Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative

Wood constitutes a material susceptible to fungal degradation, presenting frequent and aggressive deterioration when it is put into service. Although over the years compounds have been developed for their protection with various methods of impregnation, many of them present strong environmental ques...

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Autores:
Tipo de recurso:
Fecha de publicación:
2019
Institución:
Universidad Pedagógica y Tecnológica de Colombia
Repositorio:
RiUPTC: Repositorio Institucional UPTC
Idioma:
spa
OAI Identifier:
oai:repositorio.uptc.edu.co:001/15275
Acceso en línea:
https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/9807
https://repositorio.uptc.edu.co/handle/001/15275
Palabra clave:
antifúngico, cinamato de metilo, preservante, química verde
antifungal, methyl cinamate, preservative, green chemistry
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http://purl.org/coar/access_right/c_abf2
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oai_identifier_str oai:repositorio.uptc.edu.co:001/15275
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network_name_str RiUPTC: Repositorio Institucional UPTC
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spelling 2019-07-232024-07-08T14:23:57Z2024-07-08T14:23:57Zhttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/980710.19053/01217488.v10.n2.2019.9807https://repositorio.uptc.edu.co/handle/001/15275Wood constitutes a material susceptible to fungal degradation, presenting frequent and aggressive deterioration when it is put into service. Although over the years compounds have been developed for their protection with various methods of impregnation, many of them present strong environmental questions. The present work focuses on obtaining a preservative with potential antifungal activity for wood through a procedure of low environmental impact. The synthesis of methyl cinnamate (CiM) from cinnamic acid and methanol was carried out by catalysis with acids of Preyssler structure, with a yield of 49% and a selectivity of 100%. Subsequently, the antifungal action of the compound against Gloeophyllum sepiarium (Wulf.: Fr.) P. Karst, fungus causing brown rot was evaluated in-vitro. To do this, the growth of the fungus was comparatively analyzed on a control agarized culture medium and in the presence of CiM. The CiM demonstrated antifungal effect from 2000 ppm, though it was dependent on the incubation temperature. Further research is needed on wood to confirm its potential as a green preservative.La prevención y el control de hongos que atacan madera utilizando agentes sintetizados en el marco de la Química Verde es una estrategia prometedora en el desarrollo de preservantes que conduzcan a la sostenibilidad ambiental. La madera constituye un material susceptible a la degradación fúngica, presentando deterioro frecuente y agresivo cuando es puesta en servicio. Si bien a lo largo de los años se han desarrollado compuestos para su protección con diversos métodos de impregnación, muchos de los utilizados presentan fuertes cuestionamientos ambientales. El objetivo de este trabajo fue obtener cinamato de metilo (CiM) a través de un procedimiento de bajo impacto ambiental, y evaluar su actividad in vitrofrente a Gloeophyllum sepiarium(Wulf.: Fr.) P. Karst, un hongo causante de pudrición parda. Se realizó la síntesis de (CiM) a partir de ácido cinámico y metanol, mediante catálisis con ácidos de estructura Preyssler, con un rendimiento del 49% y una selectividad del 100 %. Este compuesto ejerció un efecto antifúngico, retrasando el crecimiento miceliar y su velocidad, a partir de una concentración de 2.000 ppm, aunque ello fue dependiente de la temperatura de incubación. Futuros estudios son necesarios para confirmar su potencial antifúngico cuando es aplicado en madera.  application/pdfspaspaUniversidad Pedagógica y Tecnológica de Colombiahttps://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/9807/8656Ciencia En Desarrollo; Vol. 10 No. 2 (2019): Vol 10, Núm. 2 (2019): Julio - Diciembre; 209-217Ciencia en Desarrollo; Vol. 10 Núm. 2 (2019): Vol 10, Núm. 2 (2019): Julio - Diciembre; 209-2172462-76580121-7488antifúngico, cinamato de metilo, preservante, química verdeantifungal, methyl cinamate, preservative, green chemistryGreen preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservativeSíntesis de cinamato de metilo, a través de un procedimiento de bajo impacto ambiental, y evaluación de su actividad antifúngica como potencial preservante de maderasinfo:eu-repo/semantics/articlehttp://purl.org/coar/version/c_970fb48d4fbd8a85http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/access_right/c_abf2Haug, ElizabethRuiz, DiegoRaffaeli, NataliaSaparrat, MarioRomanelli, Gustavo001/15275oai:repositorio.uptc.edu.co:001/152752025-07-18 10:56:40.433metadata.onlyhttps://repositorio.uptc.edu.coRepositorio Institucional UPTCrepositorio.uptc@uptc.edu.co
