Deshidrogenación catalítica del etilbenceno a estireno

Este trabajo está orientado a mostrar el estado actual de las diversas investigaciones acerca de la reacción de deshidrogenación catalítica del etilbenceno en la producción de estireno, de acuerdo con las formulaciones catalíticas probadas en los últimos veinte años. Para ello se describen aspectos...

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Autores:
Causado Escobar, Robert
Muñoz Martínez, Rosario
Barbosa López, Aída Liliana
Tipo de recurso:
Article of journal
Fecha de publicación:
2013
Institución:
Universidad de San Buenaventura
Repositorio:
Repositorio USB
Idioma:
spa
OAI Identifier:
oai:bibliotecadigital.usb.edu.co:10819/26052
Acceso en línea:
https://hdl.handle.net/10819/26052
https://doi.org/10.21500/22563202.603
Palabra clave:
deshidrogenación
desactivación catalítica
etilbenceno
estireno
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openAccess
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http://purl.org/coar/access_right/c_abf2
id SANBUENAV2_12709ba5e89090d479ce4e3618cf42f5
oai_identifier_str oai:bibliotecadigital.usb.edu.co:10819/26052
network_acronym_str SANBUENAV2
network_name_str Repositorio USB
repository_id_str
dc.title.spa.fl_str_mv Deshidrogenación catalítica del etilbenceno a estireno
dc.title.translated.spa.fl_str_mv Deshidrogenación catalítica del etilbenceno a estireno
title Deshidrogenación catalítica del etilbenceno a estireno
spellingShingle Deshidrogenación catalítica del etilbenceno a estireno
deshidrogenación
desactivación catalítica
etilbenceno
estireno
title_short Deshidrogenación catalítica del etilbenceno a estireno
title_full Deshidrogenación catalítica del etilbenceno a estireno
title_fullStr Deshidrogenación catalítica del etilbenceno a estireno
title_full_unstemmed Deshidrogenación catalítica del etilbenceno a estireno
title_sort Deshidrogenación catalítica del etilbenceno a estireno
dc.creator.fl_str_mv Causado Escobar, Robert
Muñoz Martínez, Rosario
Barbosa López, Aída Liliana
dc.contributor.author.eng.fl_str_mv Causado Escobar, Robert
Muñoz Martínez, Rosario
Barbosa López, Aída Liliana
dc.subject.spa.fl_str_mv deshidrogenación
desactivación catalítica
etilbenceno
estireno
topic deshidrogenación
desactivación catalítica
etilbenceno
estireno
description Este trabajo está orientado a mostrar el estado actual de las diversas investigaciones acerca de la reacción de deshidrogenación catalítica del etilbenceno en la producción de estireno, de acuerdo con las formulaciones catalíticas probadas en los últimos veinte años. Para ello se describen aspectos generales del proceso de deshidrogenación –entre los que se destaca el papel de los catalizadores en la reacción y sus aspectos cinéticos–, se analizan sus ventajas y desventajas frente a los agentes que causan la desactivación y se describen los nuevos materiales empleados en el diseño de solidos catalíticos más activos y estables.
publishDate 2013
dc.date.accessioned.none.fl_str_mv 2013-06-01T00:00:00Z
2025-07-31T17:11:51Z
dc.date.available.none.fl_str_mv 2013-06-01T00:00:00Z
2025-07-31T17:11:51Z
dc.date.issued.none.fl_str_mv 2013-06-01
dc.type.spa.fl_str_mv Artículo de revista
dc.type.coar.spa.fl_str_mv http://purl.org/coar/resource_type/c_6501
http://purl.org/coar/resource_type/c_2df8fbb1
dc.type.coarversion.spa.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.content.spa.fl_str_mv Text
dc.type.driver.spa.fl_str_mv info:eu-repo/semantics/article
dc.type.local.eng.fl_str_mv Journal article
dc.type.redcol.spa.fl_str_mv http://purl.org/redcol/resource_type/ART
dc.type.version.spa.fl_str_mv info:eu-repo/semantics/publishedVersion
format http://purl.org/coar/resource_type/c_6501
status_str publishedVersion
dc.identifier.doi.none.fl_str_mv 10.21500/22563202.603
dc.identifier.eissn.none.fl_str_mv 2256-3202
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/10819/26052
dc.identifier.url.none.fl_str_mv https://doi.org/10.21500/22563202.603
identifier_str_mv 10.21500/22563202.603
2256-3202
url https://hdl.handle.net/10819/26052
https://doi.org/10.21500/22563202.603
dc.language.iso.spa.fl_str_mv spa
language spa
dc.relation.bitstream.none.fl_str_mv https://revistas.usb.edu.co/index.php/GuillermoOckham/article/download/603/403
dc.relation.citationendpage.none.fl_str_mv 95
dc.relation.citationissue.eng.fl_str_mv 1
dc.relation.citationstartpage.none.fl_str_mv 79
dc.relation.citationvolume.eng.fl_str_mv 11
dc.relation.ispartofjournal.eng.fl_str_mv Revista Guillermo de Ockham
dc.relation.references.spa.fl_str_mv ADDIEGO, W.P., LIU, W. & BOGER, T. (2001). “Iron oxide-based honeycomb catalysts for the dehydrogenation of ethylbenzene to styrene”. En Catalysis Today, 69, 25–31. ANDERSON, R.B. & DAWSON, P.T. (1976). Experimental Methods in Catalytic Research. Vol. II. p. 44-67. New York: Academic Press. ANDRESSA H. de Morais Batista; DE SOUSA Francisco F.; HONORATO Sara B., AYALA Alejandro P., Josue M. Filho, PINHEIRO Antonio N.,J.C.S. de Araújo, Ronaldo F. Nascimento, Antoninho Valentini & Alcineia C. Oliveira. (2010). “Ethylbenzene to chemicals: Catalytic conversion of ethylbenzene into styrene over metal-containing MCM-41”. En Journal of Molecular Catalysis A: Chemical, 315, 86–98. ATANDA, L.A., Al-Yassir, N.& Al-Khattaf, S. (2011). “Kinetic modeling of ethylbenzene dehydrogenation over hydrotalcite catalysts”. En Chemical Engineering Journal, 171, 1387– 1398. ATANDA, L.A., BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2011). “Ethylbenzene dehy drogenation over Mg3Fe0.5−xCoxAl0.5 catalysts derived from hydrotalcites: Comparison with Mg3Fe0.5−y NiyAl0.5 catalysts.” En Applied Catalysis A: General, 396, 107–115. BAGHALHA, M. & EBRAHIMPOUR, O.