Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos
46 páginas : gráficas
- Autores:
-
Posada Correa, Uriel Armando
- Tipo de recurso:
- Trabajo de grado de pregrado
- Fecha de publicación:
- 2020
- Institución:
- Universidad de Ciencias Aplicadas y Ambientales U.D.C.A
- Repositorio:
- Repositorio Institucional UDCA
- Idioma:
- spa
- OAI Identifier:
- oai:repository.udca.edu.co:11158/3453
- Acceso en línea:
- https://repository.udca.edu.co/handle/11158/3453
- Palabra clave:
- Química Computacional
Algoritmos genéticos
Mecanismos de reacción orgánica
2-norbonil
Superficie de energía potencial
- Rights
- openAccess
- License
- Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales
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Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| title |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| spellingShingle |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos Química Computacional Algoritmos genéticos Mecanismos de reacción orgánica 2-norbonil Superficie de energía potencial |
| title_short |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| title_full |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| title_fullStr |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| title_full_unstemmed |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| title_sort |
Obtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticos |
| dc.creator.fl_str_mv |
Posada Correa, Uriel Armando |
| dc.contributor.advisor.spa.fl_str_mv |
Ortíz Verano, Ismael, dir. Moreno Rodríguez, Diego Vicente, dir. |
| dc.contributor.author.spa.fl_str_mv |
Posada Correa, Uriel Armando |
| dc.subject.mesh.spa.fl_str_mv |
Química Computacional |
| topic |
Química Computacional Algoritmos genéticos Mecanismos de reacción orgánica 2-norbonil Superficie de energía potencial |
| dc.subject.lemb.spa.fl_str_mv |
Algoritmos genéticos Mecanismos de reacción orgánica |
| dc.subject.proposal.spa.fl_str_mv |
2-norbonil Superficie de energía potencial |
| description |
46 páginas : gráficas |
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2020 |
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2020-08-04T19:19:28Z |
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2020-08 |
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Trabajo de grado - Pregrado |
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International Union of Pure and Applied Chemistry. Chemical Reaction. In IUPAC Compendium of Chemical Terminology, page 262. IUPAC, Research Triagle Park, NC, 2014. Eric W-G Diau, Steven De Feyter, and Ahmed H Zewail. Femtosecond dynamics of retro Diels-Alder reactions: the concept of concertedness. Technical report, Institute of technology, 1999. Brett R Beno, K N Houk, and Daniel A Singleton. Synchronous or Asynchronous? An “Experimental” Transition State from a Direct Comparison of Experimental and Theoretical Kinetic Isotope Effects for a Diels-Alder Reaction. Technical Report 1, University of california, 1995. Vildan Guner, Kelp S. Khuong, Andrew G. Leach, Patrick S. Lee, Michael D. Bartberger, and K. N. Houk. A Standard Set of Pericyclic Reactions of Hydrocarbons for the Benchmarking of Computational Methods: The Performance of ab Initio, Density Functional, CASSCF, CASPT2, and CBS-QB3 Methods for the Prediction of Activation Barriers, Reaction Energetics, and Transition State Geometries. Journal of Physical Chemistry A, 107(51):11445–11459, 12 2003. Kevin A. Lobb. Isomerization of the 2-Norbornyl Carbocation. European Journal of Organic Chemistry, 2015(24):5370–5380, 8 2015. International Union of Pure and Applied Chemistry. Mechanism of a reaction. In IUPAC Compendium of Chemical Terminology, page 902. IUPAC, Research Triagle Park, NC, 9 2008. Ira N Levine. Qu´ımica Cuantica. Pearson Educacion, Madrid, 5 edition, 2005. International Union of Pure and Applied Chemistry. Transition State. In Compendium of Chemical Terminology. IUPAC, 2 edition, 9 2008. Vicente Moliner Ib´a˜nez. Mecanismos Moleculares de Reacciones Enzim´aticas y Estructuras de Transici´on: Estudios Te´oricos. PhD thesis, Universitat Jaume I, 1993. Gabriel Cuevas and Fernando Cortes. Introducci´on a la Qu´ımica Computacional. Fondo de cultura economica, Mexico, 1 edition, 2003. J C Slater. MOLECULAR