Deshidrogenación catalítica del etilbenceno a estireno
This work pretends to show the present state inthe subject of the catalytic dehydrogenation reaction of ethylbenzene to produce styrene. It focuses on the catalyst proposals that have been presented in the last twenty years. It describes general aspects of the dehydrogenation process, highlighting t...
- Autores:
-
Causado Escobar, Robert E.
Muñoz Martínez, Rosario
Barbosa López, Aída Liliana
- Tipo de recurso:
- Fecha de publicación:
- 2013
- Institución:
- Universidad de San Buenaventura
- Repositorio:
- Repositorio USB
- Idioma:
- spa
- OAI Identifier:
- oai:bibliotecadigital.usb.edu.co:10819/4906
- Acceso en línea:
- http://hdl.handle.net/10819/4906
- Palabra clave:
- Deshidrogenación
Desactivación catalítica
Etilbenceno
Estireno
Dehydrogenation
Ethylbenzene
Styrene
Catalitic deactivation
Reacciones químicas
Procesos químicos
- Rights
- License
- Atribución-NoComercial-SinDerivadas 2.5 Colombia
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Repositorio USB |
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|
| dc.title.spa.fl_str_mv |
Deshidrogenación catalítica del etilbenceno a estireno |
| dc.title.alternative.spa.fl_str_mv |
Catalytic dehydrogenation of ethyl benzene to styrene |
| title |
Deshidrogenación catalítica del etilbenceno a estireno |
| spellingShingle |
Deshidrogenación catalítica del etilbenceno a estireno Deshidrogenación Desactivación catalítica Etilbenceno Estireno Dehydrogenation Ethylbenzene Styrene Catalitic deactivation Reacciones químicas Procesos químicos |
| title_short |
Deshidrogenación catalítica del etilbenceno a estireno |
| title_full |
Deshidrogenación catalítica del etilbenceno a estireno |
| title_fullStr |
Deshidrogenación catalítica del etilbenceno a estireno |
| title_full_unstemmed |
Deshidrogenación catalítica del etilbenceno a estireno |
| title_sort |
Deshidrogenación catalítica del etilbenceno a estireno |
| dc.creator.fl_str_mv |
Causado Escobar, Robert E. Muñoz Martínez, Rosario Barbosa López, Aída Liliana |
| dc.contributor.author.none.fl_str_mv |
Causado Escobar, Robert E. Muñoz Martínez, Rosario Barbosa López, Aída Liliana |
| dc.subject.spa.fl_str_mv |
Deshidrogenación Desactivación catalítica Etilbenceno Estireno Dehydrogenation Ethylbenzene Styrene Catalitic deactivation |
| topic |
Deshidrogenación Desactivación catalítica Etilbenceno Estireno Dehydrogenation Ethylbenzene Styrene Catalitic deactivation Reacciones químicas Procesos químicos |
| dc.subject.lemb.spa.fl_str_mv |
Reacciones químicas Procesos químicos |
| description |
This work pretends to show the present state inthe subject of the catalytic dehydrogenation reaction of ethylbenzene to produce styrene. It focuses on the catalyst proposals that have been presented in the last twenty years. It describes general aspects of the dehydrogenation process, highlighting the role of catalysts in the reaction, the kinetic aspects. Through the analysis of their advantages and disadvantages in front of agents that cause disabling. Finally, trends that are emerging in new materials to be used for designing catalyst solids more active and stable are described. |
| publishDate |
2013 |
| dc.date.issued.none.fl_str_mv |
2013-01 |