(2007). “Structural changes and surface activities of ethylbenzene dehydrogenation catalysts during deactivation.” En Applied Catalysis A: General, 326, 143–151. BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., ATANDA, L.A., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2010). “Ethylbenzene dehydrogenation over binary FeOx–MeOy/Mg(Al)O catalysts derived from hydrotalcites”. En Applied Catalysis A: General, 390, 225–234. BALASAMY, R.J., Tope, B.B., KHURSHID, A., AL-ALI, A., ATANDA, L.A., SAGATA, K., ASAMOTO,M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. y Al-KHATTAF, S.S. (2011). “Ethylbenzene dehydrogenation over FeOx/(Mg,Zn)(Al)O catalysts derived from hydrotalcites: Role of MgO as basic sites”. En Applied Catalysis A: General, 398, 113–122. BALKRISHNA B. Tope, RABINDRAN J. BALASAMY, ALAM Khurshid, LUQMAN A. ATANDA, HIDENORI Yahiro, TETSUYA Shishido, KATSUOMI Takehira, SULAIMAN S. Al-KHATTAF. (2011). “Catalytic mechanism of the dehydrogenation of ethylbenzene over Fe–Co/Mg(Al)O derived from hydrotalcites”. En Applied Catalysis A: General, 407, 118– 126. BAUTISTA, F., Campelo, J., LUNA, D., MARINAS, J., QUIROS, R. & ROMERO, A. (2007). “Screening of amorphous metal–phosphate catalysts for the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis B, 70, 611–620. BISPO, J.R.C., OLIVEIRA, A.C., CORREA, M.L.S., FIERRO, J.L.G., MARCHETTI, S.G. & RANGEL, M.C.(2002). “Characterization of FeMCM-41 and FeZSM-5 Catalysts Production to Styrene”. En Studies in Surface Science and Catalysis, 142, 517-524. BLANCO, J. y LINARTE, R. (1971). Catálisis, fundamentos y aplicaciones industriales. México: Ed. Trillar. BOND, G.C. (1962). Catalysis by Metals. London: Academic Press. BOSA Poveda, J. (1994). Estudio de la deshidrogenación catalítica del etilbenceno a estireno en un reactor de lecho fijo. Tesis Ing. Química. Universidad Nacional de Colombia. Bogotá. BURRI, D.R., CHOI, K.M., HAN, D.S., Koo, J.B. & PARK, S.E. (2006). “CO2 utilization as an oxidant in the dehydrogenation of ethylbenzene to styrene over MnO2-ZrO2 catalysts”. En Catalysis Today, 115, 242–247. BURRI, D.R., CHOI, K.M., LEE, J.H., HAN, D.S. & PARK, S.E. (2007). “Influence of SBA-15 support on CeO2–ZrO2 catalyst for the dehydrogenation of ethylbenzene to styrene with CO2”. En Catalysis Communications, 8, 43–48. BURRI, D.J., CHOI, K.M., HAN, S.C., BURRI, A., & PARK, S.E. (2007). “Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2 O and CO2”. En Journal of Molecular Catalysis A: Chemical, 269, 58–63. CAMPANATI, M., FORNASANI, G. Y VACCARI, A. (2003). “Fundamentals in the preparation of heterogeneous catalysts”. En Catalysis Today, 77, 299-314. CARBALLO, L. (2002). Introducción a la Catálisis Heterogénea. Facultad de Ingeniería, Universidad Nacional de Colombia, Bogotá: ed. Unidad de Publicaciones. CARBERRY, J.I. (1980). Ingeniería de las Reacciones Químicas y Catalíticas. Buenos Aires: Editorial Géminis S. R. L. CARJA, G., KAMESHIMA, Y. & OKADA, K. (2008). “Nanoparticles of iron and vanadium oxides supported on iron substituted LDHs: Synthesis, textural characterization and their catalytic behavior in ethylbenzene dehydrogenation”. En Microporous and Mesoporous Materials, 115, 541–547. CARJA, G., NAKAMURA, R. Aida, T. & NIIYAMA, H. (2003). “Mg–V–Al mixed oxides with mesoporous properties using layered double hydroxides as precursors: catalytic behavior for the process of ethylbenzene dehydrogenation to styrene under a carbon dioxide flow”. En Journal of Catalysis, 218, 104–110. CAUSADO, R. (2005). Desarrollo de Nuevos Catalizadores tipo NiMo, NiMo/CaO, FeMo, Fe2O3/CaO y Mo/γ-Al2 O3 como posibles alternativas para la reacción de Deshidrogenación de Etilbenceno en presencia de CO2 y vapor de agua en la producción de Estireno. Tesis para obtención del grado de Químico, Unicartagena–Licatuc (Colombia). CHEN Shuwei, QIN Zhangfeng, SUN Ailing & WANG Jianguo. (2009). Effects of Li Promoter on the Catalytic Performance of Fe-Li/AC for Ethylbenzene Dehydrogenation in the Presence of CO2. Chin J Catal, 30(4), 359–364. CHEN, S., Qin, Z., XU, X. & Wang, J. (2006). “Structure and properties of the alumina-supported vanadia catalysts for ethylbenzene dehydrogenation in the presence of carbon dioxide”. En Applied Catalysis A: General, 302, 185–192. CONCEIÇÃO Oliveira A. & DO CARMO Rangel, M. (2003). “Desidrogenação Do Etilbenzeno Sobre Compostos De Ferro E Alumínio”. En Quim. Nova, 26(2), 170-176. CONCEIÇÃO, A., FIERRO, J., VALENTÍN, A., SANTANA, P. y DO CARMO, M. (2003). Catalysis Today, 85, 49-57. DE ARAÚJO J., SOUSA C., OLIVEIRA A., FREIRE, F., AYALA, A. y OLIVEIRA, A. (2010). “Dehydrogenation of ethylbenzenewith CO2 to produce styrene over Fe-containing ceramic composites”. En Applied Catalysis A: General, 377, 55–63. DE MORAIS Batista, RAMOS A.H., BRAGA F.S.O., LIMA T.P., , C.L., DE SOUSA, F.F., BARROS, E.B.D., FILHO, J.M., de Oliveira, A.S., de Sousa, J.R., VALENTINI, A. & Oliveira, A.C. (2010). “Mesoporous MAl2 O4 (M= Cu, Ni, Fe or Mg) spinels: Characterisation and application in the catalytic dehydrogenation of ethylbenzene in the presence of CO2”. En Applied Catalysis A: General, 382, 148–157. DE SOUZA Ramos, M., DE SANTANA Santos, M., PACHECO Gomes, L., ALBORNOZ, A. y DO CARMO Rangel M. (2008). “The influence of dopants on the catalytic activity of hematite in the ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 341, 12–17. DIAS Holtz, R., DE OLIVEIRA, S.B., FRAGA, M.A. & DO CARMO Rangel, M. (2008). “Synthesis and characterization of polymeric activated carbon-supported vanadium and magnesium catalysts for ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 350, 79–85. DROGUETT, S. (1983). Elementos de la Catálisis Heterogénea. Monografía N° 26. Secretaría General de la Organización de los Estados Americanos. Washington, D.C. 12-15, 38-40 y 90-91. DULAMITA, N., MAICANEANU A., SAYLE D.C., STANCA, M., CRACIUN, R., OLEA, M., AflOROAEI, C. y FODOR, A.