Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems
A novel catalyst was synthesized employing coal and volcanic rock waste (VRW) residues enriched with iron nanoparticles, and its efficiency was investigated upon the degradation of (2,4-dichlorophenoxy)acetic acid (2,4-D) and atrazine (ATZ) pesticides. The composite was synthesized by a facile and e...
- Autores:
-
Vieira, Yasmin
Rossatto, Diovani L.
Leichtweis, Jandira
Foletto, Edson L.
Oliveira, Marcos
Silva, Luis
Dotto, Guilherme Luiz
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2022
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/14211
- Acceso en línea:
- https://hdl.handle.net/11323/14211
https://repositorio.cuc.edu.co/
- Palabra clave:
- Herbicide
Heterogeneous catalysis
Microwave-responsive catalyst
Phytotoxicity
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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| dc.title.eng.fl_str_mv |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| title |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| spellingShingle |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems Herbicide Heterogeneous catalysis Microwave-responsive catalyst Phytotoxicity |
| title_short |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| title_full |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| title_fullStr |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| title_full_unstemmed |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| title_sort |
Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems |
| dc.creator.fl_str_mv |
Vieira, Yasmin Rossatto, Diovani L. Leichtweis, Jandira Foletto, Edson L. Oliveira, Marcos Silva, Luis Dotto, Guilherme Luiz |
| dc.contributor.author.none.fl_str_mv |
Vieira, Yasmin Rossatto, Diovani L. Leichtweis, Jandira Foletto, Edson L. Oliveira, Marcos Silva, Luis Dotto, Guilherme Luiz |
| dc.subject.proposal.eng.fl_str_mv |
Herbicide Heterogeneous catalysis Microwave-responsive catalyst Phytotoxicity |
| topic |
Herbicide Heterogeneous catalysis Microwave-responsive catalyst Phytotoxicity |
| description |
A novel catalyst was synthesized employing coal and volcanic rock waste (VRW) residues enriched with iron nanoparticles, and its efficiency was investigated upon the degradation of (2,4-dichlorophenoxy)acetic acid (2,4-D) and atrazine (ATZ) pesticides. The composite was synthesized by a facile and effective chemical precipitation technique and extensively characterized by XRD, FTIR, XRF, ICP-OES, ICP-MS, and SEM-EDS. The effects of pH, catalyst dosage, and initial pollutant concentration were investigated in single and binary systems irradiated with microwave (MW) under atmospheric pressure. The optimal reaction conditions were obtained at pH 3 and 5 for 2,4-D and ATZ in single systems and pH 3 in binary systems, respectively, with 20 mg L−1 of initial pollutant concentration and 0.1 g L−1 of CVRWMag (coal, VRW, and nano-Fe3O4) catalyst. The kinetic data fitted better to the pseudo-first-order model (R2 > 0.965). In addition, the phytotoxicity was investigated with Lactuca sativa seeds, and the root elongation and the seed germination rate were enhanced as the MW irradiation time increased. The complete degradation of both compounds was reached within 30 min, with outstanding mineralization efficiency. The degradation efficiency was attributed to hydroxyl radical (radical dotOH) formation and electrostatic surface interaction, enhanced by hot spot formation. Therefore, the CVRWMag is a promising MW absorbing catalyst for the removal and degradation of pesticides without the need for H2O2 or any radical enhancing agent addition |
| publishDate |
2022 |
| dc.date.issued.none.fl_str_mv |
2022-09 |
| dc.date.accessioned.none.fl_str_mv |
2025-05-07T22:00:32Z |
| dc.date.available.none.fl_str_mv |
2025-05-07T22:00:32Z |
| dc.type.none.fl_str_mv |
Artículo de revista |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
| dc.type.content.none.fl_str_mv |
Text |
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info:eu-repo/semantics/article |
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http://purl.org/redcol/resource_type/ART |
| dc.type.version.none.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
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http://purl.org/coar/version/c_970fb48d4fbd8a85 |
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http://purl.org/coar/resource_type/c_2df8fbb1 |
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publishedVersion |
| dc.identifier.citation.none.fl_str_mv |
Yasmin Vieira, Diovani L. Rossatto, Jandira Leichtweis, Edson L. Foletto, Marcos L.S. Oliveira, Luis F.O. Silva, Guilherme Luiz Dotto, Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems, Advanced Powder Technology, Volume 33, Issue 8, 2022, 103671, ISSN 0921-8831, https://doi.org/10.1016/j.apt.2022.103671. (https://www.sciencedirect.com/science/article/pii/S0921883122002497) |
| dc.identifier.issn.none.fl_str_mv |
0921-8831 |
| dc.identifier.uri.none.fl_str_mv |
https://hdl.handle.net/11323/14211 |
| dc.identifier.doi.none.fl_str_mv |
10.1016/j.apt.2022.103671 |
| dc.identifier.eissn.none.fl_str_mv |
1568-5527 |
| dc.identifier.instname.none.fl_str_mv |
Corporación Universidad de la Costa |
| dc.identifier.reponame.none.fl_str_mv |