ENERGY LEVELS AND VALENCE BONDS The first part of the discussion, in sections i to 4, deals with the general. Technical report, 1929. Universidad de la Rioja. Conceptos b´asicos de mec´anica cu´antica. Technical report, Universidad de la Rioja, Madrid, 2011. James B Foresman and Aeleen Frisch. Exploring Chemistry With Electronic Structure Methods. University of Michigan, Pittsburgh, 2 edition, 1996. Lucjan Piela. Ideas of cuantum chemistry. Elsevier, Amsterdam, 1 edition, 2007. James P. Finley. Using the local density approximation and the LYP, BLYP and B3LYP functionals within reference-state one-particle density-matrix theory. Molecular Physics, 102(7):627–639, 4 2004. Yan Zhao and Donald G. Truhlar. The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: Two new functionals and systematic testing of four M06-class functionals and 12 other functionals. Theoretical Chemistry Accounts, 120(1-3):215–241, 5 2008. Jhon Holland. Adaptation in Natural and Artificial Systems. Bradford Books, Michigan, 1975. Ant´onio Gaspar Cunha, Ricardo Takahashi, Carlos Henggeler Antunes, and Francisco J. B. Pereira. Algoritmos gen´eticos. In Manual de computa¸c˜ao evolutiva e metaheur´ıstica, pages 25–47. Imprensa da Universidade de Coimbra, 2014. Aloysius George, B. R. Rajakumar, and D. Binu. Genetic algorithm based airlines booking terminal open/close decision system. In ACM International Conference Proceeding Series, pages 174–179, 2012. Monica Patrascu. Genetically enhanced modal controller design for seismic vibration in nonlinear multi-damper configuration. Proceedings of the Institution of Mechanical Engineers. Part I: Journal of Systems and Control Engineering, 229(2):158–168, 2 2015. J. R. Parker. Algorithms for Image Processing and Computer Vision. Wiley Publishing Inc., john wiley & sons edition, 2011. Poonam Garg and Atul Garg. A Comparison between Memetic algorithm and Genetic algorithm for the cryptanalysis of Simplified Data Encryption Standard algorithm. In Proceedings of the 2008 International Conference on Security and Management, SAM 2008, pages 443–448, 2008. Kumar Chellapilla and David B Fogel. Evolution, Neural Networks, Games, and Intelligence. Proceedings of the IEEE, 1999. Lionel Elliott, Derek B. Ingham, Adrian G. Kyne, Nicolae S. Mera, Mohamed Pourkashanian, and Christopher W. Wilson. Reaction mechanism reduction and optimization using genetic algorithms. Industrial and Engineering Chemistry Research, 44(4):658– 667, 2 2005. Jeffrey M. Blaney and J. Scott Dixont. Distance Geometry in Molecular Modeling. In Reviews in Computational Chemistry, volume 5, pages 299–335. Wiley-VCH Verlag, 1 2007. Jan T. Pedersen and John Moult. Genetic algorithms for protein structure prediction. Current Opinion in Structural Biology, 6(2):227–231, 1996. Diego Moreno. Kaxan: Un programa de b´usqueda de m´ınimos globales empleando estrategias evolutivas. PhD thesis, M´erida, 2016. Peter R. Schreiner, Hans Peter Reisenauer, Frank C. Pickard Iv, Andrew C. Simmonett, Wesley D. Allen, Edit M´atyus, and Attila G. Cs´asz´ar. Capture of hydroxymethylene and its fast disappearance through tunnelling. Nature, 453(7197):906–909, 6 2008. Andrew G Leach and E Goldstein. Energy Contour Plots: Slices through the Potential Energy Surface That Simplify Quantum Mechanical Studies of Reacting Systems. Technical Report 3, University of california, 2006. |
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Derechos Reservados - Universidad de Ciencias Aplicadas y Ambientales |
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Ortíz Verano, Ismael, dir.Moreno Rodríguez, Diego Vicente, dir.Posada Correa, Uriel Armando2020-08-04T19:19:28Z2020-08-04T19:19:28Z2020-08https://repository.udca.edu.co/handle/11158/345346 páginas : gráficasLos algoritmos genéticos han sido implementados cada vez mas en diversos campos de estudio Particularmente en el caso de la química computacional, donde se han convertido en una herramienta ´útil para en estudio de mecanismos de reacción como soporte a los estudios experimentales. A nivel experimental, el estudio de mecanismos de reacción representa un reto, ya que los estados de transición involucrados en estos mecanismos, son compuestos con un tiempo de vida media muy corto que dificulta la medición precisa de diversas