A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism

This work presents an application of a multilayer model derived from statistical physics to the adsorption experimental data of two industrial pollutants, namely perfluorohexanesulfonic (PFHxS) and Perfluorobutanesulfonic (PFBS) acids on a bio–based polyurethane /chitosan(PU/CH) adsorbent foam, at T...

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Autores:
Sellaoui, Lotfi
Dhaouadi, Fatma
Deghrigue, Monia
Bouzidi, Mohamed
Khmissi, Hammadi
Dotto, Guilherme Luiz
Oliveira, Marcos
Silva, Luis
Erto, Alessandro
Ernst, Barbara
Badawi, Michael
Tipo de recurso:
Review article
Fecha de publicación:
2024
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
eng
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/14268
Acceso en línea:
https://hdl.handle.net/11323/14268
https://repositorio.cuc.edu.co/
Palabra clave:
Adsorption
Adsorption mechanism
Modelling
Polyfluoroalkyl substances
Polyurethane/Chitosan
Statistical physiscs
Rights
openAccess
License
Atribución 4.0 Internacional (CC BY 4.0)
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oai_identifier_str oai:repositorio.cuc.edu.co:11323/14268
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.eng.fl_str_mv A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
title A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
spellingShingle A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
Adsorption
Adsorption mechanism
Modelling
Polyfluoroalkyl substances
Polyurethane/Chitosan
Statistical physiscs
title_short A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
title_full A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
title_fullStr A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
title_full_unstemmed A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
title_sort A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism
dc.creator.fl_str_mv Sellaoui, Lotfi
Dhaouadi, Fatma
Deghrigue, Monia
Bouzidi, Mohamed
Khmissi, Hammadi
Dotto, Guilherme Luiz
Oliveira, Marcos
Silva, Luis
Erto, Alessandro
Ernst, Barbara
Badawi, Michael
dc.contributor.author.none.fl_str_mv Sellaoui, Lotfi
Dhaouadi, Fatma
Deghrigue, Monia
Bouzidi, Mohamed
Khmissi, Hammadi
Dotto, Guilherme Luiz
Oliveira, Marcos
Silva, Luis
Erto, Alessandro
Ernst, Barbara
Badawi, Michael
dc.subject.proposal.eng.fl_str_mv Adsorption
Adsorption mechanism
Modelling
Polyfluoroalkyl substances
Polyurethane/Chitosan
Statistical physiscs
topic Adsorption
Adsorption mechanism
Modelling
Polyfluoroalkyl substances
Polyurethane/Chitosan
Statistical physiscs
description This work presents an application of a multilayer model derived from statistical physics to the adsorption experimental data of two industrial pollutants, namely perfluorohexanesulfonic (PFHxS) and Perfluorobutanesulfonic (PFBS) acids on a bio–based polyurethane /chitosan(PU/CH) adsorbent foam, at T = 298–328 K and pH 4. This model shows that the number of PFHxS and PFBS layers formed on adsorbent surface increases from 1.61 to 3.80, and from 1.56 to 2.26 respectively by increasing the temperature.This means that the adsorbate molecules are arranged on a variable number of layers. For instance, at 328 K, it was deduced that around 80 % of PFHxS acid was taken up by the PU/CH composite, forming a total of four layers, whereas the remaining 20 % contributed to the formation of three layers. The estimation and analysis of the number of molecules bound per active site is useful to understand the adsorption mechanism. PFHxS and PFBS adsorb on PU/CH in non-parallel configuration, through a multimolecular docking characterized by more than one molecule per active site. The PU/CH performances are investigated in terms of the maximum adsorption capacity of both the tested industrial pollutants, retrieving similar values for both PFHxS and PFBS. Two adsorption energies are calculated showing that physical forces are contributing to remove these pollutants. Interstingly, thermodynamic calculations are also introduced and interpreted to understand the adsorption mechanism at macroscopic level. These theoretical scientific evidences provide a plausible explanation of the PFHxS and PFBS adsorption mechanisms and contribute to understand this interfacial process at the molecular level.