REDICUC - Repositorio CUC |
| dc.identifier.repourl.none.fl_str_mv |
https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Yasmin Vieira, Diovani L. Rossatto, Jandira Leichtweis, Edson L. Foletto, Marcos L.S. Oliveira, Luis F.O. Silva, Guilherme Luiz Dotto, Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems, Advanced Powder Technology, Volume 33, Issue 8, 2022, 103671, ISSN 0921-8831, https://doi.org/10.1016/j.apt.2022.103671. (https://www.sciencedirect.com/science/article/pii/S0921883122002497) 0921-8831 10.1016/j.apt.2022.103671 1568-5527 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/14211 https://repositorio.cuc.edu.co/ |
| dc.language.iso.none.fl_str_mv |
eng |
| language |
eng |
| dc.relation.ispartofjournal.none.fl_str_mv |
Advanced Powder Technology |
| dc.relation.references.none.fl_str_mv |
R. Macirella, G. Madeo, S. Sesti, M. Tripepi, I. Bernabò, N. Godbert, D. La Russa, E. Brunelli, Exposure and post-exposure effects of chlorpyrifos on Carassius auratus gills: an ultrastructural and morphofunctional investigation, Chemosphere 251 (2020) 126434 S. Shukla, R.C. Jhamtani, M.S. Dahiya, R. Agarwal, Oxidative injury caused by individual and combined exposure of neonicotinoid, organophosphate and herbicide in zebrafish, Toxicol. Reports. 4 (2017) 240–244, https://doi.org/ 10.1016/J.TOXREP.2017.05.002 Ö. Demirci, K. Güven, D. Asma, S. Ög˘üt, P. Ug˘urlu, Effects of endosulfan, thiamethoxam, and indoxacarb in combination with atrazine on multi biomarkers in Gammarus kischineffensis, Ecotoxicol. Environ. Saf. 147 (2018) 749–758, https://doi.org/10.1016/J.ECOENV.2017.09.038 K.E. Murray, S.M. Thomas, A.A. Bodour, Prioritizing research for trace pollutants and emerging contaminants in the freshwater environment, Environ. Pollut. 158 (12) (2010) 3462–3471 T. Smital, T. Luckenbach, R. Sauerborn, A.M. Hamdoun, R.L. Vega, D. Epel, Emerging contaminants—pesticides, PPCPs, microbial degradation products and natural substances as inhibitors of multixenobiotic defense in aquatic organisms, Mutat. Res. Mol. Mech. Mutagen. 552 (1-2) (2004) 101–117 M. Kah, Nanopesticides and Nanofertilizers: Emerging Contaminants or Opportunities for Risk Mitigation?, Front Chem. (2015) 64, https://doi.org/ 10.3389/FCHEM.2015.00064 M.-H.Y. Yu, H. Tsunoda, M. Tsunoda, Environmental Toxicology Biological and Health Effects of Pollutants, 2004 Y. Jin-Clark, M.J. Lydy, K.Y. Zhu, Effects of atrazine and cyanazine on chlorpyrifos toxicity in Chironomus tentans (Diptera: Chironomidae), Environ. Toxicol. Chem. 21 (3) (2002) 598–603 M. Abdennouri, A. Elhalil, M. Farnane, H. Tounsadi, F.Z. Mahjoubi, R. Elmoubarki, M. Sadiq, L. Khamar, A. Galadi, M. Baâlala, M. Bensitel, Y. El hafiane, A. Smith, N. Barka, Photocatalytic degradation of 2,4-D and 2,4-DP herbicides on Pt/TiO2 nanoparticles, J. Saudi Chem. Soc. 19 (5) (2015) 485–493 J.A. Pascual Aguilar, V. Andreu, J. Campo, Y. Picó, A. Masiá, Pesticide occurrence in the waters of Júcar River, Spain from different farming landscapes, Sci. Total Environ. 607–608 (2017) 752–760, https://doi.org/10.1016/J. SCITOTENV.2017.06.176 Y.-F. Jiang, X.-T. Wang, Y. Jia, F. Wang, M.-H. Wu, G.-Y. Sheng, J.-M. Fu, Occurrence, distribution and possible sources of organochlorine pesticides in agricultural soil of Shanghai, China, J. Hazard. Mater. 170 (2-3) (2009) 989–997 D.W. Kolpin*, J.E. Barbash, R.J. Gilliom, Occurrence of Pesticides in Shallow Groundwater of the United States: Initial Results from the National Water Quality Assessment Program, Environ. Sci. Technol. 32 (1998) 558–566. https://doi.org/10.1021/ES970412G D. Ramírez-Morales, M.E. Pérez-Villanueva, J.S. Chin-Pampillo, P. Aguilar Mora, V. Arias-Mora, M. Masís-Mora, Pesticide occurrence and water quality assessment from an agriculturally influenced Latin-American tropical region, Chemosphere. 262 (2021) 127851 B.J. Mahler, L.H. Nowell, M.W. Sandstrom, P.M. Bradley, K.M. Romanok, C.P. Konrad, P.C. Van Metre, Van Metre, Inclusion of Pesticide Transformation Products Is Key to Estimating Pesticide Exposures and Effects in Small U.S. Streams, Environ. Sci. Technol. 55 (8) (2021) 4740–4752 J. Stanley, G. Preetha, Pesticide toxicity to non-target organisms: Exposure, toxicity and risk assessment methodologies, Pestic. Toxic. to Non-Target Org, Expo. Toxic. Risk Assess. Methodol. (2016) 1–502, https://doi.org/10.1007/ 978-94-017-7752-0 L. Bakker, J. Sok, W. van der Werf, F.J.J.A. Bianchi, Kicking the Habit: What Makes and Breaks Farmers’ Intentions to Reduce Pesticide Use?, Ecol Econ. 180 (2021) 106868 A. Bagheri, N. Emami, C.A. Damalas, Farmers’ behavior towards safe pesticide handling: An analysis with the theory of planned behavior, Sci. Total Environ. 751 (2021) 141709 M. Tudi, H. Daniel Ruan, L.i. Wang, J. Lyu, R. Sadler, D. Connell, C. Chu, D.T. Phung, Agriculture Development, Pesticide Application and Its Impact on the Environment, IJERPH 18 (3) (2021) 1112, https://doi.org/10.3390/ ijerph18031112 M. Yeganeh, E. Charkhloo, H.R. Sobhi, A. Esrafili, M. Gholami, Photocatalytic processes associated with degradation of pesticides in aqueous solutions: Systematic review and meta-analysis, Chem. Eng. J. 428 (2022) 130081 S. Horikoshi, A. Osawa, S. Sakamoto, N. Serpone, Control of microwave generated hot spots. Part V. Mechanisms of hot-spot generation and aggregation of catalyst in a microwave-assisted reaction in toluene catalyzed by Pd-loaded AC particulates, Appl. Catal. A Gen. 460–461 (2013) 52–60, https://doi.org/10.1016/j.apcata.2013.04.022 S. Horikoshi, N. Serpone, Coupled microwave/photoassisted methods for environmental remediation, Molecules. 