(2005). “Ethylbenzene dehydrogenation on Fe2O3-Cr2O3-K2CO3 catalysts promoted with transitional metal oxides”. En Applied Catalysis A: General, 287, 9–18. DZIEWIECKI, Z. & OZDOBA, E. (1991). Preparation of Catalysts V. Amsterdam: Elsevier Science Publishers B.V. FAROLDOS, M. y GOBERNA, C. (2002). Técnicas en el análisis y caracterización de materiales. Consejo Superior de Investigaciones Científicas, CSIC. Madrid, España. FREIRE, R.M., DE SOUSA, F.F., PINHEIRO, A.L., LONGHINOTTI, E., MENDES Filho, J., OLIVEIRA, A.C., DE TARSO, P., FREIRE, C., AYALA, A.P. & OLIVEIRA, A.C.(2009). “Studies of catalytic activity and coke deactivation of spinel oxides during ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 359, 165–179. GAO, Z., ZHANG, B. Y CUI, J. (1991). Applied Catalysis A: General, 12, 332 HABER, J. (1991). “Manual on Catalyst Characterization”. En Pure and Applied Chemistry, 63 (9), 1227-1246. HONG, D.Y., CHANG, J.S., LEE, J.H., VISLOVSKIY, W.P., JHUNG, S.H., PARK, S.E. & PARK, Y.H. (2006). “Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium–antimony oxide catalyst”. En Catalysis Today, 112, 86–88. HUERTA, L., MEYER, A. & CHOREN, E. (2003). “Synthesis, characterization and catalytic application for ethylbenzene dehydrogenation of an iron pillared clay”. En Microporous and Mesoporous Materials, 57, 219–227. HURST, N.W., GENTRY, S.J., JONES, A. y MCNICOL, B.D. (1982). Temperature Programmed Reduction. Catal. Rev. Sci. Eng. 24 (2), 233-309. IKENAGA, N.O., TSURUDA, T., SENMA, K., YAMAGUCHI, T., SAKURAI, Y. & SUZUKI, T. (2000). “Dehydrogenation of Ethylbenzene with Carbon Dioxide Using Activated Carbon-Supported Catalysts”. En Ind. Eng. Chem. Res. 39, 1228-1234. JI, M., CHEN, G., WANG, J., WANG, X. y ZHANG, T. (2010). “Dehydrogenation of ethylbenzene to styrene with CO2 over iron oxide-based catalysts”. En Catalysis Today. 158, 464–469. JONES, A. & MCNICOL, B.D. ( 1986). “Temperature-Programmed Reduction for Solid Materials Characterization”. En Chemical Industries/24. Usa: Marcel Dekker, Inc. KHATAMIAN, M., KHANDAR, A.A., HAGHIGHI, M. & GHADIRI, M. (2011). “Nano ZSM-5 type ferrisilicates as novel catalysts for ethylbenzenedehydrogenation in the presence of N2O”. En Applied Surface Science. 258, 865– 872. KIRK, Othmer. (1997). Enciclopedia of Chemical Technology, 4ta Edición KOTARBA, A., BIENIASZ, W., KUSTROWSKI, P., STADNICKA, K. & SOJKA, Z. (2011). “Composite ferrite catalyst for ethylbenzene dehydrogenation: Enhancement ofpotassium stability and catalytic performance by phase selective doping”. En Applied Catalysis A: General. 407, 100–105. KUSTROWSKI, P., ŁASOCHA, A.R., MAJDA, D., TOMASZEWSKA, D. & DZIEMBAJ, R. (2001). “Preparation and characterization of new Mg–Al–Fe oxide catalyst precursors for dehydrogenation of ethylbenzene in the presence of carbon dioxide”. En Solid State Ionics.141–142, 237–242. LANGE, Jean-Paul y OTTEN, Vincent. (2006). “Dehydration of phenyl-ethanol to styrene: Zeolite catalysis under reactive distillation”. En Journal of Catalysis.238, 6–12. LI, Z., & SHANKS, E.H. (2011). “Role of Cr and V on the stability of potassium-promoted iron oxides used as catalysts in ethylbenzene dehydrogenation”. En Aplied Catalysis A: General. 405, 101– 107. LIAO, S.J., CHEN, T., MIAO, C.X., YANG, W.M., Xie, Z.K. & CHEN, Q.L. (2008). “Effect of TiO2 on the structure and catalytic behavior of iron–potassium oxide catalyst for dehydrogenation of ethylbenzene to styrene”. En Catalysis Communications. 9, 1817–1821. MATSUI, J., SODESAWA, T. y NURAKI, F. (1990). “Influence of carbon dioxide addition upon decay of activity of a potassium-promoted iron oxide catalyst for dehydrogenation of ethylbenzene”. En Applied Catalysis A: General. 67, 179. Meima, G.R. & MENON, P.G. (2001). “Catalyst deactivation phenomena in styrene production”. En Applied Catalysis A: General. 212, 239–245. MIMURA, N. & SAITO, M. (2000). “Dehydrogenation of ethylbenzene to styrene over Fe2 O3/Al2O3 catalysts in the presence of carbon dioxide”. En Catalysis Today. 55. 173–178. Mimura, N. y Saito, M. (1999). “Dehydrogenation of ethylbenzene to styrene over Fe2O3/Al2O3 catalysts in the presence of carbon dioxide”. En Catalysis Today. 55, 173-178. MIMURA, N., TAKANARA, L., SAITO, M., HATTORI, T., OHKUMA, M. y ANDO, M. (1998). “Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide”. En Catalysis Today. 45, 61. MIMURA, N., TAKANARA, L., SAITO, M., HATTORI, T., OHKUMA, M. y ANDO, M. (1998). “Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide”. En Studies Surfaces Catalysis.114, 415. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “Mn-substituted Fe–K mixed oxide catalysts for dehydrogenation of ethylbenzene towards styrene”. En Applied Catalysis A: General. 216, 137–146. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “XPS and TPD characterization of manganesesubstituted iron–potassium oxide catalysts which are selective for dehydrogenation of ethylbenzene into styrene”. En Applied Catalysis A: General. 