publishDate 2024
dc.date.issued.none.fl_str_mv 2024-04-12
dc.date.accessioned.none.fl_str_mv 2025-06-04T19:51:42Z
dc.date.available.none.fl_str_mv 2025-06-04T19:51:42Z
dc.type.none.fl_str_mv Artículo de revista
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dc.identifier.citation.none.fl_str_mv Lotfi Sellaoui, Fatma Dhaouadi, Monia Deghrigue, Mohamed Bouzidi, Hammadi Khmissi, Guilherme Luiz Dotto, Marcos Leandro Silva Oliveira, Luis Felipe Oliveira Silva, Alessandro Erto, Barbara Ernst, Michael Badawi, A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism, Chemical Engineering Journal, Volume 489, 2024, 151173, ISSN 1385-8947, https://doi.org/10.1016/j.cej.2024.151173.
dc.identifier.issn.none.fl_str_mv 1385-8947
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/11323/14268
dc.identifier.doi.none.fl_str_mv 10.1016/j.cej.2024.151173
dc.identifier.instname.none.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.none.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.none.fl_str_mv https://repositorio.cuc.edu.co/
identifier_str_mv Lotfi Sellaoui, Fatma Dhaouadi, Monia Deghrigue, Mohamed Bouzidi, Hammadi Khmissi, Guilherme Luiz Dotto, Marcos Leandro Silva Oliveira, Luis Felipe Oliveira Silva, Alessandro Erto, Barbara Ernst, Michael Badawi, A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism, Chemical Engineering Journal, Volume 489, 2024, 151173, ISSN 1385-8947, https://doi.org/10.1016/j.cej.2024.151173.
1385-8947
10.1016/j.cej.2024.151173
Corporación Universidad de la Costa
REDICUC - Repositorio CUC
url https://hdl.handle.net/11323/14268
https://repositorio.cuc.edu.co/
dc.language.iso.none.fl_str_mv eng
language eng
dc.relation.ispartofjournal.none.fl_str_mv Chemical Engineering Journal
dc.relation.references.none.fl_str_mv H.-Y. Xu, J.-Q. Zhu, W. Wang, X.-L. Xu, Y. Lu, The study of interaction between PFOA/PFOS and uracil by topology quality and spectroscopic analysis, Russ. J. Phys. Chem. 88 (2014) 279–286, https://doi.org/10.1134/S0036024414020332.
P. Grandjean, R. Clapp, Perfluorinated alkyl substances: emerging insights into health risks, New Solut.. 25 (2015) 147–163, https://doi.org/10.1177/ 1048291115590506.
R.C. Buck, J. Franklin, U. Berger, J.M. Conder, I.T. Cousins, P. De Voogt, A. A. Jensen, K. Kannan, S.A. Mabury, S.P. Van Leeuwen, Perfluoroalkyl and polyfluoroalkyl substances in the environment: terminology, classification, and origins, Integr. Environ. Assess Manag 7 (2011) 513–541, https://doi.org/ 10.1002/ieam.258.
E.M. Sunderland, X.C. Hu, C. Dassuncao, A.K. Tokranov, C.C. Wagner, J.G. Allen, A review of the pathways of human exposure to poly-and perfluoroalkyl substances (PFASs) and present understanding of health effects, J. Exposure Sci. Environ. Epidemiol. 29 (2019) 131–147.
S.B. Gewurtz, S.M. Backus, A.O. De Silva, L. Ahrens, A. Armellin, M. Evans, S. Fraser, M. Gledhill, P. Guerra, T. Harner, Perfluoroalkyl acids in the Canadian environment: multi-media assessment of current status and trends, Environ. Int. 59 (2013) 183–200.
N. Liu, C. Wu, G. Lyu, M. Li, Efficient adsorptive removal of short-chain perfluoroalkyl acids using reed straw-derived biochar (RESCA), Sci. Total Environ. 798 (2021) 149191.
A. Moller, ¨ L. Ahrens, R. Surm, J. Westerveld, F. van der Wielen, R. Ebinghaus, P. de Voogt, Distribution and sources of polyfluoroalkyl substances (PFAS) in the River Rhine watershed, Environ. Pollut. 158 (2010) 3243–3250.
Z. Zhang, D. Sarkar, R. Datta, Y. Deng, Adsorption of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) by aluminum-based drinking water treatment residuals, J. Hazard. Mater. Lett. 2 (2021) 100034.