19 (2014) 18102–18128, https://doi. org/10.3390/molecules191118102 Y. Vieira, S. Silvestri, J. Leichtweis, S.L. Jahn, É.M. de Moraes Flores, G.L. Dotto, E. L. Foletto, New insights into the mechanism of heterogeneous activation of nano–magnetite by microwave irradiation for use as Fenton catalyst, J. Environ Chem. Eng. 8 (3) (2020) 103787 S. Horikoshi, M. Abe, N. Serpone, Novel designs of microwave discharge electrodeless lamps (MDEL) in photochemical applications. Use in advanced oxidation processes, Photochem. Photobiol. Sci. 8 (8) (2009) 1087, https://doi. org/10.1039/b818491g Y. Vieira, H.A. Pereira, J. Leichtweis, C.M. Mistura, E.L. Foletto, L.F.S. Oliveira, G. L. Dotto, Effective treatment of hospital wastewater with high-concentration diclofenac and ibuprofen using a promising technology based on degradation reaction catalyzed by Fe0 under microwave irradiation, Sci. Total Environ. 783 (2021) 146991, https://doi.org/10.1016/j.scitotenv.2021.146991 S. Horikoshi, A. Osawa, M. Abe, N. Serpone, On the generation of hot-spots by microwave electric and magnetic fields and their impact on a microwave assisted heterogeneous reaction in the presence of metallic Pd nanoparticles on an activated carbon support, J. Phys. Chem. C. 115 (46) (2011) 23030– 23035, https://doi.org/10.1021/jp2076269 C. Xue, Y. Mao, W. Wang, Z. Song, X. Zhao, J. Sun, Y. Wang, Current status of applying microwave-associated catalysis for the degradation of organics in aqueous phase – A review, J. Environ. Sci. (China) 81 (2019) 119–135, https:// doi.org/10.1016/j.jes.2019.01.019 R. Wei, P. Wang, G. Zhang, N. Wang, T. Zheng, Microwave-responsive catalysts for wastewater treatment: A review, Chem. Eng. J. 382 (2020) 122781, https:// doi.org/10.1016/j.cej.2019.122781 S. Liu, L. Mei, X. Liang, L. Liao, G. Lv, S. Ma, S. Lu, A. Abdelkader, K. Xi, Anchoring Fe3O4 Nanoparticles on Carbon Nanotubes for Microwave-Induced Catalytic Degradation of Antibiotics, ACS Appl. Mater. Interfaces. 10 (35) (2018) 29467– 29475 S.P. Pawar, M. Gandi, S. Bose, High performance electromagnetic wave absorbers derived from PC/SAN blends containing multiwall carbon nanotubes and Fe 3 O 4 decorated onto graphene oxide sheets, RSC Adv. 6 (44) (2016) 37633–37645, https://doi.org/10.1039/C5RA25435C N. Wang, X. Sun, Q. Zhao, Y. Yang, P. Wang, Leachability and adverse effects of coal fly ash: A review, J. Hazard. Mater. 396 (2020) 122725 N. Wang, X. Sun, Q. Zhao, P. Wang, Treatment of polymer-flooding wastewater by a modified coal fly ash-catalysed Fenton-like process with microwave pre enhancement: System parameters, kinetics, and proposed mechanism, Chem. Eng. J. 406 (2021) 126734 N. Wang, L.u. Jin, C. Li, Y. Liang, P. Wang, Preparation of coal fly ash-based Fenton-like catalyst and its application for the treatment of organic wastewater under microwave assistance, J. Clean. Prod. 342 (2022) 130926 Z. Zhang, J. Jiatieli, D. Liu, F. Yu, S. Xue, W. Gao, Y. Li, D.D. Dionysiou, Microwave induced degradation of parathion in the presence of supported anatase- and rutile-TiO2/AC and comparison of their catalytic activity, Chem. Eng. J. 231 (2013) 84–93, https://doi.org/10.1016/J.CEJ.2013.07.001 X. Quan, Y. Zhang, S. Chen, Y. Zhao, F. Yang, Generation of hydroxyl radical in aqueous solution by microwave energy using activated carbon as catalyst and its potential in removal of persistent organic substances, J. Mol. Catal. A Chem. 263 (1-2) (2007) 216–222 M. Shen, L. Fu, J. Tang, M. Liu, Y. Song, F. Tian, Z. Zhao, Z. Zhang, D.D. Dionysiou, Microwave hydrothermal-assisted preparation of novel spinel NiFe2O4/natural mineral composites as microwave catalysts for degradation of aquatic organic pollutants, J. Hazard. Mater. 350 (2018) 1–9, https://doi.org/ 10.1016/J.JHAZMAT.2018.02.014 H. Teng, L.-Y. Hsu, High-Porosity Carbons Prepared from Bituminous Coal with Potassium Hydroxide Activation, (1999). https://doi.org/10.1021/ ie990101 C.G. Ramos, X. Querol, M.L.S. Oliveira, K. Pires, R.M. Kautzmann, L.F.O. Silva, A preliminary evaluation of volcanic rock powder for application in agriculture as soil a remineralizer, Sci. Total Environ. 512–513 (2015) 371–380, https:// doi.org/10.1016/j.scitotenv.2014.12.070 P. Panneerselvam, N. Morad, K.A. Tan, Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution, J. Hazard. Mater. 186 (1) (2011) 160–168, https://doi.org/10.1016/j. jhazmat.2010.10.102 C.S. Castro, M.C. Guerreiro, M. Gonçalves, L.C.A. Oliveira, A.S. Anastácio, Activated carbon/iron oxide composites for the removal of atrazine from aqueous medium, J. Hazard. Mater. 164 (2-3) (2009) 609–614, https://doi.org/ 10.1016/j.jhazmat.2008.08.066 Z. Han, B. Sani, W. Mrozik, M. Obst, B. Beckingham, H.K. Karapanagioti, D. Werner, Magnetite impregnation effects on the sorbent properties of activated carbons and biochars, Water Res. 70 (2015) 394–403, https://doi.org/10.1016/ j.watres.2014.12.016 Y. Vieira, M.B. Ceretta, E.L. Foletto, E.A. Wolski, S. Silvestri, Application of a novel rGO-CuFeS2 composite catalyst conjugated to microwave irradiation for ultra-fast real textile wastewater treatment, J. Water Process Eng. 36 (2020) 101397, https://doi.org/10.1016/j.jwpe.2020.101397 J.F. Osma, J.L. Toca-Herrera, S. Rodríguez-Couto, Transformation pathway of Remazol Brilliant Blue R by immobilised laccase, Bioresour. Technol. 