| dc.date.accessioned.none.fl_str_mv |
2017-11-08T13:25:38Z |
| dc.date.available.none.fl_str_mv |
2017-11-08T13:25:38Z |
| dc.date.submitted.none.fl_str_mv |
2017-11-07 |
| dc.type.spa.fl_str_mv |
Artículo de revista |
| dc.type.coar.fl_str_mv |
http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.spa.spa.fl_str_mv |
Artículo |
| dc.type.driver.spa.fl_str_mv |
info:eu-repo/semantics/article |
| dc.type.hasVersion.spa.fl_str_mv |
info:eu-repo/semantics/published |
| dc.identifier.issn.none.fl_str_mv |
1794-192X 2256-3202 (en línea) |
| dc.identifier.uri.none.fl_str_mv |
http://hdl.handle.net/10819/4906 |
| identifier_str_mv |
1794-192X 2256-3202 (en línea) |
| url |
http://hdl.handle.net/10819/4906 |
| dc.language.iso.spa.fl_str_mv |
spa |
| language |
spa |
| dc.relation.ispartofseries.none.fl_str_mv |
Revista Científica Guillermo de Ockham;Vol. 11, No. 1 Enero-Junio de 2013 |
| dc.rights.coar.fl_str_mv |
http://purl.org/coar/access_right/c_abf2 |
| dc.rights.cc.spa.fl_str_mv |
Atribución-NoComercial-SinDerivadas 2.5 Colombia |
| dc.rights.uri.spa.fl_str_mv |
http://creativecommons.org/licenses/by-nc-nd/2.5/co/ |
| rights_invalid_str_mv |
Atribución-NoComercial-SinDerivadas 2.5 Colombia http://creativecommons.org/licenses/by-nc-nd/2.5/co/ http://purl.org/coar/access_right/c_abf2 |
| dc.format.spa.fl_str_mv |
pdf |
| dc.format.extent.spa.fl_str_mv |
79 - 95 páginas |
| dc.format.medium.spa.fl_str_mv |
Recurso en linea |
| dc.format.mimetype.spa.fl_str_mv |
application/pdf |
| dc.publisher.spa.fl_str_mv |
Universidad de San Buenaventura |
| dc.publisher.faculty.spa.fl_str_mv |
Documento USB |
| dc.publisher.program.spa.fl_str_mv |
Documentos USB |
| dc.publisher.sede.spa.fl_str_mv |
Cali |
| dc.source.spa.fl_str_mv |
Revista Cientifica Guillermo de Ockham |
| institution |
Universidad de San Buenaventura |
| dc.source.bibliographicCitation.spa.fl_str_mv |
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BALASAMY, R.J., Tope, B.B., KHURSHID, A., AL-ALI, A., ATANDA, L.A., SAGATA, K., ASAMOTO,M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. y Al-KHATTAF, S.S. (2011). “Ethylbenzene dehydrogenation over FeOx/(Mg,Zn)(Al)O catalysts derived from hydrotalcites: Role of MgO as basic sites”. En Applied Catalysis A: General, 398, 113–122. BALKRISHNA B. Tope, RABINDRAN J. BALASAMY, ALAM Khurshid, LUQMAN A. ATANDA, HIDENORI Yahiro, TETSUYA Shishido, KATSUOMI Takehira, SULAIMAN S. Al-KHATTAF. (2011). “Catalytic mechanism of the dehydrogenation of ethylbenzene over Fe–Co/Mg(Al)O derived from hydrotalcites”. En Applied Catalysis A: General, 407, 118– 126. BAUTISTA, F., Campelo, J., LUNA, D., MARINAS, J., QUIROS, R. & ROMERO, A. (2007). “Screening of amorphous metal–phosphate catalysts for the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis B, 70, 611–620. BISPO, J.R.C., OLIVEIRA, A.C., CORREA, M.L.S., FIERRO, J.L.G., MARCHETTI, S.G. & RANGEL, M.C.