X. Wang, Z. Chen, Y. Wang, W. Sun, A review on degradation of perfluorinated compounds based on ultraviolet advanced oxidation, Environ. Pollut. 291 (2021) 118014.
S.P. Chetverikov, D.A. Sharipov, T.Y. Korshunova, O.N. Loginov, Degradation of perfluorooctanylsulfonate by strain Pseudomonas plecoglossicida 2.4-D, Appl. Biochem. Microbiol. 53 (2017) 533–538, https://doi.org/10.1134/ S0003683817050027.
C. Chen, Q. Ma, F. Liu, J. Gao, X. Li, S. Sun, H. Yao, C. Liu, J. Young, W. Zhang, Photocatalytically reductive defluorination of perfluorooctanoic acid (PFOA) using Pt/La2Ti2O7 nanoplates: experimental and DFT assessment, J. Hazard. Mater. 419 (2021) 126452.
V.A.A. Espana, M. Mallavarapu, R. Naidu, Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA): a critical review with an emphasis on field testing, Environ. Technol. Innov. 4 (2015) 168–181.
C.D. Vecitis, H. Park, J. Cheng, B.T. Mader, M.R. Hoffmann, Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), Front. Environ. Sci. Eng. China 3 (2009) 129–151, https://doi.org/ 10.1007/s11783-009-0022-7.
A. Dąbrowski, Adsorption—from theory to practice, Adv. Colloid Interface Sci. 93 (2001) 135–224.
J.E. Zenobio, O.A. Salawu, Z. Han, A.S. Adeleye, Adsorption of per-and polyfluoroalkyl substances (PFAS) to containers, J. Hazard. Mater. Adv. 7 (2022) 100130.
P.S. Pauletto, T.J. Bandosz, Activated carbon versus metal-organic frameworks: a review of their PFAS adsorption performance, J. Hazard. Mater. 425 (2022) 127810.
X. Lei, Q. Lian, X. Zhang, T.K. Karsili, W. Holmes, Y. Chen, M.E. Zappi, D.D. Gang, A review of PFAS adsorption from aqueous solutions: current approaches, engineering applications, challenges, and opportunities, Environ. Pollut. 321 (2023) 121138, https://doi.org/10.1016/j.envpol.2023.121138.
M. Riegel, B. Haist-Gulde, F. Sacher, Sorptive removal of short-chain perfluoroalkyl substances (PFAS) during drinking water treatment using activated carbon and anion exchanger, Environ. Sci. Eur. 35 (2023) 12, https://doi.org/10.1186/ s12302-023-00716-5.
N. Saeidi, F.-D. Kopinke, A. Georgi, Understanding the effect of carbon surface chemistry on adsorption of perfluorinated alkyl substances, Chem. Eng. J. 381 (2020) 122689.
J. He, A. Gomeniuc, Y. Olshansky, J. Hatton, L. Abrell, J.A. Field, J. Chorover, R. Sierra-Alvarez, Enhanced removal of per-and polyfluoroalkyl substances by crosslinkedpolyaniline polymers, Chem. Eng. J. 446 (2022) 137246.