219, 249–258. MONTI, D.A.M. & BAIKER, A. (1983). “Temperature-Programmed Reduction. Parametric Sensitivity and Estimation of Kinetic Parameters”. En Journal of Catalysis. 83 323-335. MORONTA, A., TROCONIS, M.E., GONZÁLEZ, E., MORÁN, C., SÁNCHEZ, J., GONZÁLEZ, A. & QUIÑÓNEZ, J. (2006). Dehydrogenation of ethylbenzene to styrene catalyzed by Co, Mo and CoMo catalysts supported on natural and aluminum-pillared clays. Effect of the metal reduction. Applied Catalysis A: General.310, 199–204. NEDERLOF, C., KAPTEIJN, F. & MAKKEE, M. (2012). “Catalysed ethylbenzene dehydrogenation in CO2 or N2 Carbon deposits as theactive phase”. En Applied Catalysis A: General. 417– 418, 163– 173. NEDERLOF, C., TALAY, G., KAPTEIJN, F.& MAKKEE, M. (2012). “The role of RWGS in the dehydrogenation of ethylbenzene to styrene in CO2”. En Applied Catalysis A: General.423– 424, 59– 68. NIETO, S. (2001). Síntesis y caracterización de molibdatos y heteropolimolibdatos de cobre como posible utilización en catálisis. Tesis para obtención del grado de Químico. Universidad de Cartagena-I.V.I.C. Cartagena. NOGUEIRA, I.M., SABADIA, G. Q., MOREIRA, A.A., FILHO, J.M. & OLIVEIRA, A.C. (2011). “Investigation of the deactivation of iron nanocomposites by coking in dehydrogenation of ethylbenzene”. En Journal of Molecular Catalysis A: Chemical. 351, 81– 92. OHISHI, Y., KAWABATA, T., SHISHIDO, T., TAKAKI, K., ZHANG, Q., WANG, Y., NOMURA, K. & Takehira, K. (2005). “Mg–Fe–Al mixed oxides with mesoporous properties prepared from hydrotalcite as precursors: Catalytic behavior in ethylbenzene dehydrogenation”. En Applied Catalysis A: General. 288, 220–231. PARK, M.S., VISLOVSKIY, V.P., CHANG, J.S., SHUL, Y.G., YOO, J.S. & PARK, S.E.(2003). “Catalytic dehydrogenation of ethylbenzene with carbon dioxide: promotional effect of antimony in supported vanadium–antimony oxide catalyst”. En Catalysis Today. 87, 205–212. PENG Feng, FU Xiao-bo, YU Hao, WANG Hong-Juan.(2007). Preparation of carbon nanotube-supported Fe2 O3 catalysts and their catalytic activities for ethylbenzene dehydrogenation. New Carbon Materials. 22 (3), 213–217. PINHEIRO Braga, T., LONGHINOTTI, E., PINHEIRO, A.N. & VALENTINI, A. (2009). “Synthesis of hybrid spheres for the dehydrogenation of ethylbenzene in the presence of CO2”. En Applied Catalysis A: General. 362, 139–146. PONOMOREVA, O.A, YUSCHENKO, V.V., LVANOVA, I.I., PASQUA, L., TESTA, F., Di RENZO, F. & FAJULA, F. (2004). “Dehydrogenation of Ethylbenzene Over Ga-And Fe-Containing MCM-41”. En Studies in Surface Science and Catalysis. 154, 2208-2211. ROSSETTI, I., BENCINI, E., TRENTINI, L., FORNI, L. (2005). “Study of the deactivation of a commercial catalyst for ethylbenzene dehydrogenation to styrene”. En Applied Catalysis A: General. 292, 118–123. SAITO, K., OKUDA, K., IKENAGA, N.O., MIYAKE, T. & SUZUKI, T. (2010). “Role of Lattice Oxygen of Metal Oxides in the Dehydrogenation of Ethylbenzene under a Carbon Dioxide Atmosphere”. En J. Phys. Chem. A. 114, 3845–3854. Saito, M., KIMURA, H., MIMURA, N., Wu, J. y MURATA, K. (2003). “Dehydrogenation of ethylbenzene in the presence of CO2 over an alumina-supported iron oxide catalyst”. En Applied Catalysis A: General. 239, 71-77. SAITO, M., KIMURA, H., MIMURA, N., WU, J. y MURATA, K. (2003). “Dehydrogenation of ethylbenzene in the presence of CO2 over an alumina-supported iron oxide catalyst”. En Applied Catalysis A: General. 239, 71-77. SAKURAI, Y., SUZAKI, T., NAKAGAWA, K., IKENAGA, N., AOTA, H. y Suzuki, T. (2002). Journal of Catalysis. 209(1),16-24. SANTOS M.D.S., ALBORNOZ, A. & DO CARMO Rangel, M. (2006). “The influence of the preparation method on the catalytic properties of Lanthanum-doped hematite in the ethylbenzene dehydrogenation”. En Scientific Bases for the Preparation of Heterogeneous Catalysts. Elsevier B.V, 753-760. SANTOS, M.D.S., MARCHETTI, S.G., ALBORNOZ, A. & DO CARMO Rangel, M. (2008). “Effect of lanthanum addition on the properties of potassium-free catalysts for ethylbenzene dehydrogenation”. En Catalysis Today. 133–135 160–167. SECRETARÍA GENERAL DE LA ORGANIZACIÓN DE LOS ESTADOS AMERICANOS (1980). La espectroscopía infrarroja. Washington, D.C. SHEKHAH, O., RANKE, W. & SCHLÖGL, R. (2004). “Styrene synthesis: in situ characterization and reactivity studies of unpromoted and potassium-promoted iron oxide model catalysts”. En Journal of Catalysis. 225, 56–68. STYLES, A. B. (1983). Applied Industrial Catalysis. New York: Academic Press. SUGINO, M., SHIMADA, H., TURUDA, T., MIURA, H., IKENAGA, N. & SUZUKI, T. (1995). “Oxidative dehydrogenation of ethylbenzene with carbon dioxide”. En Applied Catalysis A: General.121, 125-137. SUN, A., QIN, Z., Chen, S. & WANG, J. (2004). “Ethylbenzene dehydrogenation in the presence of carbon dioxide over alumina supported catalysts”. En Catalysis Today. 93–95, 273–279. SUN, A., QIN, Z., CHEN, S. & WANG, J. (2004). “Role of carbon dioxide in the ethylbenzene dehydrogenation coupled with reverse water–gas shift”. En Journal of Molecular Catalysis A: Chemical. 210, 189–195. VISLOVSKIY, V.P., CHANG, J.S., PARK, M.S. & PARK, S.E. (2002). “Ethylbenzene into styrene with carbon dioxide over modified vanadia–alumina catalysts”. En Catalysis Communications. 3, 227–231. XIANG Bin, XU HENGYONG & LI Wenzhou. (2007). “Highly efficient nano-sized Fe2 O3–K2 O catalyst for dehydrogenation of ethylbenzene to styrene”. En Chinese Journal of Catalysis. 28(10). 841–843. XU, J., HUANG, J., LIU, Y., Cao, Y.,Li, Y. y FAN, K. (2011). Catal. Lett. 141, 198–206. XU, J., XUE, B., LIU, Y., LI, Y., CAO Y. y FAN, K. (2011). “Mesostructured Ni-doped ceria as an efficient catalyst for styrene synthesis by oxidative dehydrogenation of ethylbenzene”. En Applied Catalysis A: General. 