101 (22) (2010) 8509–8514 A. Priac, P.-M. Badot, G. Crini, Treated wastewater phytotoxicity assessment using Lactuca sativa: Focus on germination and root elongation test parameters, C. R. Biol. 340 (3) (2017) 188–194 X. Wang, Y. Li, B. Liu, X. Zhou, X. Su, F. Ma, Fe 3 O 4 Nanoparticles Supported on Modified Coal toward Catalytic Hydrogenation of Coal to Oil, ACS Omega. 5 (27) (2020) 16789–16795, https://doi.org/10.1021/ acsomega.0c0183610.1021/acsomega.0c01836.s001 X. Huang, H. Zhao, X. Hu, F. Liu, L.u. Wang, X. Zhao, P. Gao, P. Ji, Optimization of preparation technology for modified coal fly ash and its adsorption properties for Cd2+, J. Hazard. Mater. 392 (2020) 122461, https://doi.org/10.1016/j. jhazmat.2020.122461 Y. Zhou, B. Gao, A.R. Zimmerman, H. Chen, M. Zhang, X. Cao, Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions, Bioresour. Technol. 152 (2014) 538–542, https://doi.org/10.1016/j. biortech.2013.11.021 C.D. Woolard, J. Strong, C.R. Erasmus, Evaluation of the use of modified coal ash as a potential sorbent for organic waste streams, Appl. Geochemistry. 17 (8) (2002) 1159–1164, https://doi.org/10.1016/S0883-2927(02)00057-4 T. Bruno, P. Svoronos, CRC Handbook of Fundamental Spectroscopic Correlation Charts, CRC Press (2005), https://doi.org/10.1201/9781420037685 BD. Mistry, A Handbook of Spectroscopic Data: UV, IR, PMR, CNMR and Mass Spectroscopy, 2009 J. Gañan, C.M. González-Garcı´a, J.F. González, E. Sabio, A. Macı´as-Garcı´ a, M.A. Dı´ az-Dı´ ez, Preparation of activated carbons from bituminous coal pitches, Appl. Surf. Sci. 238 (1-4) (2004) 347–354 A. Ates , K.O. Oskay, KO OSKAY, Preparation and characterization of nanosized Fe3O4-biochar electrocatalysts with large surface area for H2O2 sensing, Surfaces and Interfaces. 29 (2022) 101733 A. Kumar Prajapati, M. Kumar Mondal, Green synthesis of Fe3O4-onion peel biochar nanocomposites for adsorption of Cr(VI), methylene blue and congo red dye from aqueous solutions, J. Mol. Liq. 349 (2022) 118161 R. Foroutan, S.J. Peighambardoust, R. Mohammadi, S.H. Peighambardoust, B. Ramavandi, Development of new magnetic adsorbent of walnut shell ash/ starch/Fe3O4 for effective copper ions removal: Treatment of groundwater samples, Chemosphere. 296 (2022) 133978 J. Chen, P. Zhang, J. Zhang, Y. He, Y.W. Tong, Micro-Nano Magnetite-Loaded Biochar Enhances Interspecies Electron Transfer and Viability of Functional Microorganisms in Anaerobic Digestion, ACS Sustain. Chem. Eng. 10 (2022) 2811–2821, https://doi.org/10.1021/ACSSUSCHEMENG.1C08288/SUPPL_FILE/ SC1C08288_SI_001.PDF G. Zhou, Z. Chen, F. Fang, Y. He, H. Sun, H. Shi, Fenton-like degradation of Methylene Blue using paper mill sludge-derived magnetically separable heterogeneous catalyst: Characterization and mechanism, J. Environ. Sci. 35 (2015) 20–26, https://doi.org/10.1016/J.JES.2015.01.026 M.C. Pereira, C.M. Tavares, J.D. Fabris, R.M. Lago, E. Murad, P.S. Criscuolo, Characterization of a tropical soil and a waste from kaolin mining and their suitability as heterogeneous catalysts for Fenton and Fenton-like reactions, Clay Miner. 42 (3) (2007) 299–306 N. Jaafarzadeh, F. Ghanbari, M. Ahmadi, Catalytic degradation of 2,4- dichlorophenoxyacetic acid (2,4-D) by nano-Fe2O3 activated peroxymonosulfate: Influential factors and mechanism determination, Chemosphere. 169 (2017) 568–576, https://doi.org/10.1016/J. CHEMOSPHERE.2016.11.038 E.R. Bandala, M.A. Peláez, D.D. Dionysiou, S. Gelover, J. Garcia, D. Macías, Degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) using cobalt peroxymonosulfate in Fenton-like process, J. Photochem. Photobiol. A Chem. 186 (2-3) (2007) 357–363 Y. Shi, X. Wang, X. Liu, C. Ling, W. Shen, L. Zhang, Visible light promoted Fe3S4 Fenton oxidation of atrazine, Appl. Catal. B Environ. 277 (2020) 119229 S. Horikoshi, H. Hidaka, N. Serpone, Environmental remediation by an integrated microwave/UV illumination technique VI. A simple modified domestic microwave oven integrating an electrodeless UV-Vis lamp to photodegrade environmental pollutants in aqueous media, J. Photochem. Photobiol. A Chem. 161 (2-3) (2004) 221–225, https://doi.org/10.1016/ j.nainr.2003.07.003 J.G. Yu, X.H. Zhao, H. Yang, X.H. Chen, Q. Yang, L.Y. Yu, J.H. Jiang, X.Q. Chen, Aqueous adsorption and removal of organic contaminants by carbon nanotubes, Sci. Total Environ. 482–483 (2014) 241–251, https://doi.org/ 10.1016/J.SCITOTENV.2014.02.129 L. Bo, X. Quan, S. Chen, H. Zhao, Y. Zhao, Degradation of p-nitrophenol in aqueous solution by microwave assisted oxidation process through a granular activated carbon fixed bed, Water Res. 40 (16) (2006) 3061–3068 N. Wang, Q.i. Hu, X. Du, H. Xu, L. Hao, Study on decolorization of Rhodamine B by raw coal fly ash catalyzed Fenton-like process under microwave irradiation, Adv. Powder Technol. 