dc.title.en-US.fl_str_mv Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
dc.title.es-ES.fl_str_mv Síntesis de cinamato de metilo, a través de un procedimiento de bajo impacto ambiental, y evaluación de su actividad antifúngica como potencial preservante de maderas
title Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
spellingShingle Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
antifúngico, cinamato de metilo, preservante, química verde
antifungal, methyl cinamate, preservative, green chemistry
title_short Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
title_full Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
title_fullStr Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
title_full_unstemmed Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
title_sort Green preparation of methyl cinnamate and evaluation of its antifungal activity as a potential wood preservative
dc.subject.es-ES.fl_str_mv antifúngico, cinamato de metilo, preservante, química verde
topic antifúngico, cinamato de metilo, preservante, química verde
antifungal, methyl cinamate, preservative, green chemistry
dc.subject.en-US.fl_str_mv antifungal, methyl cinamate, preservative, green chemistry
description Wood constitutes a material susceptible to fungal degradation, presenting frequent and aggressive deterioration when it is put into service. Although over the years compounds have been developed for their protection with various methods of impregnation, many of them present strong environmental questions. The present work focuses on obtaining a preservative with potential antifungal activity for wood through a procedure of low environmental impact. The synthesis of methyl cinnamate (CiM) from cinnamic acid and methanol was carried out by catalysis with acids of Preyssler structure, with a yield of 49% and a selectivity of 100%. Subsequently, the antifungal action of the compound against Gloeophyllum sepiarium (Wulf.: Fr.) P. Karst, fungus causing brown rot was evaluated in-vitro. To do this, the growth of the fungus was comparatively analyzed on a control agarized culture medium and in the presence of CiM. The CiM demonstrated antifungal effect from 2000 ppm, though it was dependent on the incubation temperature. Further research is needed on wood to confirm its potential as a green preservative.
publishDate 2019
dc.date.accessioned.none.fl_str_mv 2024-07-08T14:23:57Z
dc.date.available.none.fl_str_mv 2024-07-08T14:23:57Z
dc.date.none.fl_str_mv 2019-07-23
dc.type.none.fl_str_mv info:eu-repo/semantics/article
dc.type.coarversion.fl_str_mv http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.coar.fl_str_mv http://purl.org/coar/resource_type/c_2df8fbb1
dc.identifier.none.fl_str_mv https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/9807
10.19053/01217488.v10.n2.2019.9807
dc.identifier.uri.none.fl_str_mv https://repositorio.uptc.edu.co/handle/001/15275
url https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/9807
https://repositorio.uptc.edu.co/handle/001/15275
identifier_str_mv 10.19053/01217488.v10.n2.2019.9807
dc.language.none.fl_str_mv spa
dc.language.iso.none.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/9807/8656
dc.rights.coar.fl_str_mv http://purl.org/coar/access_right/c_abf2
rights_invalid_str_mv http://purl.org/coar/access_right/c_abf2
dc.format.none.fl_str_mv application/pdf
dc.publisher.es-ES.fl_str_mv Universidad Pedagógica y Tecnológica de Colombia
dc.source.en-US.fl_str_mv Ciencia En Desarrollo; Vol. 10 No. 2 (2019): Vol 10, Núm. 2 (2019): Julio - Diciembre; 209-217
dc.source.es-ES.fl_str_mv Ciencia en Desarrollo; Vol. 10 Núm. 2 (2019): Vol 10, Núm. 2 (2019): Julio - Diciembre; 209-217
dc.source.none.fl_str_mv 2462-7658
0121-7488
institution Universidad Pedagógica y Tecnológica de Colombia
repository.name.fl_str_mv Repositorio Institucional UPTC
repository.mail.fl_str_mv repositorio.uptc@uptc.edu.co
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