(2002). “Characterization of FeMCM-41 and FeZSM-5 Catalysts Production to Styrene”. En Studies in Surface Science and Catalysis, 142, 517-524. BLANCO, J. y LINARTE, R. (1971). Catálisis, fundamentos y aplicaciones industriales. México: Ed. Trillar. BOND, G.C. (1962). Catalysis by Metals. London: Academic Press. BOSA Poveda, J. (1994). Estudio de la deshidrogenación catalítica del etilbenceno a estireno en un reactor de lecho fijo. Tesis Ing. Química. Universidad Nacional de Colombia. Bogotá. BURRI, D.R., CHOI, K.M., HAN, D.S., Koo, J.B. & PARK, S.E. (2006). “CO2 utilization as an oxidant in the dehydrogenation of ethylbenzene to styrene over MnO2-ZrO2 catalysts”. En Catalysis Today, 115, 242–247. BURRI, D.R., CHOI, K.M., LEE, J.H., HAN, D.S. & PARK, S.E. (2007). “Influence of SBA-15 support on CeO2–ZrO2 catalyst for the dehydrogenation of ethylbenzene to styrene with CO2”. En Catalysis Communications, 8, 43–48. BURRI, D.J., CHOI, K.M., HAN, S.C., BURRI, A., & PARK, S.E. (2007). “Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2 O and CO2”. En Journal of Molecular Catalysis A: Chemical, 269, 58–63. CAMPANATI, M., FORNASANI, G. Y VACCARI, A. (2003). “Fundamentals in the preparation of heterogeneous catalysts”. En Catalysis Today, 77, 299-314. CARBALLO, L. (2002). Introducción a la Catálisis Heterogénea. Facultad de Ingeniería, Universidad Nacional de Colombia, Bogotá: ed. Unidad de Publicaciones. CARBERRY, J.I. (1980). Ingeniería de las Reacciones Químicas y Catalíticas. Buenos Aires: Editorial Géminis S. R. L. CARJA, G., KAMESHIMA, Y. & OKADA, K. (2008). “Nanoparticles of iron and vanadium oxides supported on iron substituted LDHs: Synthesis, textural characterization and their catalytic behavior in ethylbenzene dehydrogenation”. En Microporous and Mesoporous Materials, 115, 541–547. CARJA, G., NAKAMURA, R. Aida, T. & NIIYAMA, H. (2003). “Mg–V–Al mixed oxides with mesoporous properties using layered double hydroxides as precursors: catalytic behavior for the process of ethylbenzene dehydrogenation to styrene under a carbon dioxide flow”. En Journal of Catalysis, 218, 104–110. CAUSADO, R. (2005). Desarrollo de Nuevos Catalizadores tipo NiMo, NiMo/CaO, FeMo, Fe2O3/CaO y Mo/γ-Al2 O3 como posibles alternativas para la reacción de Deshidrogenación de Etilbenceno en presencia de CO2 y vapor de agua en la producción de Estireno. Tesis para obtención del grado de Químico, Unicartagena–Licatuc (Colombia). CHEN Shuwei, QIN Zhangfeng, SUN Ailing & WANG Jianguo. (2009). Effects of Li Promoter on the Catalytic Performance of Fe-Li/AC for Ethylbenzene Dehydrogenation in the Presence of CO2. Chin J Catal, 30(4), 359–364. CHEN, S., Qin, Z., XU, X. & Wang, J. (2006). “Structure and properties of the alumina-supported vanadia catalysts for ethylbenzene dehydrogenation in the presence of carbon dioxide”. En Applied Catalysis A: General, 302, 185–192. CONCEIÇÃO Oliveira A. & DO CARMO Rangel, M. (2003). “Desidrogenação Do Etilbenzeno Sobre Compostos De Ferro E Alumínio”. En Quim. Nova, 26(2), 170-176. CONCEIÇÃO, A., FIERRO, J., VALENTÍN, A., SANTANA, P. y DO CARMO, M. (2003). Catalysis Today, 85, 49-57. DE ARAÚJO J., SOUSA C., OLIVEIRA A., FREIRE, F., AYALA, A. y OLIVEIRA, A. (2010). “Dehydrogenation of ethylbenzenewith CO2 to produce styrene over Fe-containing ceramic composites”. En Applied Catalysis A: General, 377, 55–63. DE MORAIS Batista, RAMOS A.H., BRAGA F.S.O., LIMA T.P., , C.L., DE SOUSA, F.F., BARROS, E.B.D., FILHO, J.M., de Oliveira, A.S., de Sousa, J.R., VALENTINI, A. & Oliveira, A.C. 