495/4512110.1007/s11051-025-06217-11572-896XABSTRACT: Magnesium’s high storage capacity, with a theoretical value of about 7.6 wt.%, makes it a via- ble candidate for hydrogen storage. However, slow kinetics and strong thermodynamic stability lead to a rather high desorption temperature, usually above 350 °C. It has been demonstrated that nanosizing magnesium-based materials is a successful strategy for simultaneously improving the kinetic and ther- modynamic characteristics of MgH2 during hydrogen absorption and desorption. MgH2 nanoparticles were obtained by microwave assisted synthesis. To the best of our knowledge, synthesis of MgH2 nanoparticles by this method has not been reported. It was possible to produce MgH2 nanoparticles smaller than 20 nm. MgO and Mg(OH)2 were also present in the produced nanoparticles, although these compounds may enhance the processes involved in the release and absorption of hydrogen.Universidad de Antioquia. Vicerrectoría de investigación. Comité para el Desarrollo de la Investigación - CODIColombia. Ministerio de Ciencia, Tecnología e Innovación - MinCienciasSistema General de Regalías de ColombiaUniversidad Pontifcia Bolivariana. Centro de Investigación para el Desarrollo de la Innovación - CIDIUniversidad de Medellín. Centro de Investigación en Ingenierías - CEINCOL000792714 páginasapplication/pdfengSpringerReino Unidohttps://creativecommons.org/licenses/by/4.0/http://creativecommons.org/licenses/by/2.5/co/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Microwave‐assisted synthesis of MgH2 nanoparticles for hydrogen storage applicationsArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionNanopartículasNanoparticlesMicroondasMicrowavesMagnesium hydrideHydrogen storageParticle synthesishttps://id.nlm.nih.gov/mesh/D053758https://id.nlm.nih.gov/mesh/D008872J. Nanopart. Res.1452127Journal of Nanoparticle ResearchBPIN 2022000100089UPB 822C06/23-35RoR:03bp5hc83RoR:03fd5ne08RoR:05x7bg352RoR:04vh21716RoR:030kw0b65PublicationLICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://bibliotecadigital.udea.edu.co/bitstreams/ca9aad51-244c-48ff-8b79-9def0c91225a/download8a4605be74aa9ea9d79846c1fba20a33MD53falseAnonymousREADCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8927https://bibliotecadigital.udea.edu.co/bitstreams/66ee03b0-cca1-4cf2-9224-92f990cd3ae9/download1646d1f6b96dbbbc38035efc9239ac9cMD52falseAnonymousREADORIGINALAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdfAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdfArtículo de investigaciónapplication/pdf3439068https://bibliotecadigital.udea.edu.co/bitstreams/21b6e064-51c0-4214-bec7-e75ae893e38a/downloadabccb6cf57590760e5472d741138b8d6MD51trueAnonymousREADTEXTAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdf.txtAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdf.txtExtracted texttext/plain47618https://bibliotecadigital.udea.edu.co/bitstreams/c3f8b38b-f4f2-4eb8-a213-f9621e580d89/downloada0c661a839b9e8c199795ba725ffa818MD54falseAnonymousREADTHUMBNAILAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdf.jpgAguirreRobinson_2025_Synthesis_MgH2_Hydrogen.pdf.jpgGenerated Thumbnailimage/jpeg13714https://bibliotecadigital.udea.edu.co/bitstreams/6b2cb3b4-4818-4bac-9ff6-b76fe033f648/downloadeddb203589681932d0916a1a38cd8c17MD55falseAnonymousREAD10495/45121oai:bibliotecadigital.udea.edu.co:10495/451212025-03-26 20:19:49.669https://creativecommons.org/licenses/by/4.0/open.accesshttps://bibliotecadigital.udea.edu.coRepositorio Institucional de la Universidad de Antioquiaaplicacionbibliotecadigitalbiblioteca@udea.edu.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 |