propiedades, entre ellas su geometría molecular. En este trabajo, haciendo uso de los algoritmos gen éticos implementados en el programa Kaxan, se pudieron determinar la existencia de estados de transición e intermediarios de reacción en la síntesis de formaldehido, síntesis de ciclohexeno por reacción de Diels-Alder y la isomerización del 2-norbonil. Adicionalmente, con los estados de transición e intermediarios encontrados, se pudieron proponer los respectivos perfiles de reacción para cada uno de los procesos químicos ya mencionados. Los datos analizados evidencian que es posible construir los perfiles de reacción a partir del uso de los algoritmos genéticos.The use of Genetic Algorithms (GAs) have been widely spread among different fields of study. In the particular case of Computational Chemistry, GAs have been used to propose reaction mechanisms as support to experimental studies, in which the estimation of such mechanisms is limited due to the instability of the intermediary compounds, also known as transition states. In this work, GAs implemented in Kaxan software package have been used to determine the existence of transition states and reaction intermediaries of formaldehyde synthesis, DielsAlder cyclohexene synthesis, and 2-Norboryl isomerization. Finally, these transitions states and reaction intermediaries were used to propose the reaction profile for each of the mentioned chemical processes.Results from this research suggest that genetic algorithms can be used as a tool to elucidate reaction profiles.Incluye bibliografíaPregradoQuímico(a)application/pdfspaBogotá : Universidad de Ciencias Aplicadas y Ambientales, 2020Facultad de CienciasQuímicaDerechos Reservados - Universidad de Ciencias Aplicadas y Ambientaleshttps://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessAtribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)http://purl.org/coar/access_right/c_abf2Química ComputacionalAlgoritmos genéticosMecanismos de reacción orgánica2-norbonilSuperficie de energía potencialObtención de perfiles de reacción de diversos compuestos utilizando algoritmos genéticosTrabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_7a1finfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/publishedVersionTexthttp://purl.org/redcol/resource_type/TPhttp://purl.org/coar/version/c_970fb48d4fbd8a85International Union of Pure and Applied Chemistry. Chemical Reaction. In IUPAC Compendium of Chemical Terminology, page 262. IUPAC, Research Triagle Park, NC, 2014.Eric W-G Diau, Steven De Feyter, and Ahmed H Zewail. Femtosecond dynamics of retro Diels-Alder reactions: the concept of concertedness. Technical report, Institute of technology, 1999.Brett R Beno, K N Houk, and Daniel A Singleton. Synchronous or Asynchronous? An “Experimental” Transition State from a Direct Comparison of Experimental and Theoretical Kinetic Isotope Effects for a Diels-Alder Reaction. Technical Report 1, University of california, 1995.Vildan Guner, Kelp S. Khuong, Andrew G. Leach, Patrick S. Lee, Michael D. Bartberger, and K. N. Houk. A Standard Set of Pericyclic Reactions of Hydrocarbons for the Benchmarking of Computational Methods: The Performance of ab Initio, Density Functional, CASSCF, CASPT2, and CBS-QB3 Methods for the Prediction of Activation Barriers, Reaction Energetics, and Transition State Geometries. Journal of Physical Chemistry A, 107(51):11445–11459, 12 2003.Kevin A. Lobb. Isomerization of the 2-Norbornyl Carbocation. European Journal of Organic Chemistry, 2015(24):5370–5380, 8 2015.International Union of Pure and Applied Chemistry. Mechanism of a reaction. In IUPAC Compendium of Chemical Terminology, page 902. IUPAC, Research Triagle Park, NC, 9 2008.Ira N Levine. Qu´ımica Cuantica. Pearson Educacion, Madrid, 5 edition, 2005.International Union of Pure and Applied Chemistry. Transition State. In Compendium of Chemical Terminology. IUPAC, 2 edition, 9 2008.Vicente Moliner Ib´a˜nez. Mecanismos Moleculares de Reacciones Enzim´aticas y Estructuras de Transici´on: Estudios Te´oricos. PhD thesis, Universitat Jaume I, 1993.Gabriel Cuevas and Fernando Cortes. Introducci´on a la Qu´ımica Computacional. Fondo de cultura economica, Mexico, 1 edition, 2003.J C Slater. MOLECULAR ENERGY LEVELS AND VALENCE BONDS The first part of the