405, 142–148. YE, X., MA, N., HUA, W., YUE, Y., MIAO, C., XIE, Z. & GAO, Z. (2004). “Dehydrogenation of ethylbenzene in the presence of CO2 over catalysts prepared from hydrotalcite-like precursors”. En Journal of Molecular Catalysis A: Chemical. 217, 103–108. ZHAO, T.J., SUN, Y.J., GU, X.Y., LI, P., CHEN, D., DAI, D.Y., YUAN, W.K. & Holmen, A. (2006). “Dehydrogenation of ethylbenzene with carbon nanofiber supported iron oxide carbon dioxide over”. En Studies in Surface Science and Catalysis, 159, 741-744. ZHU, X.M., SCHÖN, M., BARTMANN, U., VAN VEEN, A.C. y MUHLER, M. (2004). “The dehydrogenation of ethylbenzene to styrene over a potassium-promoted iron oxide-based catalyst: a transient kinetic study”. En Applied Catalysis A: General. 266, 99–108. ZHYZNEVSKIY, V.M., TSYBUKH, R.D., GUMENETSKIY V.V. y KOCHUBEIY V.V. (2003). “Physicochemical and catalytic properties of Fe2 BiMo2 Ox catalyst ultrasound treated and promoted with Al2O3 in the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis A: General. 238, 19–28
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spelling Causado Escobar, RobertMuñoz Martínez, RosarioBarbosa López, Aída Liliana2013-06-01T00:00:00Z2025-07-31T17:11:51Z2013-06-01T00:00:00Z2025-07-31T17:11:51Z2013-06-01Este trabajo está orientado a mostrar el estado actual de las diversas investigaciones acerca de la reacción de deshidrogenación catalítica del etilbenceno en la producción de estireno, de acuerdo con las formulaciones catalíticas probadas en los últimos veinte años. Para ello se describen aspectos generales del proceso de deshidrogenación –entre los que se destaca el papel de los catalizadores en la reacción y sus aspectos cinéticos–, se analizan sus ventajas y desventajas frente a los agentes que causan la desactivación y se describen los nuevos materiales empleados en el diseño de solidos catalíticos más activos y estables.application/pdf10.21500/22563202.6032256-3202https://hdl.handle.net/10819/26052https://doi.org/10.21500/22563202.603spaUniversidad de San Buenaventura Calihttps://revistas.usb.edu.co/index.php/GuillermoOckham/article/download/603/4039517911Revista Guillermo de OckhamADDIEGO, W.P., LIU, W. & BOGER, T. (2001). “Iron oxide-based honeycomb catalysts for the dehydrogenation of ethylbenzene to styrene”. En Catalysis Today, 69, 25–31. ANDERSON, R.B. & DAWSON, P.T. (1976). Experimental Methods in Catalytic Research. Vol. II. p. 44-67. New York: Academic Press. ANDRESSA H. de Morais Batista; DE SOUSA Francisco F.; HONORATO Sara B., AYALA Alejandro P., Josue M. Filho, PINHEIRO Antonio N.,J.C.S. de Araújo, Ronaldo F. Nascimento, Antoninho Valentini & Alcineia C. Oliveira. (2010). “Ethylbenzene to chemicals: Catalytic conversion of ethylbenzene into styrene over metal-containing MCM-41”. En Journal of Molecular Catalysis A: Chemical, 315, 86–98. ATANDA, L.A., Al-Yassir, N.& Al-Khattaf, S. (2011). “Kinetic modeling of ethylbenzene dehydrogenation over hydrotalcite catalysts”. En Chemical Engineering Journal, 171, 1387– 1398. ATANDA, L.A., BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2011). “Ethylbenzene dehy drogenation over Mg3Fe0.5−xCoxAl0.5 catalysts derived from hydrotalcites: Comparison with Mg3Fe0.5−y NiyAl0.5 catalysts.” En Applied Catalysis A: General, 396, 107–115. BAGHALHA, M. & EBRAHIMPOUR, O.(2007). “Structural changes and surface activities of ethylbenzene dehydrogenation catalysts during deactivation.” En Applied Catalysis A: General, 326, 143–151. BALASAMY, R.J., KHURSHID, A., Al-Ali, A.A.S., ATANDA, L.A., SAGATA, K., ASAMOTO, M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. & Al-Khattaf, S.S. (2010). “Ethylbenzene dehydrogenation over binary FeOx–MeOy/Mg(Al)O catalysts derived from hydrotalcites”. En Applied Catalysis A: General, 390, 225–234. BALASAMY, R.J., Tope, B.B., KHURSHID, A., AL-ALI, A., ATANDA, L.A., SAGATA, K., ASAMOTO,M., YAHIRO, H., NOMURA, K., SANO, T., TAKEHIRA, K. y Al-KHATTAF, S.S. (2011). “Ethylbenzene dehydrogenation over FeOx/(Mg,Zn)(Al)O catalysts derived from hydrotalcites: Role of MgO as basic sites”. En Applied Catalysis A: General, 398, 113–122. BALKRISHNA B. Tope, RABINDRAN J. BALASAMY, ALAM Khurshid, LUQMAN A. ATANDA, HIDENORI Yahiro, TETSUYA Shishido, KATSUOMI Takehira, SULAIMAN S. Al-KHATTAF. (2011). “Catalytic mechanism of the dehydrogenation of ethylbenzene over Fe–Co/Mg(Al)O derived from hydrotalcites”. En Applied Catalysis A: General, 407, 118– 126. BAUTISTA, F., Campelo, J., LUNA, D., MARINAS, J., QUIROS, R. & ROMERO, A. (2007). “Screening of amorphous metal–phosphate catalysts for the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis B, 70, 611–620. BISPO, J.R.C., OLIVEIRA, A.C., CORREA, M.L.S., FIERRO, J.L.G., MARCHETTI, S.G. & RANGEL, M.C.