30 (10) (2019) 2369–2378 P. Grassi, F.C. Drumm, J. da Silveira Salla, S. Silvestri, K. da Boit Martinello, G.L. Dotto, E.L. Foletto, S.L. Jahn, Investigation of the reaction pathway for degradation of emerging contaminant in water by photo-Fenton oxidation using fly ash as low-cost raw catalyst, Int. J. Environ. Res. 14 (2020) 427–438, https://doi.org/10.1007/S41742-020-00266-1/FIGURES/13 F.C. Drumm, P. Grassi, A.A. Sulkovski, D.S.P. Franco, J. Georgin, G.L. Dotto, E.L. Foletto, S.L. Jahn, Applicability of Coal Bottom Ash from Thermoelectric Power Plant as an Alternative Heterogeneous Catalyst in Photo-Fenton Reaction, Water. Air. Soil Pollut. 230 (2019) 1–12, https://doi.org/10.1007/S11270-019- 4327-2/TABLES/6 J. Tang, J. Wang, Fenton-like degradation of sulfamethoxazole using Fe-based magnetic nanoparticles embedded into mesoporous carbon hybrid as an efficient catalyst, Chem. Eng. J. 351 (2018) 1085–1094, https://doi.org/ 10.1016/J.CEJ.2018.06.169 E.M. Hulzebos, E.M. Dirven-Van Breemen, W.A. van Dis, H.A. Herbold, J.A. Hoekstra, R. Baerselman, C.A.M. van Gestel, D.M.M. Adema, L. Henzen, Phytotoxicity studies with Lactuca sativa in soil and nutrient solution, Environ. Toxicol. Chem. 12 (6) (1993) 1079–1094 W. Wang, Root elongation method for toxicity testing of organic and inorganic pollutants, Environ. Toxicol. Chem. 6 (5) (1987) 409–41 F. Zucconi, A. Monaco, M. Forte, M. de Bertoldi, Phytotoxins during the stabilization of organic matter, Compost. Agric. Other Wastes. (1985) 73–86 C. Paredes, M.P. Bernal, A. Roig, J. Cegarra, M.A. Sánchez-Monedero, Influence of the bulking agent on the degradation of olive-mill wastewater sludge during composting, Int. Biodeterior. Biodegradation. 38 (3-4) (1996) 205–210, https:// doi.org/10.1016/S0964-8305(96)00052-2 |
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© 2022 The Society of Powder Technology Japan |
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Atribución 4.0 Internacional (CC BY 4.0) |
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https://creativecommons.org/licenses/by/4.0/ |
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info:eu-repo/semantics/openAccess |
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Atribución 4.0 Internacional (CC BY 4.0) © 2022 The Society of Powder Technology Japan https://creativecommons.org/licenses/by/4.0/ http://purl.org/coar/access_right/c_abf2 |
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openAccess |
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11 páginas |
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application/pdf |
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Elsevier B.V. |
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Netherlands |
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Elsevier B.V. |
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https://www.sciencedirect.com/science/article/pii/S0921883122002497 |
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Corporación Universidad de la Costa |
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Atribución 4.0 Internacional (CC BY 4.0)© 2022 The Society of Powder Technology Japanhttps://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Vieira, YasminRossatto, Diovani L.Leichtweis, JandiraFoletto, Edson L.Oliveira, Marcosvirtual::1162-1Silva, Luisvirtual::1161-1Dotto, Guilherme Luiz2025-05-07T22:00:32Z2025-05-07T22:00:32Z2022-09Yasmin Vieira, Diovani L. Rossatto, Jandira Leichtweis, Edson L. Foletto, Marcos L.S. Oliveira, Luis F.O. Silva, Guilherme Luiz Dotto, Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systems, Advanced Powder Technology, Volume 33, Issue 8, 2022, 103671, ISSN 0921-8831, https://doi.org/10.1016/j.apt.2022.103671. (https://www.sciencedirect.com/science/article/pii/S0921883122002497)0921-8831https://hdl.handle.net/11323/1421110.1016/j.apt.2022.1036711568-5527Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/A novel catalyst was synthesized employing coal and volcanic rock waste (VRW) residues enriched with iron nanoparticles, and its efficiency was investigated upon the degradation of (2,4-dichlorophenoxy)acetic acid (2,4-D) and atrazine (ATZ) pesticides. The composite was synthesized by a facile and effective chemical precipitation technique and extensively characterized by XRD, FTIR, XRF, ICP-OES, ICP-MS, and SEM-EDS. The effects of pH, catalyst dosage, and initial pollutant concentration were investigated in single and binary systems irradiated with microwave (MW) under atmospheric pressure. The optimal reaction conditions were obtained at pH 3 and 5 for 2,4-D and ATZ in single systems and pH 3 in binary systems, respectively, with 20 mg L−1 of initial pollutant concentration and 0.1 g L−1 of CVRWMag (coal, VRW, and nano-Fe3O4) catalyst. The kinetic data fitted better to the pseudo-first-order model (R2 > 0.965). In addition, the phytotoxicity was investigated with Lactuca sativa seeds, and the root elongation and the seed germination rate were enhanced as the MW irradiation time increased. The complete degradation of both compounds was reached within 30 min, with outstanding mineralization efficiency. The degradation efficiency was attributed to hydroxyl radical (radical dotOH) formation and electrostatic surface interaction, enhanced by hot spot formation. Therefore, the CVRWMag is a promising MW absorbing catalyst for the removal and degradation of pesticides without the need for H2O2 or any radical enhancing agent