discussion, in sections i to 4, deals with the general. Technical report, 1929.Universidad de la Rioja. Conceptos b´asicos de mec´anica cu´antica. Technical report, Universidad de la Rioja, Madrid, 2011.James B Foresman and Aeleen Frisch. Exploring Chemistry With Electronic Structure Methods. University of Michigan, Pittsburgh, 2 edition, 1996.Lucjan Piela. Ideas of cuantum chemistry. Elsevier, Amsterdam, 1 edition, 2007.James P. Finley. Using the local density approximation and the LYP, BLYP and B3LYP functionals within reference-state one-particle density-matrix theory. Molecular Physics, 102(7):627–639, 4 2004.Yan Zhao and Donald G. Truhlar. The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: Two new functionals and systematic testing of four M06-class functionals and 12 other functionals. Theoretical Chemistry Accounts, 120(1-3):215–241, 5 2008.Jhon Holland. Adaptation in Natural and Artificial Systems. Bradford Books, Michigan, 1975.Ant´onio Gaspar Cunha, Ricardo Takahashi, Carlos Henggeler Antunes, and Francisco J. B. Pereira. Algoritmos gen´eticos. In Manual de computa¸c˜ao evolutiva e metaheur´ıstica, pages 25–47. Imprensa da Universidade de Coimbra, 2014.Aloysius George, B. R. Rajakumar, and D. Binu. Genetic algorithm based airlines booking terminal open/close decision system. In ACM International Conference Proceeding Series, pages 174–179, 2012.Monica Patrascu. Genetically enhanced modal controller design for seismic vibration in nonlinear multi-damper configuration. Proceedings of the Institution of Mechanical Engineers. Part I: Journal of Systems and Control Engineering, 229(2):158–168, 2 2015.J. R. Parker. Algorithms for Image Processing and Computer Vision. Wiley Publishing Inc., john wiley & sons edition, 2011.Poonam Garg and Atul Garg. A Comparison between Memetic algorithm and Genetic algorithm for the cryptanalysis of Simplified Data Encryption Standard algorithm. In Proceedings of the 2008 International Conference on Security and Management, SAM 2008, pages 443–448, 2008.Kumar Chellapilla and David B Fogel. Evolution, Neural Networks, Games, and Intelligence. Proceedings of the IEEE, 1999.Lionel Elliott, Derek B. Ingham, Adrian G. Kyne, Nicolae S. Mera, Mohamed Pourkashanian, and Christopher W. Wilson. Reaction mechanism reduction and optimization using genetic algorithms. Industrial and Engineering Chemistry Research, 44(4):658– 667, 2 2005.Jeffrey M. Blaney and J. Scott Dixont. Distance Geometry in Molecular Modeling. In Reviews in Computational Chemistry, volume 5, pages 299–335. Wiley-VCH Verlag, 1 2007.Jan T. Pedersen and John Moult. Genetic algorithms for protein structure prediction. Current Opinion in Structural Biology, 6(2):227–231, 1996.Diego Moreno. Kaxan: Un programa de b´usqueda de m´ınimos globales empleando estrategias evolutivas. PhD thesis, M´erida, 2016.Peter R. Schreiner, Hans Peter Reisenauer, Frank C. Pickard Iv, Andrew C. Simmonett, Wesley D. Allen, Edit M´atyus, and Attila G. Cs´asz´ar. Capture of hydroxymethylene and its fast disappearance through tunnelling. Nature, 453(7197):906–909, 6 2008.Andrew G Leach and E Goldstein. Energy Contour Plots: Slices through the Potential Energy Surface That Simplify Quantum Mechanical Studies of Reacting Systems. 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 nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.
d.	Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
i.	Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.
ii.	Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.
e.	Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, Acinpro), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.
5. Representaciones, Garantías y Limitaciones de Responsabilidad.
A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
6. Limitación de responsabilidad.
A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.
7. Término.
a.	Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.
b.	Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.
8. Varios.
a.	Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.
b.	Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.
c.	Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.
d.	Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.

 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