Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method

ABSTRACT: In this paper the synthesis of the LaBiFe2O6 material by the modified Pechini method is reported. Structural, morphologic, magnetic and optic experimental studies were performed. Rietveld refinement of x-ray diffraction patterns revealed that LaBiFe2O6 crystallizes in an orthorhombic perov...

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Autores:
Jaramillo Palacio, Johny Andrés
Barrera Bello, Elixir William
Munévar Cagigas, Julián Andrés
Arnache Olmos, Oscar Luis
Landínez Téllez, David A.
Roa Rojas, Jairo
Tipo de recurso:
Article of investigation
Fecha de publicación:
2017
Institución:
Universidad de Antioquia
Repositorio:
Repositorio UdeA
Idioma:
eng
OAI Identifier:
oai:bibliotecadigital.udea.edu.co:10495/10968
Acceso en línea:
http://hdl.handle.net/10495/10968
Palabra clave:
Propiedades físicas
Physical Phenomena
Semiconductores
Semiconductors
Método Pechini modificado
Doble perovskita
Ferromagnético
http://aims.fao.org/aos/agrovoc/c_8e15773e
Rights
openAccess
License
https://creativecommons.org/licenses/by-nc-nd/4.0/
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network_name_str Repositorio UdeA
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dc.title.spa.fl_str_mv Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
title Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
spellingShingle Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
Propiedades físicas
Physical Phenomena
Semiconductores
Semiconductors
Método Pechini modificado
Doble perovskita
Ferromagnético
http://aims.fao.org/aos/agrovoc/c_8e15773e
title_short Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
title_full Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
title_fullStr Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
title_full_unstemmed Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
title_sort Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method
dc.creator.fl_str_mv Jaramillo Palacio, Johny Andrés
Barrera Bello, Elixir William
Munévar Cagigas, Julián Andrés
Arnache Olmos, Oscar Luis
Landínez Téllez, David A.
Roa Rojas, Jairo
dc.contributor.author.none.fl_str_mv Jaramillo Palacio, Johny Andrés
Barrera Bello, Elixir William
Munévar Cagigas, Julián Andrés
Arnache Olmos, Oscar Luis
Landínez Téllez, David A.
Roa Rojas, Jairo
dc.contributor.researchgroup.spa.fl_str_mv Grupo Estado Sólido
dc.subject.decs.none.fl_str_mv Propiedades físicas
Physical Phenomena
topic Propiedades físicas
Physical Phenomena
Semiconductores
Semiconductors
Método Pechini modificado
Doble perovskita
Ferromagnético
http://aims.fao.org/aos/agrovoc/c_8e15773e
dc.subject.agrovoc.none.fl_str_mv Semiconductores
Semiconductors
dc.subject.proposal.spa.fl_str_mv Método Pechini modificado
Doble perovskita
Ferromagnético
dc.subject.agrovocuri.none.fl_str_mv http://aims.fao.org/aos/agrovoc/c_8e15773e
description ABSTRACT: In this paper the synthesis of the LaBiFe2O6 material by the modified Pechini method is reported. Structural, morphologic, magnetic and optic experimental studies were performed. Rietveld refinement of x-ray diffraction patterns revealed that LaBiFe2O6 crystallizes in an orthorhombic perovskite structure (space group Pnma, # 62). Scanning electron microscopy images showed the nanometric feature of grains. X-ray dispersive spectroscopy permitted to infer the obtaining of the LaBiFe2O6 expected stoichiometry. Results of magnetic susceptibility as a function of temperature and field magnetization evidenced mixed ferromagnetism and superparamagnetism behavior at T=300 K. Mössbauer spectroscopy supported the superparamagnetic and ferromagnetic responses as a result of the nanogranular morphology and anisotropy effects. Spectrum of diffuse reflectance suggest that this material behaves as a semiconductor with energy gap Eg=2.13 eV.