addition11 páginasapplication/pdfengElsevier B.V.Netherlandshttps://www.sciencedirect.com/science/article/pii/S0921883122002497Iron-enriched coal and volcanic rock waste powder composite with enhanced microwave absorption capacity for the degradation of 2,4-D and atrazine pesticides in single and binary systemsArtículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85Advanced Powder TechnologyR. Macirella, G. Madeo, S. Sesti, M. Tripepi, I. Bernabò, N. Godbert, D. La Russa, E. Brunelli, Exposure and post-exposure effects of chlorpyrifos on Carassius auratus gills: an ultrastructural and morphofunctional investigation, Chemosphere 251 (2020) 126434S. Shukla, R.C. Jhamtani, M.S. Dahiya, R. Agarwal, Oxidative injury caused by individual and combined exposure of neonicotinoid, organophosphate and herbicide in zebrafish, Toxicol. Reports. 4 (2017) 240–244, https://doi.org/ 10.1016/J.TOXREP.2017.05.002Ö. Demirci, K. Güven, D. Asma, S. Ög˘üt, P. Ug˘urlu, Effects of endosulfan, thiamethoxam, and indoxacarb in combination with atrazine on multi biomarkers in Gammarus kischineffensis, Ecotoxicol. Environ. Saf. 147 (2018) 749–758, https://doi.org/10.1016/J.ECOENV.2017.09.038K.E. Murray, S.M. Thomas, A.A. Bodour, Prioritizing research for trace pollutants and emerging contaminants in the freshwater environment, Environ. Pollut. 158 (12) (2010) 3462–3471T. Smital, T. Luckenbach, R. Sauerborn, A.M. Hamdoun, R.L. Vega, D. Epel, Emerging contaminants—pesticides, PPCPs, microbial degradation products and natural substances as inhibitors of multixenobiotic defense in aquatic organisms, Mutat. Res. Mol. Mech. Mutagen. 552 (1-2) (2004) 101–117M. Kah, Nanopesticides and Nanofertilizers: Emerging Contaminants or Opportunities for Risk Mitigation?, Front Chem. (2015) 64, https://doi.org/ 10.3389/FCHEM.2015.00064M.-H.Y. Yu, H. Tsunoda, M. Tsunoda, Environmental Toxicology Biological and Health Effects of Pollutants, 2004Y. Jin-Clark, M.J. Lydy, K.Y. Zhu, Effects of atrazine and cyanazine on chlorpyrifos toxicity in Chironomus tentans (Diptera: Chironomidae), Environ. Toxicol. Chem. 21 (3) (2002) 598–603M. Abdennouri, A. Elhalil, M. Farnane, H. Tounsadi, F.Z. Mahjoubi, R. Elmoubarki, M. Sadiq, L. Khamar, A. Galadi, M. Baâlala, M. Bensitel, Y. El hafiane, A. Smith, N. Barka, Photocatalytic degradation of 2,4-D and 2,4-DP herbicides on Pt/TiO2 nanoparticles, J. Saudi Chem. Soc. 19 (5) (2015) 485–493J.A. Pascual Aguilar, V. Andreu, J. Campo, Y. Picó, A. Masiá, Pesticide occurrence in the waters of Júcar River, Spain from different farming landscapes, Sci. Total Environ. 607–608 (2017) 752–760, https://doi.org/10.1016/J. SCITOTENV.2017.06.176Y.-F. Jiang, X.-T. Wang, Y. Jia, F. Wang, M.-H. Wu, G.-Y. Sheng, J.-M. Fu, Occurrence, distribution and possible sources of organochlorine pesticides in agricultural soil of Shanghai, China, J. Hazard. Mater. 170 (2-3) (2009) 989–997D.W. Kolpin*, J.E. Barbash, R.J. Gilliom, Occurrence of Pesticides in Shallow Groundwater of the United States: Initial Results from the National Water Quality Assessment Program, Environ. Sci. Technol. 32 (1998) 558–566. https://doi.org/10.1021/ES970412GD. Ramírez-Morales, M.E. Pérez-Villanueva, J.S. Chin-Pampillo, P. Aguilar Mora, V. Arias-Mora, M. Masís-Mora, Pesticide occurrence and water quality assessment from an agriculturally influenced Latin-American tropical region, Chemosphere. 262 (2021) 127851B.J. Mahler, L.H. Nowell, M.W. Sandstrom, P.M. Bradley, K.M. Romanok, C.P. Konrad, P.C. Van Metre, Van Metre, Inclusion of Pesticide Transformation Products Is Key to Estimating Pesticide Exposures and Effects in Small U.S. Streams, Environ. Sci. Technol. 55 (8) (2021) 4740–4752J. Stanley, G. Preetha, Pesticide toxicity to non-target organisms: Exposure, toxicity and risk assessment methodologies, Pestic. Toxic. to Non-Target Org, Expo. Toxic. Risk Assess. Methodol. (2016) 1–502, https://doi.org/10.1007/ 978-94-017-7752-0L. Bakker, J. Sok, W. van der Werf, F.J.J.A. Bianchi, Kicking the Habit: What Makes and Breaks Farmers’ Intentions to Reduce Pesticide Use?, Ecol Econ. 180 (2021) 106868A. Bagheri, N. Emami, C.A. Damalas, Farmers’ behavior towards safe pesticide handling: An analysis with the theory of planned behavior, Sci. Total Environ. 751 (2021) 141709M. Tudi, H. Daniel Ruan, L.i. Wang, J. Lyu, R. Sadler, D. Connell, C. Chu, D.T. Phung, Agriculture Development, Pesticide Application and Its Impact on the Environment, IJERPH 18 (3) (2021) 1112, https://doi.org/10.3390/ ijerph18031112M. Yeganeh, E. Charkhloo, H.R. Sobhi, A. Esrafili, M. Gholami, Photocatalytic processes associated with degradation of pesticides in aqueous solutions: Systematic review and meta-analysis, Chem. Eng. J. 428 (2022) 130081S. Horikoshi, A. Osawa, S. Sakamoto, N. Serpone, Control of microwave generated hot spots. Part V. Mechanisms of hot-spot generation and aggregation of catalyst in a microwave-assisted reaction in toluene catalyzed by Pd-loaded AC particulates, Appl. Catal. A Gen. 460–461 (2013) 52–60, https://doi.org/10.1016/j.apcata.2013.04.022S. Horikoshi, N. Serpone, Coupled microwave/photoassisted methods for environmental remediation, Molecules. 