(2002). “Characterization of FeMCM-41 and FeZSM-5 Catalysts Production to Styrene”. En Studies in Surface Science and Catalysis, 142, 517-524. BLANCO, J. y LINARTE, R. (1971). Catálisis, fundamentos y aplicaciones industriales. México: Ed. Trillar. BOND, G.C. (1962). Catalysis by Metals. London: Academic Press. BOSA Poveda, J. (1994). Estudio de la deshidrogenación catalítica del etilbenceno a estireno en un reactor de lecho fijo. Tesis Ing. Química. Universidad Nacional de Colombia. Bogotá. BURRI, D.R., CHOI, K.M., HAN, D.S., Koo, J.B. & PARK, S.E. (2006). “CO2 utilization as an oxidant in the dehydrogenation of ethylbenzene to styrene over MnO2-ZrO2 catalysts”. En Catalysis Today, 115, 242–247. BURRI, D.R., CHOI, K.M., LEE, J.H., HAN, D.S. & PARK, S.E. (2007). “Influence of SBA-15 support on CeO2–ZrO2 catalyst for the dehydrogenation of ethylbenzene to styrene with CO2”. En Catalysis Communications, 8, 43–48. BURRI, D.J., CHOI, K.M., HAN, S.C., BURRI, A., & PARK, S.E. (2007). “Selective conversion of ethylbenzene into styrene over K2O/TiO2-ZrO2 catalysts: Unified effects of K2 O and CO2”. En Journal of Molecular Catalysis A: Chemical, 269, 58–63. CAMPANATI, M., FORNASANI, G. Y VACCARI, A. (2003). “Fundamentals in the preparation of heterogeneous catalysts”. En Catalysis Today, 77, 299-314. CARBALLO, L. (2002). Introducción a la Catálisis Heterogénea. Facultad de Ingeniería, Universidad Nacional de Colombia, Bogotá: ed. Unidad de Publicaciones. CARBERRY, J.I. (1980). Ingeniería de las Reacciones Químicas y Catalíticas. Buenos Aires: Editorial Géminis S. R. L. CARJA, G., KAMESHIMA, Y. & OKADA, K. (2008). “Nanoparticles of iron and vanadium oxides supported on iron substituted LDHs: Synthesis, textural characterization and their catalytic behavior in ethylbenzene dehydrogenation”. En Microporous and Mesoporous Materials, 115, 541–547. CARJA, G., NAKAMURA, R. Aida, T. & NIIYAMA, H. (2003). “Mg–V–Al mixed oxides with mesoporous properties using layered double hydroxides as precursors: catalytic behavior for the process of ethylbenzene dehydrogenation to styrene under a carbon dioxide flow”. En Journal of Catalysis, 218, 104–110. CAUSADO, R. (2005). Desarrollo de Nuevos Catalizadores tipo NiMo, NiMo/CaO, FeMo, Fe2O3/CaO y Mo/γ-Al2 O3 como posibles alternativas para la reacción de Deshidrogenación de Etilbenceno en presencia de CO2 y vapor de agua en la producción de Estireno. Tesis para obtención del grado de Químico, Unicartagena–Licatuc (Colombia). CHEN Shuwei, QIN Zhangfeng, SUN Ailing & WANG Jianguo. (2009). Effects of Li Promoter on the Catalytic Performance of Fe-Li/AC for Ethylbenzene Dehydrogenation in the Presence of CO2. Chin J Catal, 30(4), 359–364. CHEN, S., Qin, Z., XU, X. & Wang, J. (2006). “Structure and properties of the alumina-supported vanadia catalysts for ethylbenzene dehydrogenation in the presence of carbon dioxide”. En Applied Catalysis A: General, 302, 185–192. CONCEIÇÃO Oliveira A. & DO CARMO Rangel, M. (2003). “Desidrogenação Do Etilbenzeno Sobre Compostos De Ferro E Alumínio”. En Quim. Nova, 26(2), 170-176. CONCEIÇÃO, A., FIERRO, J., VALENTÍN, A., SANTANA, P. y DO CARMO, M. (2003). Catalysis Today, 85, 49-57. DE ARAÚJO J., SOUSA C., OLIVEIRA A., FREIRE, F., AYALA, A. y OLIVEIRA, A. (2010). “Dehydrogenation of ethylbenzenewith CO2 to produce styrene over Fe-containing ceramic composites”. En Applied Catalysis A: General, 377, 55–63. DE MORAIS Batista, RAMOS A.H., BRAGA F.S.O., LIMA T.P., , C.L., DE SOUSA, F.F., BARROS, E.B.D., FILHO, J.M., de Oliveira, A.S., de Sousa, J.R., VALENTINI, A. & Oliveira, A.C. (2010). “Mesoporous MAl2 O4 (M= Cu, Ni, Fe or Mg) spinels: Characterisation and application in the catalytic dehydrogenation of ethylbenzene in the presence of CO2”. En Applied Catalysis A: General, 382, 148–157. DE SOUZA Ramos, M., DE SANTANA Santos, M., PACHECO Gomes, L., ALBORNOZ, A. y DO CARMO Rangel M. (2008). “The influence of dopants on the catalytic activity of hematite in the ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 341, 12–17. DIAS Holtz, R., DE OLIVEIRA, S.B., FRAGA, M.A. & DO CARMO Rangel, M. (2008). “Synthesis and characterization of polymeric activated carbon-supported vanadium and magnesium catalysts for ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 350, 79–85. DROGUETT, S. (1983). Elementos de la Catálisis Heterogénea. Monografía N° 26. Secretaría General de la Organización de los Estados Americanos. Washington, D.C. 12-15, 38-40 y 90-91. DULAMITA, N., MAICANEANU A., SAYLE D.C., STANCA, M., CRACIUN, R., OLEA, M., AflOROAEI, C. y FODOR, A.(2005). “Ethylbenzene dehydrogenation on Fe2O3-Cr2O3-K2CO3 catalysts promoted with transitional metal oxides”. En Applied Catalysis A: General, 287, 9–18. DZIEWIECKI, Z. & OZDOBA, E. (1991). Preparation of Catalysts V. Amsterdam: Elsevier Science Publishers B.V. FAROLDOS, M. y GOBERNA, C. (2002). Técnicas en el análisis y caracterización de materiales. Consejo Superior de Investigaciones Científicas, CSIC. Madrid, España. FREIRE, R.M., DE SOUSA, F.F., PINHEIRO, A.L., LONGHINOTTI, E., MENDES Filho, J., OLIVEIRA, A.C., DE TARSO, P., FREIRE, C., AYALA, A.P. & OLIVEIRA, A.C.(2009). “Studies of catalytic activity and coke deactivation of spinel oxides during ethylbenzene dehydrogenation”. En Applied Catalysis A: General, 359, 165–179. GAO, Z., ZHANG, B. Y CUI, J. (1991). Applied Catalysis A: General, 12, 332 HABER, J. (1991). “Manual on Catalyst Characterization”. En Pure and Applied Chemistry, 63 (9), 1227-1246. HONG, D.Y., CHANG, J.S., LEE, J.H., VISLOVSKIY, W.P., JHUNG, S.H., PARK, S.E. & PARK, Y.H. (2006). “Effect of carbon dioxide as oxidant in dehydrogenation of ethylbenzene over alumina-supported vanadium–antimony oxide catalyst”. En Catalysis Today, 112, 86–88. HUERTA, L., MEYER, A. & CHOREN, E. (2003). “Synthesis, characterization and catalytic application for ethylbenzene dehydrogenation of an iron pillared clay”. En Microporous and Mesoporous Materials, 57, 219–227. HURST, N.W., GENTRY, S.J., JONES, A. y MCNICOL, B.D. (1982). Temperature Programmed Reduction. Catal. Rev. Sci. Eng. 24 (2), 233-309. IKENAGA, N.O., TSURUDA, T., SENMA, K., YAMAGUCHI, T., SAKURAI, Y. & SUZUKI, T. (2000). “Dehydrogenation of Ethylbenzene with Carbon Dioxide Using Activated Carbon-Supported Catalysts”. En Ind. Eng. Chem. Res. 39, 1228-1234. JI, M., CHEN, G., WANG, J., WANG, X. y ZHANG, T. (2010). “Dehydrogenation of ethylbenzene to styrene with CO2 over iron oxide-based catalysts”. En Catalysis Today. 