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DULAMITA, N., MAICANEANU A., SAYLE D.C., STANCA, M., CRACIUN, R., OLEA, M., AflOROAEI, C. y FODOR, A.(2005). “Ethylbenzene dehydrogenation on Fe2O3-Cr2O3-K2CO3 catalysts promoted with transitional metal oxides”. En Applied Catalysis A: General, 287, 9–18. DZIEWIECKI, Z. & OZDOBA, E. (1991). Preparation of Catalysts V. Amsterdam: Elsevier Science Publishers B.V. FAROLDOS, M. y GOBERNA, C. (2002). Técnicas en el análisis y caracterización de materiales. Consejo Superior de Investigaciones Científicas, CSIC. Madrid, España. FREIRE, R.M., DE SOUSA, F.F., PINHEIRO, A.L., LONGHINOTTI, E., MENDES Filho, J., OLIVEIRA, A.C., DE TARSO, P., FREIRE, C., AYALA, A.P. & OLIVEIRA, A.C.(2009). “Studies of catalytic activity and coke deactivation of spinel oxides during ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 359, 165–179. GAO, Z., ZHANG, B. Y CUI, J. (1991). Applied Catalysis A: General, 12, 332 HABER, J. (1991). “Manual on Catalyst Characterization”. 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(1998). “Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide”. En Studies Surfaces Catalysis.114, 415. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “Mn-substituted Fe–K mixed oxide catalysts for dehydrogenation of ethylbenzene towards styrene”. En Applied Catalysis A: General. 216, 137–146. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “XPS and TPD characterization of manganesesubstituted iron–potassium oxide catalysts which are selective for dehydrogenation of ethylbenzene into styrene”. En Applied Catalysis A: General. 219, 249–258. MONTI, D.A.M. & BAIKER, A. (1983). “Temperature-Programmed Reduction. Parametric Sensitivity and Estimation of Kinetic Parameters”. En Journal of Catalysis. 83 323-335. MORONTA, A., TROCONIS, M.E., GONZÁLEZ, E., MORÁN, C., SÁNCHEZ, J., GONZÁLEZ, A. & QUIÑÓNEZ, J. (2006). Dehydrogenation of ethylbenzene to styrene catalyzed by Co, Mo and CoMo catalysts supported on natural and aluminum-pillared clays. Effect of the metal reduction. Applied Catalysis A: General.310, 199–204. NEDERLOF, C., KAPTEIJN, F. & MAKKEE, M. (2012). “Catalysed ethylbenzene dehydrogenation in CO2 or N2 Carbon deposits as theactive phase”. En Applied Catalysis A: General. 417– 418, 163– 173. NEDERLOF, C., TALAY, G., KAPTEIJN, F.& MAKKEE, M. (2012). “The role of RWGS in the dehydrogenation of ethylbenzene to styrene in CO2”. En Applied Catalysis A: General.423– 424, 59– 68. NIETO, S. (2001). Síntesis y caracterización de molibdatos y heteropolimolibdatos de cobre como posible utilización en catálisis. Tesis para obtención del grado de Químico. Universidad de Cartagena-I.V.I.C. Cartagena. NOGUEIRA, I.M., SABADIA, G. Q., MOREIRA, A.A., FILHO, J.M. & OLIVEIRA, A.C. (2011). “Investigation of the deactivation of iron nanocomposites by coking in dehydrogenation of ethylbenzene”. En Journal of Molecular Catalysis A: Chemical. 351, 81– 92. OHISHI, Y., KAWABATA, T., SHISHIDO, T., TAKAKI, K., ZHANG, Q., WANG, Y., NOMURA, K. & Takehira, K. (2005). “Mg–Fe–Al mixed oxides with mesoporous properties prepared from hydrotalcite as precursors: Catalytic behavior in ethylbenzene dehydrogenation”. En Applied Catalysis A: General. 288, 220–231. PARK, M.S., VISLOVSKIY, V.P., CHANG, J.S., SHUL, Y.G., YOO, J.S. & PARK, S.E.