19 (2014) 18102–18128, https://doi. org/10.3390/molecules191118102Y. Vieira, S. Silvestri, J. Leichtweis, S.L. Jahn, É.M. de Moraes Flores, G.L. Dotto, E. L. Foletto, New insights into the mechanism of heterogeneous activation of nano–magnetite by microwave irradiation for use as Fenton catalyst, J. Environ Chem. Eng. 8 (3) (2020) 103787S. Horikoshi, M. Abe, N. Serpone, Novel designs of microwave discharge electrodeless lamps (MDEL) in photochemical applications. Use in advanced oxidation processes, Photochem. Photobiol. Sci. 8 (8) (2009) 1087, https://doi. org/10.1039/b818491gY. Vieira, H.A. Pereira, J. Leichtweis, C.M. Mistura, E.L. Foletto, L.F.S. Oliveira, G. L. Dotto, Effective treatment of hospital wastewater with high-concentration diclofenac and ibuprofen using a promising technology based on degradation reaction catalyzed by Fe0 under microwave irradiation, Sci. Total Environ. 783 (2021) 146991, https://doi.org/10.1016/j.scitotenv.2021.146991S. Horikoshi, A. Osawa, M. Abe, N. Serpone, On the generation of hot-spots by microwave electric and magnetic fields and their impact on a microwave assisted heterogeneous reaction in the presence of metallic Pd nanoparticles on an activated carbon support, J. Phys. Chem. C. 115 (46) (2011) 23030– 23035, https://doi.org/10.1021/jp2076269C. Xue, Y. Mao, W. Wang, Z. Song, X. Zhao, J. Sun, Y. Wang, Current status of applying microwave-associated catalysis for the degradation of organics in aqueous phase – A review, J. Environ. Sci. (China) 81 (2019) 119–135, https:// doi.org/10.1016/j.jes.2019.01.019R. Wei, P. Wang, G. Zhang, N. Wang, T. Zheng, Microwave-responsive catalysts for wastewater treatment: A review, Chem. Eng. J. 382 (2020) 122781, https:// doi.org/10.1016/j.cej.2019.122781S. Liu, L. Mei, X. Liang, L. Liao, G. Lv, S. Ma, S. Lu, A. Abdelkader, K. Xi, Anchoring Fe3O4 Nanoparticles on Carbon Nanotubes for Microwave-Induced Catalytic Degradation of Antibiotics, ACS Appl. Mater. Interfaces. 10 (35) (2018) 29467– 29475S.P. Pawar, M. Gandi, S. Bose, High performance electromagnetic wave absorbers derived from PC/SAN blends containing multiwall carbon nanotubes and Fe 3 O 4 decorated onto graphene oxide sheets, RSC Adv. 6 (44) (2016) 37633–37645, https://doi.org/10.1039/C5RA25435CN. Wang, X. Sun, Q. Zhao, Y. Yang, P. Wang, Leachability and adverse effects of coal fly ash: A review, J. Hazard. Mater. 396 (2020) 122725N. Wang, X. Sun, Q. Zhao, P. Wang, Treatment of polymer-flooding wastewater by a modified coal fly ash-catalysed Fenton-like process with microwave pre enhancement: System parameters, kinetics, and proposed mechanism, Chem. Eng. J. 406 (2021) 126734N. Wang, L.u. Jin, C. Li, Y. Liang, P. Wang, Preparation of coal fly ash-based Fenton-like catalyst and its application for the treatment of organic wastewater under microwave assistance, J. Clean. Prod. 342 (2022) 130926Z. Zhang, J. Jiatieli, D. Liu, F. Yu, S. Xue, W. Gao, Y. Li, D.D. Dionysiou, Microwave induced degradation of parathion in the presence of supported anatase- and rutile-TiO2/AC and comparison of their catalytic activity, Chem. Eng. J. 231 (2013) 84–93, https://doi.org/10.1016/J.CEJ.2013.07.001X. Quan, Y. Zhang, S. Chen, Y. Zhao, F. Yang, Generation of hydroxyl radical in aqueous solution by microwave energy using activated carbon as catalyst and its potential in removal of persistent organic substances, J. Mol. Catal. A Chem. 263 (1-2) (2007) 216–222M. Shen, L. Fu, J. Tang, M. Liu, Y. Song, F. Tian, Z. Zhao, Z. Zhang, D.D. Dionysiou, Microwave hydrothermal-assisted preparation of novel spinel NiFe2O4/natural mineral composites as microwave catalysts for degradation of aquatic organic pollutants, J. Hazard. Mater. 350 (2018) 1–9, https://doi.org/ 10.1016/J.JHAZMAT.2018.02.014H. Teng, L.-Y. Hsu, High-Porosity Carbons Prepared from Bituminous Coal with Potassium Hydroxide Activation, (1999). https://doi.org/10.1021/ ie990101C.G. Ramos, X. Querol, M.L.S. Oliveira, K. Pires, R.M. Kautzmann, L.F.O. Silva, A preliminary evaluation of volcanic rock powder for application in agriculture as soil a remineralizer, Sci. Total Environ. 512–513 (2015) 371–380, https:// doi.org/10.1016/j.scitotenv.2014.12.070P. Panneerselvam, N. Morad, K.A. Tan, Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel(II) from aqueous solution, J. Hazard. Mater. 186 (1) (2011) 160–168, https://doi.org/10.1016/j. jhazmat.2010.10.102C.S. Castro, M.C. Guerreiro, M. Gonçalves, L.C.A. Oliveira, A.S. Anastácio, Activated carbon/iron oxide composites for the removal of atrazine from aqueous medium, J. Hazard. Mater. 164 (2-3) (2009) 609–614, https://doi.org/ 10.1016/j.jhazmat.2008.08.066Z. Han, B. Sani, W. Mrozik, M. Obst, B. Beckingham, H.K. Karapanagioti, D. Werner, Magnetite impregnation effects on the sorbent properties of activated carbons and biochars, Water Res. 70 (2015) 394–403, https://doi.org/10.1016/ j.watres.2014.12.016Y. Vieira, M.B. Ceretta, E.L. Foletto, E.A. Wolski, S. Silvestri, Application of a novel rGO-CuFeS2 composite catalyst conjugated to microwave irradiation for ultra-fast real textile wastewater treatment, J. Water Process Eng. 36 (2020) 101397, https://doi.org/10.1016/j.jwpe.2020.101397J.F. Osma, J.L. Toca-Herrera, S. Rodríguez-Couto, Transformation pathway of Remazol Brilliant Blue R by immobilised laccase, Bioresour. Technol. 101 (22) (2010) 8509–8514A. Priac, P.