158, 464–469. JONES, A. & MCNICOL, B.D. ( 1986). “Temperature-Programmed Reduction for Solid Materials Characterization”. En Chemical Industries/24. Usa: Marcel Dekker, Inc. KHATAMIAN, M., KHANDAR, A.A., HAGHIGHI, M. & GHADIRI, M. (2011). “Nano ZSM-5 type ferrisilicates as novel catalysts for ethylbenzenedehydrogenation in the presence of N2O”. En Applied Surface Science. 258, 865– 872. KIRK, Othmer. (1997). Enciclopedia of Chemical Technology, 4ta Edición KOTARBA, A., BIENIASZ, W., KUSTROWSKI, P., STADNICKA, K. & SOJKA, Z. (2011). “Composite ferrite catalyst for ethylbenzene dehydrogenation: Enhancement ofpotassium stability and catalytic performance by phase selective doping”. En Applied Catalysis A: General. 407, 100–105. KUSTROWSKI, P., ŁASOCHA, A.R., MAJDA, D., TOMASZEWSKA, D. & DZIEMBAJ, R. (2001). “Preparation and characterization of new Mg–Al–Fe oxide catalyst precursors for dehydrogenation of ethylbenzene in the presence of carbon dioxide”. En Solid State Ionics.141–142, 237–242. LANGE, Jean-Paul y OTTEN, Vincent. (2006). “Dehydration of phenyl-ethanol to styrene: Zeolite catalysis under reactive distillation”. En Journal of Catalysis.238, 6–12. LI, Z., & SHANKS, E.H. (2011). “Role of Cr and V on the stability of potassium-promoted iron oxides used as catalysts in ethylbenzene dehydrogenation”. En Aplied Catalysis A: General. 405, 101– 107. LIAO, S.J., CHEN, T., MIAO, C.X., YANG, W.M., Xie, Z.K. & CHEN, Q.L. (2008). “Effect of TiO2 on the structure and catalytic behavior of iron–potassium oxide catalyst for dehydrogenation of ethylbenzene to styrene”. En Catalysis Communications. 9, 1817–1821. MATSUI, J., SODESAWA, T. y NURAKI, F. (1990). “Influence of carbon dioxide addition upon decay of activity of a potassium-promoted iron oxide catalyst for dehydrogenation of ethylbenzene”. En Applied Catalysis A: General. 67, 179. Meima, G.R. & MENON, P.G. (2001). “Catalyst deactivation phenomena in styrene production”. En Applied Catalysis A: General. 212, 239–245. MIMURA, N. & SAITO, M. (2000). “Dehydrogenation of ethylbenzene to styrene over Fe2 O3/Al2O3 catalysts in the presence of carbon dioxide”. En Catalysis Today. 55. 173–178. Mimura, N. y Saito, M. (1999). “Dehydrogenation of ethylbenzene to styrene over Fe2O3/Al2O3 catalysts in the presence of carbon dioxide”. En Catalysis Today. 55, 173-178. MIMURA, N., TAKANARA, L., SAITO, M., HATTORI, T., OHKUMA, M. y ANDO, M. (1998). “Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide”. En Catalysis Today. 45, 61. MIMURA, N., TAKANARA, L., SAITO, M., HATTORI, T., OHKUMA, M. y ANDO, M. (1998). “Dehydrogenation of ethylbenzene over iron oxide-based catalyst in the presence of carbon dioxide”. En Studies Surfaces Catalysis.114, 415. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “Mn-substituted Fe–K mixed oxide catalysts for dehydrogenation of ethylbenzene towards styrene”. En Applied Catalysis A: General. 216, 137–146. MIYAKOSHI, A., UENO, A. y ICHIKAWA, M. (2001). “XPS and TPD characterization of manganesesubstituted iron–potassium oxide catalysts which are selective for dehydrogenation of ethylbenzene into styrene”. En Applied Catalysis A: General. 219, 249–258. MONTI, D.A.M. & BAIKER, A. (1983). “Temperature-Programmed Reduction. Parametric Sensitivity and Estimation of Kinetic Parameters”. En Journal of Catalysis. 83 323-335. MORONTA, A., TROCONIS, M.E., GONZÁLEZ, E., MORÁN, C., SÁNCHEZ, J., GONZÁLEZ, A. & QUIÑÓNEZ, J. (2006). Dehydrogenation of ethylbenzene to styrene catalyzed by Co, Mo and CoMo catalysts supported on natural and aluminum-pillared clays. Effect of the metal reduction. Applied Catalysis A: General.310, 199–204. NEDERLOF, C., KAPTEIJN, F. & MAKKEE, M. (2012). “Catalysed ethylbenzene dehydrogenation in CO2 or N2 Carbon deposits as theactive phase”. En Applied Catalysis A: General. 417– 418, 163– 173. NEDERLOF, C., TALAY, G., KAPTEIJN, F.& MAKKEE, M. (2012). “The role of RWGS in the dehydrogenation of ethylbenzene to styrene in CO2”. En Applied Catalysis A: General.423– 424, 59– 68. NIETO, S. (2001). Síntesis y caracterización de molibdatos y heteropolimolibdatos de cobre como posible utilización en catálisis. Tesis para obtención del grado de Químico. Universidad de Cartagena-I.V.I.C. Cartagena. NOGUEIRA, I.M., SABADIA, G. Q., MOREIRA, A.A., FILHO, J.M. & OLIVEIRA, A.C. (2011). “Investigation of the deactivation of iron nanocomposites by coking in dehydrogenation of ethylbenzene”. En Journal of Molecular Catalysis A: Chemical. 351, 81– 92. OHISHI, Y., KAWABATA, T., SHISHIDO, T., TAKAKI, K., ZHANG, Q., WANG, Y., NOMURA, K. & Takehira, K. (2005). “Mg–Fe–Al mixed oxides with mesoporous properties prepared from hydrotalcite as precursors: Catalytic behavior in ethylbenzene dehydrogenation”. En Applied Catalysis A: General. 288, 220–231. PARK, M.S., VISLOVSKIY, V.P., CHANG, J.S., SHUL, Y.G., YOO, J.S. & PARK, S.E.(2003). “Catalytic dehydrogenation of ethylbenzene with carbon dioxide: promotional effect of antimony in supported vanadium–antimony oxide catalyst”. En Catalysis Today. 87, 205–212. PENG Feng, FU Xiao-bo, YU Hao, WANG Hong-Juan.(2007). Preparation of carbon nanotube-supported Fe2 O3 catalysts and their catalytic activities for ethylbenzene dehydrogenation. New Carbon Materials. 