(2003). “Catalytic dehydrogenation of ethylbenzene with carbon dioxide: promotional effect of antimony in supported vanadium–antimony oxide catalyst”. En Catalysis Today. 87, 205–212. PENG Feng, FU Xiao-bo, YU Hao, WANG Hong-Juan.(2007). Preparation of carbon nanotube-supported Fe2 O3 catalysts and their catalytic activities for ethylbenzene dehydrogenation. New Carbon Materials. 22 (3), 213–217. PINHEIRO Braga, T., LONGHINOTTI, E., PINHEIRO, A.N. & VALENTINI, A. (2009). “Synthesis of hybrid spheres for the dehydrogenation of ethylbenzene in the presence of CO2”. En Applied Catalysis A: General. 362, 139–146. PONOMOREVA, O.A, YUSCHENKO, V.V., LVANOVA, I.I., PASQUA, L., TESTA, F., Di RENZO, F. & FAJULA, F. (2004). “Dehydrogenation of Ethylbenzene Over Ga-And Fe-Containing MCM-41”. En Studies in Surface Science and Catalysis. 154, 2208-2211. ROSSETTI, I., BENCINI, E., TRENTINI, L., FORNI, L. (2005). “Study of the deactivation of a commercial catalyst for ethylbenzene dehydrogenation to styrene”. En Applied Catalysis A: General. 292, 118–123. SAITO, K., OKUDA, K., IKENAGA, N.O., MIYAKE, T. & SUZUKI, T. (2010). “Role of Lattice Oxygen of Metal Oxides in the Dehydrogenation of Ethylbenzene under a Carbon Dioxide Atmosphere”. En J. Phys. Chem. A. 114, 3845–3854. Saito, M., KIMURA, H., MIMURA, N., Wu, J. y MURATA, K. (2003). “Dehydrogenation of ethylbenzene in the presence of CO2 over an alumina-supported iron oxide catalyst”. En Applied Catalysis A: General. 239, 71-77. SAITO, M., KIMURA, H., MIMURA, N., WU, J. y MURATA, K. 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En Studies in Surface Science and Catalysis, 159, 741-744. ZHU, X.M., SCHÖN, M., BARTMANN, U., VAN VEEN, A.C. y MUHLER, M. (2004). “The dehydrogenation of ethylbenzene to styrene over a potassium-promoted iron oxide-based catalyst: a transient kinetic study”. En Applied Catalysis A: General. 266, 99–108. ZHYZNEVSKIY, V.M., TSYBUKH, R.D., GUMENETSKIY V.V. y KOCHUBEIY V.V. (2003). “Physicochemical and catalytic properties of Fe2 BiMo2 Ox catalyst ultrasound treated and promoted with Al2O3 in the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis A: General. 238, 19–28 |
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Comunidad Científica y AcadémicaCausado Escobar, Robert E.85e2f947-c6a3-4029-8858-5fd9d56d59ae-1Muñoz Martínez, Rosarioe8476606-4ae1-4521-9b35-65a6de188628-1Barbosa López, Aída Liliana2ed46f7b-278f-41fc-a773-655cf4ec149e-12017-11-08T13:25:38Z2017-11-08T13:25:38Z2013-012017-11-07This work pretends to show the present state inthe subject of the catalytic dehydrogenation reaction of ethylbenzene to produce styrene. It focuses on the catalyst proposals that have been presented in the last twenty years. It describes general aspects of the dehydrogenation process, highlighting the role of catalysts in the reaction, the kinetic aspects. Through the analysis of their advantages and disadvantages in front of agents that cause disabling. Finally, trends that are emerging in new materials to be used for designing catalyst solids more active and stable are described.Este trabajo está orientado a mostrar el estado actual de las diversas investigaciones acerca de la reacción de deshidrogenación