Glycerol oxidation by fluorinated and platinized Titania
In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 w...
- Autores:
- Tipo de recurso:
- Fecha de publicación:
- 2021
- Institución:
- Universidad Pedagógica y Tecnológica de Colombia
- Repositorio:
- RiUPTC: Repositorio Institucional UPTC
- Idioma:
- spa
- OAI Identifier:
- oai:repositorio.uptc.edu.co:001/15306
- Acceso en línea:
- https://revistas.uptc.edu.co/index.php/ciencia_en_desarrollo/article/view/12417
https://repositorio.uptc.edu.co/handle/001/15306
- Palabra clave:
- Glycerol; 0.5wt.% Pt-F-TiO2; 2wt.% Pt-F-TiO2; Glyceraldehyde; Dihydroxyacetone.
Glicerol
0.5wt.% Pt-F-TiO2
2wt.% Pt-F-TiO2
Glyceraldehyde
Dihydroxyacetone.
- Rights
- License
- Derechos de autor 2021 CIENCIA EN DESARROLLO
Summary: | In this work, fluorinated and platinized TiO2 was evaluated in the glycerol oxidation. Fluorination led to increase the specific surface area of titania, and platinization treatment led to obtain the highest absorption in the visible region of the electromagnetic spectrum; thus, 0.5 wt.% Pt-F-TiO2 was the best catalyst in the obtention of highest yield and selectivity to glyceraldehyde (GAL). It was also found that 2wt.% of Pt content had a detrimental effect in the glycerol conversion. Fluorination and platinum addition led to modify the reaction mechanism and selectivity. |
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