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spelling Atribución 4.0 Internacional (CC BY 4.0)© 2024 Elsevier B.V.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Sellaoui, LotfiDhaouadi, FatmaDeghrigue, MoniaBouzidi, MohamedKhmissi, HammadiDotto, Guilherme LuizOliveira, Marcosvirtual::1196-1Silva, Luisvirtual::1197-1Erto, AlessandroErnst, BarbaraBadawi, Michael2025-06-04T19:51:42Z2025-06-04T19:51:42Z2024-04-12Lotfi Sellaoui, Fatma Dhaouadi, Monia Deghrigue, Mohamed Bouzidi, Hammadi Khmissi, Guilherme Luiz Dotto, Marcos Leandro Silva Oliveira, Luis Felipe Oliveira Silva, Alessandro Erto, Barbara Ernst, Michael Badawi, A multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanism, Chemical Engineering Journal, Volume 489, 2024, 151173, ISSN 1385-8947, https://doi.org/10.1016/j.cej.2024.151173.1385-8947https://hdl.handle.net/11323/1426810.1016/j.cej.2024.151173Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/This work presents an application of a multilayer model derived from statistical physics to the adsorption experimental data of two industrial pollutants, namely perfluorohexanesulfonic (PFHxS) and Perfluorobutanesulfonic (PFBS) acids on a bio–based polyurethane /chitosan(PU/CH) adsorbent foam, at T = 298–328 K and pH 4. This model shows that the number of PFHxS and PFBS layers formed on adsorbent surface increases from 1.61 to 3.80, and from 1.56 to 2.26 respectively by increasing the temperature.This means that the adsorbate molecules are arranged on a variable number of layers. For instance, at 328 K, it was deduced that around 80 % of PFHxS acid was taken up by the PU/CH composite, forming a total of four layers, whereas the remaining 20 % contributed to the formation of three layers. The estimation and analysis of the number of molecules bound per active site is useful to understand the adsorption mechanism. PFHxS and PFBS adsorb on PU/CH in non-parallel configuration, through a multimolecular docking characterized by more than one molecule per active site. The PU/CH performances are investigated in terms of the maximum adsorption capacity of both the tested industrial pollutants, retrieving similar values for both PFHxS and PFBS. Two adsorption energies are calculated showing that physical forces are contributing to remove these pollutants. Interstingly, thermodynamic calculations are also introduced and interpreted to understand the adsorption mechanism at macroscopic level. These theoretical scientific evidences provide a plausible explanation of the PFHxS and PFBS adsorption mechanisms and contribute to understand this interfacial process at the molecular level.10 páginasapplication/pdfengElsevier B.V.Netherlandshttps://www.sciencedirect.com/science/article/pii/S1385894724026603?via%3DihubA multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on bio-based polyurethane/chitosan foam: Advanced interpretation of the adsorption mechanismArtículo de revistahttp://purl.org/coar/resource_type/c_dcae04bchttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Chemical Engineering JournalH.-Y. Xu, J.-Q. Zhu, W. Wang, X.-L. Xu, Y. Lu, The study of interaction between PFOA/PFOS and uracil by topology quality and spectroscopic analysis, Russ. J. Phys. Chem. 88 (2014) 279–286, https://doi.org/10.1134/S0036024414020332.P. Grandjean, R. Clapp, Perfluorinated alkyl substances: emerging insights into health risks, New Solut.. 25 (2015) 147–163, https://doi.org/10.1177/ 1048291115590506.R.C. Buck, J. Franklin, U. Berger, J.M. Conder, I.T. Cousins, P. De Voogt, A. A. Jensen, K. Kannan, S.A. Mabury, S.P. Van Leeuwen, Perfluoroalkyl and polyfluoroalkyl substances in the environment: terminology, classification, and origins, Integr. Environ. Assess Manag 7 (2011) 513–541, https://doi.org/ 10.1002/ieam.258.E.M. Sunderland, X.C. Hu, C. Dassuncao, A.K. Tokranov, C.C. Wagner, J.G. Allen, A review of the pathways of human exposure to poly-and perfluoroalkyl substances (PFASs) and present understanding of health effects, J. Exposure Sci. Environ. Epidemiol. 