catalítica del etilbenceno en la producción de estireno, de acuerdo con las formulaciones catalíticas probadas en los últimos veinte años. Para ello se describen aspectos generales del proceso de deshidrogenación –entre los que se destaca el papel de los catalizadores en la reacción y sus aspectos cinéticos–, se analizan sus ventajas y desventajas frente a los agentes que causan la desactivación y se describen los nuevos materiales empleados en el diseño de sólidos catalíticos más activos y estables.Universidad de San Buenaventura - Calipdf79 - 95 páginasRecurso en lineaapplication/pdf1794-192X2256-3202 (en línea)http://hdl.handle.net/10819/4906spaUniversidad de San BuenaventuraDocumento USBDocumentos USBCaliRevista Científica Guillermo de Ockham;Vol. 11, No. 1 Enero-Junio de 2013Atribución-NoComercial-SinDerivadas 2.5 ColombiaPor medio de este formato manifiesto mi voluntad de AUTORIZAR a la Universidad de San Buenaventura, Sede Bogotá, Seccionales Medellín, Cali y Cartagena, la difusión en texto completo de manera gratuita y por tiempo indefinido en la Biblioteca Digital Universidad de San Buenaventura, el documento académico-investigativo objeto de la presente autorización, con fines estrictamente educativos, científicos y culturales, en los términos establecidos en la Ley 23 de 1982, Ley 44 de 1993, Decisión Andina 351 de 1993, Decreto 460 de 1995 y demás normas generales sobre derechos de autor. Como autor manifiesto que el presente documento académico-investigativo es original y se realiza sin violar o usurpar derechos de autor de terceros, por lo tanto, la obra es de mi exclusiva autora y poseo la titularidad sobre la misma. La Universidad de San Buenaventura no será responsable de ninguna utilización indebida del documento por parte de terceros y será exclusivamente mi responsabilidad atender personalmente cualquier reclamación que pueda presentarse a la Universidad. Autorizo a la Biblioteca Digital de la Universidad de San Buenaventura convertir el documento al formato que el repositorio lo requiera (impreso, digital, electrónico o cualquier otro conocido o por conocer) o con fines de preservación digital. Esta autorización no implica renuncia a la facultad que tengo de publicar posteriormente la obra, en forma total o parcial, por lo cual podrá, dando aviso por escrito con no menos de un mes de antelación, solicitar que el documento deje de estar disponible para el público en la Biblioteca Digital de la Universidad de San Buenaventura, así mismo, cuando se requiera por razones legales y/o reglas del editor de una revista.http://creativecommons.org/licenses/by-nc-nd/2.5/co/http://purl.org/coar/access_right/c_abf2Revista Cientifica Guillermo de OckhamADDIEGO, W.P., LIU, W. & BOGER, T. (2001). “Iron oxide-based honeycomb catalysts for the dehydrogenation of ethylbenzene to styrene”. En Catalysis Today, 69, 25–31. ANDERSON, R.B. & DAWSON, P.T. (1976). Experimental Methods in Catalytic Research. Vol. II. p. 44-67. New York: Academic Press. ANDRESSA H. de Morais Batista; DE SOUSA Francisco F.; HONORATO Sara B., AYALA Alejandro P., Josue M. Filho, PINHEIRO Antonio N.,J.C.S. de Araújo, Ronaldo F. Nascimento, Antoninho Valentini & Alcineia C. Oliveira. (2010). “Ethylbenzene to chemicals: Catalytic conversion of ethylbenzene into styrene over metal-containing MCM-41”. En Journal of Molecular Catalysis A: Chemical, 315, 86–98. ATANDA, L.A., Al-Yassir, N.