22 (3), 213–217. PINHEIRO Braga, T., LONGHINOTTI, E., PINHEIRO, A.N. & VALENTINI, A. (2009). “Synthesis of hybrid spheres for the dehydrogenation of ethylbenzene in the presence of CO2”. En Applied Catalysis A: General. 362, 139–146. PONOMOREVA, O.A, YUSCHENKO, V.V., LVANOVA, I.I., PASQUA, L., TESTA, F., Di RENZO, F. & FAJULA, F. (2004). “Dehydrogenation of Ethylbenzene Over Ga-And Fe-Containing MCM-41”. En Studies in Surface Science and Catalysis. 154, 2208-2211. ROSSETTI, I., BENCINI, E., TRENTINI, L., FORNI, L. (2005). “Study of the deactivation of a commercial catalyst for ethylbenzene dehydrogenation to styrene”. En Applied Catalysis A: General. 292, 118–123. SAITO, K., OKUDA, K., IKENAGA, N.O., MIYAKE, T. & SUZUKI, T. (2010). “Role of Lattice Oxygen of Metal Oxides in the Dehydrogenation of Ethylbenzene under a Carbon Dioxide Atmosphere”. En J. Phys. Chem. A. 114, 3845–3854. Saito, M., KIMURA, H., MIMURA, N., Wu, J. y MURATA, K. (2003). “Dehydrogenation of ethylbenzene in the presence of CO2 over an alumina-supported iron oxide catalyst”. En Applied Catalysis A: General. 239, 71-77. SAITO, M., KIMURA, H., MIMURA, N., WU, J. y MURATA, K. (2003). “Dehydrogenation of ethylbenzene in the presence of CO2 over an alumina-supported iron oxide catalyst”. En Applied Catalysis A: General. 239, 71-77. SAKURAI, Y., SUZAKI, T., NAKAGAWA, K., IKENAGA, N., AOTA, H. y Suzuki, T. (2002). Journal of Catalysis. 209(1),16-24. SANTOS M.D.S., ALBORNOZ, A. & DO CARMO Rangel, M. (2006). “The influence of the preparation method on the catalytic properties of Lanthanum-doped hematite in the ethylbenzene dehydrogenation”. En Scientific Bases for the Preparation of Heterogeneous Catalysts. Elsevier B.V, 753-760. SANTOS, M.D.S., MARCHETTI, S.G., ALBORNOZ, A. & DO CARMO Rangel, M. (2008). “Effect of lanthanum addition on the properties of potassium-free catalysts for ethylbenzene dehydrogenation”. En Catalysis Today. 133–135 160–167. SECRETARÍA GENERAL DE LA ORGANIZACIÓN DE LOS ESTADOS AMERICANOS (1980). La espectroscopía infrarroja. Washington, D.C. SHEKHAH, O., RANKE, W. & SCHLÖGL, R. (2004). “Styrene synthesis: in situ characterization and reactivity studies of unpromoted and potassium-promoted iron oxide model catalysts”. En Journal of Catalysis. 225, 56–68. STYLES, A. B. (1983). Applied Industrial Catalysis. New York: Academic Press. SUGINO, M., SHIMADA, H., TURUDA, T., MIURA, H., IKENAGA, N. & SUZUKI, T. (1995). “Oxidative dehydrogenation of ethylbenzene with carbon dioxide”. En Applied Catalysis A: General.121, 125-137. SUN, A., QIN, Z., Chen, S. & WANG, J. (2004). “Ethylbenzene dehydrogenation in the presence of carbon dioxide over alumina supported catalysts”. En Catalysis Today. 93–95, 273–279. SUN, A., QIN, Z., CHEN, S. & WANG, J. (2004). “Role of carbon dioxide in the ethylbenzene dehydrogenation coupled with reverse water–gas shift”. En Journal of Molecular Catalysis A: Chemical. 210, 189–195. VISLOVSKIY, V.P., CHANG, J.S., PARK, M.S. & PARK, S.E. (2002). “Ethylbenzene into styrene with carbon dioxide over modified vanadia–alumina catalysts”. En Catalysis Communications. 3, 227–231. XIANG Bin, XU HENGYONG & LI Wenzhou. (2007). “Highly efficient nano-sized Fe2 O3–K2 O catalyst for dehydrogenation of ethylbenzene to styrene”. En Chinese Journal of Catalysis. 28(10). 841–843. XU, J., HUANG, J., LIU, Y., Cao, Y.,Li, Y. y FAN, K. (2011). Catal. Lett. 141, 198–206. XU, J., XUE, B., LIU, Y., LI, Y., CAO Y. y FAN, K. (2011). “Mesostructured Ni-doped ceria as an efficient catalyst for styrene synthesis by oxidative dehydrogenation of ethylbenzene”. En Applied Catalysis A: General. 405, 142–148. YE, X., MA, N., HUA, W., YUE, Y., MIAO, C., XIE, Z. & GAO, Z. (2004). “Dehydrogenation of ethylbenzene in the presence of CO2 over catalysts prepared from hydrotalcite-like precursors”. En Journal of Molecular Catalysis A: Chemical. 217, 103–108. ZHAO, T.J., SUN, Y.J., GU, X.Y., LI, P., CHEN, D., DAI, D.Y., YUAN, W.K. & Holmen, A. (2006). “Dehydrogenation of ethylbenzene with carbon nanofiber supported iron oxide carbon dioxide over”. En Studies in Surface Science and Catalysis, 159, 741-744. ZHU, X.M., SCHÖN, M., BARTMANN, U., VAN VEEN, A.C. y MUHLER, M. (2004). “The dehydrogenation of ethylbenzene to styrene over a potassium-promoted iron oxide-based catalyst: a transient kinetic study”. En Applied Catalysis A: General. 266, 99–108. ZHYZNEVSKIY, V.M., TSYBUKH, R.D., GUMENETSKIY V.V. y KOCHUBEIY V.V. (2003). “Physicochemical and catalytic properties of Fe2 BiMo2 Ox catalyst ultrasound treated and promoted with Al2O3 in the oxidative dehydrogenation of ethylbenzene to styrene”. En Applied Catalysis A: General. 238, 19–28info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2https://creativecommons.org/licenses/by-nc-sa/4.0/https://revistas.usb.edu.co/index.php/GuillermoOckham/article/view/603deshidrogenacióndesactivación catalíticaetilbencenoestirenoDeshidrogenación catalítica del etilbenceno a estirenoDeshidrogenación catalítica del etilbenceno a estirenoArtículo de revistahttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85Textinfo:eu-repo/semantics/articleJournal articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionPublicationOREORE.xmltext/xml2614https://bibliotecadigital.usb.edu.co/bitstreams/bbd86aba-d658-44cb-9c4a-14b3390a7916/download00d31a72d113b3c6e087ab8f2b803502MD5110819/26052oai:bibliotecadigital.usb.edu.co:10819/260522025-07-31 12:11:51.113https://creativecommons.org/licenses/by-nc-sa/4.0/https://bibliotecadigital.usb.edu.coRepositorio Institucional Universidad de San Buenaventura Colombiabdigital@metabiblioteca.com