29 (2019) 131–147.S.B. Gewurtz, S.M. Backus, A.O. De Silva, L. Ahrens, A. Armellin, M. Evans, S. Fraser, M. Gledhill, P. Guerra, T. Harner, Perfluoroalkyl acids in the Canadian environment: multi-media assessment of current status and trends, Environ. Int. 59 (2013) 183–200.N. Liu, C. Wu, G. Lyu, M. Li, Efficient adsorptive removal of short-chain perfluoroalkyl acids using reed straw-derived biochar (RESCA), Sci. Total Environ. 798 (2021) 149191.A. Moller, ¨ L. Ahrens, R. Surm, J. Westerveld, F. van der Wielen, R. Ebinghaus, P. de Voogt, Distribution and sources of polyfluoroalkyl substances (PFAS) in the River Rhine watershed, Environ. Pollut. 158 (2010) 3243–3250.Z. Zhang, D. Sarkar, R. Datta, Y. Deng, Adsorption of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) by aluminum-based drinking water treatment residuals, J. Hazard. Mater. Lett. 2 (2021) 100034.X. Wang, Z. Chen, Y. Wang, W. Sun, A review on degradation of perfluorinated compounds based on ultraviolet advanced oxidation, Environ. Pollut. 291 (2021) 118014.S.P. Chetverikov, D.A. Sharipov, T.Y. Korshunova, O.N. Loginov, Degradation of perfluorooctanylsulfonate by strain Pseudomonas plecoglossicida 2.4-D, Appl. Biochem. Microbiol. 53 (2017) 533–538, https://doi.org/10.1134/ S0003683817050027.C. Chen, Q. Ma, F. Liu, J. Gao, X. Li, S. Sun, H. Yao, C. Liu, J. Young, W. Zhang, Photocatalytically reductive defluorination of perfluorooctanoic acid (PFOA) using Pt/La2Ti2O7 nanoplates: experimental and DFT assessment, J. Hazard. Mater. 419 (2021) 126452.V.A.A. Espana, M. Mallavarapu, R. Naidu, Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA): a critical review with an emphasis on field testing, Environ. Technol. Innov. 4 (2015) 168–181.C.D. Vecitis, H. Park, J. Cheng, B.T. Mader, M.R. Hoffmann, Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA), Front. Environ. Sci. Eng. China 3 (2009) 129–151, https://doi.org/ 10.1007/s11783-009-0022-7.A. Dąbrowski, Adsorption—from theory to practice, Adv. Colloid Interface Sci. 93 (2001) 135–224.J.E. Zenobio, O.A. Salawu, Z. Han, A.S. Adeleye, Adsorption of per-and polyfluoroalkyl substances (PFAS) to containers, J. Hazard. Mater. Adv. 7 (2022) 100130.P.S. Pauletto, T.J. Bandosz, Activated carbon versus metal-organic frameworks: a review of their PFAS adsorption performance, J. Hazard. Mater. 425 (2022) 127810.X. Lei, Q. Lian, X. Zhang, T.K. Karsili, W. Holmes, Y. Chen, M.E. Zappi, D.D. Gang, A review of PFAS adsorption from aqueous solutions: current approaches, engineering applications, challenges, and opportunities, Environ. Pollut. 321 (2023) 121138, https://doi.org/10.1016/j.envpol.2023.121138.M. Riegel, B. Haist-Gulde, F. Sacher, Sorptive removal of short-chain perfluoroalkyl substances (PFAS) during drinking water treatment using activated carbon and anion exchanger, Environ. Sci. Eur. 35 (2023) 12, https://doi.org/10.1186/ s12302-023-00716-5.N. Saeidi, F.-D. Kopinke, A. Georgi, Understanding the effect of carbon surface chemistry on adsorption of perfluorinated alkyl substances, Chem. Eng. J. 381 (2020) 122689.J. He, A. Gomeniuc, Y. Olshansky, J. Hatton, L. Abrell, J.A. Field, J. Chorover, R. Sierra-Alvarez, Enhanced removal of per-and polyfluoroalkyl substances by crosslinkedpolyaniline polymers, Chem. Eng. J. 446 (2022) 137246.101151173489AdsorptionAdsorption mechanismModellingPolyfluoroalkyl substancesPolyurethane/ChitosanStatistical physiscsPublication486b5991-6bbd-4f12-9907-dd19efe24611virtual::1196-1f2872e80-7316-4a56-b020-995de6547b54virtual::1197-1486b5991-6bbd-4f12-9907-dd19efe24611virtual::1196-1f2872e80-7316-4a56-b020-995de6547b54virtual::1197-10000-0002-7771-5085virtual::1196-10000-0001-7678-9130virtual::1197-1ORIGINALA multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on biobased polyurethanechitosan foam Advanced interpretation of the adsorption mechanism.pdfA multilayer adsorption of perfluorohexanesulfonic and perfluorobutanesulfonic acids on biobased polyurethanechitosan foam Advanced interpretation of the adsorption mechanism.pdfapplication/pdf1575242https://repositorio.cuc.edu.co/bitstreams/49949267-f622-417e-b010-cfc80f76bfd3/download08bf934a305e93e0cf83f60a80f975c3MD51LICENSElicense.txtlicense.txttext/plain; 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