& Al-Khattaf, S. (2011). “Kinetic modeling of ethylbenzene dehydrogenation over hydrotalcite catalysts”. En Chemical Engineering Journal, 171, 1387– 1398. ATANDA, L.A., BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2011). “Ethylbenzene dehy drogenation over Mg3Fe0.5−xCoxAl0.5 catalysts derived from hydrotalcites: Comparison with Mg3Fe0.5−y NiyAl0.5 catalysts.” En Applied Catalysis A: General, 396, 107–115. BAGHALHA, M. & EBRAHIMPOUR, O.(2007). “Structural changes and surface activities of ethylbenzene dehydrogenation catalysts during deactivation.” En Applied Catalysis A: General, 326, 143–151. BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., ATANDA, L.A., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2010). “Ethylbenzene dehydrogenation over binary FeOx–MeOy/Mg(Al)O catalysts derived from hydrotalcites”. En Applied Catalysis A: General, 390, 225–234. BALASAMY, R.J., Tope, B.B., KHURSHID, A., AL-ALI, A., ATANDA, L.A., SAGATA, K., ASAMOTO,M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. y Al-KHATTAF, S.S. (2011). “Ethylbenzene dehydrogenation over FeOx/(Mg,Zn)(Al)O catalysts derived from hydrotalcites: Role of MgO as basic sites”. En Applied Catalysis A: General, 398, 113–122. BALKRISHNA B. Tope, RABINDRAN J. BALASAMY, ALAM Khurshid, LUQMAN A. ATANDA, HIDENORI Yahiro, TETSUYA Shishido, KATSUOMI Takehira, SULAIMAN S. Al-KHATTAF. 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En Applied Catalysis A: General. 238, 19–28Universidad de San Buenaventura - CaliCali, Hemeroteca 3er. pisoBiblioteca Digital Universidad de San BuenaventuraDeshidrogenaciónDesactivación catalíticaEtilbencenoEstirenoDehydrogenationEthylbenzeneStyreneCatalitic deactivationReacciones químicasProcesos químicosDeshidrogenación catalítica del etilbenceno a estirenoCatalytic dehydrogenation of ethyl benzene to styreneArtículo de revistaArtículoinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedhttp://purl.org/coar/resource_type/c_2df8fbb1PublicationORIGINAL603-1589-1-PB.pdf603-1589-1-PB.pdfapplication/pdf336968https://bibliotecadigital.usb.edu.co/bitstreams/ed3769a7-8f36-4da3-b255-f6c252aac557/downloaddcb591cbf55be31bbf7924817ab48d00MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-82071https://bibliotecadigital.usb.edu.co/bitstreams/fbacbe97-622a-45e6-86c6-d628d10396e4/download0c7b7184e7583ec671a5d9e43f0939c0MD52TEXT603-1589-1-PB.pdf.txt603-1589-1-PB.pdf.txtExtracted texttext/plain62752https://bibliotecadigital.usb.edu.co/bitstreams/b0d77395-f0aa-4fb8-94e5-b62ee62516c9/download00bcfc9750658c0e32662a6b60e031d0MD53THUMBNAIL603-1589-1-PB.pdf.jpg603-1589-1-PB.pdf.jpgGenerated Thumbnailimage/jpeg12593https://bibliotecadigital.usb.edu.co/bitstreams/9f4d9a33-1d38-47b8-95b9-07539656aae9/download7b26b2099c71050f148d5e6e80aeab9dMD5410819/4906oai:bibliotecadigital.usb.edu.co:10819/49062023-04-12 16:47:24.819http://creativecommons.org/licenses/by-nc-nd/2.5/co/https://bibliotecadigital.usb.edu.coRepositorio Institucional Universidad de San Buenaventura Colombiabdigital@metabiblioteca.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 |