publishDate 2017
dc.date.issued.none.fl_str_mv 2017
dc.date.accessioned.none.fl_str_mv 2019-05-02T19:37:44Z
dc.date.available.none.fl_str_mv 2019-05-02T19:37:44Z
dc.type.spa.fl_str_mv Artículo de investigación
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dc.identifier.citation.spa.fl_str_mv Jaramillo, J. A., Barrera, E., Munévar, J. A., Arnache, O. L., Landínez, D. A., & Roa, J. (2017). Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method. Materials Research. 20(5), 1309-1316. DOI:10.1590/1980-5373-MR-2017-0290
dc.identifier.issn.none.fl_str_mv 1516-1439
dc.identifier.uri.none.fl_str_mv http://hdl.handle.net/10495/10968
dc.identifier.doi.none.fl_str_mv 10.1590/1980-5373-MR-2017-0290
dc.identifier.eissn.none.fl_str_mv 1980-5373
identifier_str_mv Jaramillo, J. A., Barrera, E., Munévar, J. A., Arnache, O. L., Landínez, D. A., & Roa, J. (2017). Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method. Materials Research. 20(5), 1309-1316. DOI:10.1590/1980-5373-MR-2017-0290
1516-1439
10.1590/1980-5373-MR-2017-0290
1980-5373
url http://hdl.handle.net/10495/10968
dc.language.iso.spa.fl_str_mv eng
language eng
dc.relation.ispartofjournalabbrev.spa.fl_str_mv Mat. Res.
dc.relation.citationendpage.spa.fl_str_mv 1316
dc.relation.citationissue.spa.fl_str_mv 5
dc.relation.citationstartpage.spa.fl_str_mv 1309
dc.relation.citationvolume.spa.fl_str_mv 20
dc.relation.ispartofjournal.spa.fl_str_mv Universidade Federal de São Carlos (UFSCar)
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dc.publisher.spa.fl_str_mv Universidade Federal de São Carlos (UFSCar)
dc.publisher.place.spa.fl_str_mv Brasil
institution Universidad de Antioquia
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spelling Jaramillo Palacio, Johny AndrésBarrera Bello, Elixir WilliamMunévar Cagigas, Julián AndrésArnache Olmos, Oscar LuisLandínez Téllez, David A.Roa Rojas, JairoGrupo Estado Sólido2019-05-02T19:37:44Z2019-05-02T19:37:44Z2017Jaramillo, J. A., Barrera, E., Munévar, J. A., Arnache, O. L., Landínez, D. A., & Roa, J. (2017). Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini Method. Materials Research. 20(5), 1309-1316. DOI:10.1590/1980-5373-MR-2017-02901516-1439http://hdl.handle.net/10495/1096810.1590/1980-5373-MR-2017-02901980-5373ABSTRACT: In this paper the synthesis of the LaBiFe2O6 material by the modified Pechini method is reported. Structural, morphologic, magnetic and optic experimental studies were performed. Rietveld refinement of x-ray diffraction patterns revealed that LaBiFe2O6 crystallizes in an orthorhombic perovskite structure (space group Pnma, # 62). Scanning electron microscopy images showed the nanometric feature of grains. X-ray dispersive spectroscopy permitted to infer the obtaining of the LaBiFe2O6 expected stoichiometry. Results of magnetic susceptibility as a function of temperature and field magnetization evidenced mixed ferromagnetism and superparamagnetism behavior at T=300 K. Mössbauer spectroscopy supported the superparamagnetic and ferromagnetic responses as a result of the nanogranular morphology and anisotropy effects. Spectrum of diffuse reflectance suggest that this material behaves as a semiconductor with energy gap Eg=2.13 eV.COL0008138application/pdfengUniversidade Federal de São Carlos (UFSCar)Brasilhttps://creativecommons.org/licenses/by-nc-nd/4.0/http://creativecommons.org/licenses/by-nc-nd/2.5/co/Atribución-NoComercial-SinDerivadas 2.5 Colombiainfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Structure and physical properties of the LaBiFe2O6 Perovskite produced by the Modified Pechini MethodArtículo de investigaciónhttp://purl.org/coar/resource_type/c_2df8fbb1https://purl.org/redcol/resource_type/ARThttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/version/c_71e4c1898caa6e32info:eu-repo/semantics/articlePropiedades físicasPhysical PhenomenaSemiconductoresSemiconductorsMétodo Pechini modificadoDoble perovskitaFerromagnéticohttp://aims.fao.org/aos/agrovoc/c_8e15773eMat. 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