-M. Badot, G. Crini, Treated wastewater phytotoxicity assessment using Lactuca sativa: Focus on germination and root elongation test parameters, C. R. Biol. 340 (3) (2017) 188–194X. Wang, Y. Li, B. Liu, X. Zhou, X. Su, F. Ma, Fe 3 O 4 Nanoparticles Supported on Modified Coal toward Catalytic Hydrogenation of Coal to Oil, ACS Omega. 5 (27) (2020) 16789–16795, https://doi.org/10.1021/ acsomega.0c0183610.1021/acsomega.0c01836.s001X. Huang, H. Zhao, X. Hu, F. Liu, L.u. Wang, X. Zhao, P. Gao, P. Ji, Optimization of preparation technology for modified coal fly ash and its adsorption properties for Cd2+, J. Hazard. Mater. 392 (2020) 122461, https://doi.org/10.1016/j. jhazmat.2020.122461Y. Zhou, B. Gao, A.R. Zimmerman, H. Chen, M. Zhang, X. Cao, Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions, Bioresour. Technol. 152 (2014) 538–542, https://doi.org/10.1016/j. biortech.2013.11.021C.D. Woolard, J. Strong, C.R. Erasmus, Evaluation of the use of modified coal ash as a potential sorbent for organic waste streams, Appl. Geochemistry. 17 (8) (2002) 1159–1164, https://doi.org/10.1016/S0883-2927(02)00057-4T. Bruno, P. Svoronos, CRC Handbook of Fundamental Spectroscopic Correlation Charts, CRC Press (2005), https://doi.org/10.1201/9781420037685BD. Mistry, A Handbook of Spectroscopic Data: UV, IR, PMR, CNMR and Mass Spectroscopy, 2009J. Gañan, C.M. González-Garcı´a, J.F. González, E. Sabio, A. Macı´as-Garcı´ a, M.A. Dı´ az-Dı´ ez, Preparation of activated carbons from bituminous coal pitches, Appl. Surf. Sci. 238 (1-4) (2004) 347–354A. Ates , K.O. Oskay, KO OSKAY, Preparation and characterization of nanosized Fe3O4-biochar electrocatalysts with large surface area for H2O2 sensing, Surfaces and Interfaces. 29 (2022) 101733A. Kumar Prajapati, M. Kumar Mondal, Green synthesis of Fe3O4-onion peel biochar nanocomposites for adsorption of Cr(VI), methylene blue and congo red dye from aqueous solutions, J. Mol. Liq. 349 (2022) 118161R. Foroutan, S.J. Peighambardoust, R. Mohammadi, S.H. Peighambardoust, B. Ramavandi, Development of new magnetic adsorbent of walnut shell ash/ starch/Fe3O4 for effective copper ions removal: Treatment of groundwater samples, Chemosphere. 296 (2022) 133978J. Chen, P. Zhang, J. Zhang, Y. He, Y.W. Tong, Micro-Nano Magnetite-Loaded Biochar Enhances Interspecies Electron Transfer and Viability of Functional Microorganisms in Anaerobic Digestion, ACS Sustain. Chem. Eng. 10 (2022) 2811–2821, https://doi.org/10.1021/ACSSUSCHEMENG.1C08288/SUPPL_FILE/ SC1C08288_SI_001.PDFG. Zhou, Z. Chen, F. Fang, Y. He, H. Sun, H. Shi, Fenton-like degradation of Methylene Blue using paper mill sludge-derived magnetically separable heterogeneous catalyst: Characterization and mechanism, J. Environ. Sci. 35 (2015) 20–26, https://doi.org/10.1016/J.JES.2015.01.026M.C. Pereira, C.M. Tavares, J.D. Fabris, R.M. Lago, E. Murad, P.S. Criscuolo, Characterization of a tropical soil and a waste from kaolin mining and their suitability as heterogeneous catalysts for Fenton and Fenton-like reactions, Clay Miner. 42 (3) (2007) 299–306N. Jaafarzadeh, F. Ghanbari, M. Ahmadi, Catalytic degradation of 2,4- dichlorophenoxyacetic acid (2,4-D) by nano-Fe2O3 activated peroxymonosulfate: Influential factors and mechanism determination, Chemosphere. 169 (2017) 568–576, https://doi.org/10.1016/J. CHEMOSPHERE.2016.11.038E.R. Bandala, M.A. Peláez, D.D. Dionysiou, S. Gelover, J. Garcia, D. Macías, Degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) using cobalt peroxymonosulfate in Fenton-like process, J. Photochem. Photobiol. A Chem. 186 (2-3) (2007) 357–363Y. Shi, X. Wang, X. Liu, C. Ling, W. Shen, L. Zhang, Visible light promoted Fe3S4 Fenton oxidation of atrazine, Appl. Catal. B Environ. 277 (2020) 119229S. Horikoshi, H. Hidaka, N. Serpone, Environmental remediation by an integrated microwave/UV illumination technique VI. A simple modified domestic microwave oven integrating an electrodeless UV-Vis lamp to photodegrade environmental pollutants in aqueous media, J. Photochem. Photobiol. A Chem. 161 (2-3) (2004) 221–225, https://doi.org/10.1016/ j.nainr.2003.07.003J.G. Yu, X.H. Zhao, H. Yang, X.H. Chen, Q. Yang, L.Y. Yu, J.H. Jiang, X.Q. Chen, Aqueous adsorption and removal of organic contaminants by carbon nanotubes, Sci. Total Environ. 482–483 (2014) 241–251, https://doi.org/ 10.1016/J.SCITOTENV.2014.02.129L. Bo, X. Quan, S. Chen, H. Zhao, Y. Zhao, Degradation of p-nitrophenol in aqueous solution by microwave assisted oxidation process through a granular activated carbon fixed bed, Water Res. 40 (16) (2006) 3061–3068N. Wang, Q.i. Hu, X. Du, H. Xu, L. Hao, Study on decolorization of Rhodamine B by raw coal fly ash catalyzed Fenton-like process under microwave irradiation, Adv. Powder Technol. 30 (10) (2019) 2369–2378P. Grassi, F.C. Drumm, J. da Silveira Salla, S. Silvestri, K. da Boit Martinello, G.L. Dotto, E.L. Foletto, S.L. Jahn, Investigation of the reaction pathway for degradation of emerging contaminant in water by photo-Fenton oxidation using fly ash as low-cost raw catalyst, Int. J. Environ. Res. 14 (2020) 427–438, https://doi.org/10.1007/S41742-020-00266-1/FIGURES/13F.C. Drumm, P. Grassi, A.A. Sulkovski, D.S.P. Franco, J. Georgin, G.L. Dotto, E.L. Foletto, S.L. Jahn, Applicability of Coal Bottom Ash from Thermoelectric Power Plant as an Alternative Heterogeneous Catalyst in Photo-Fenton Reaction, Water. Air. Soil Pollut. 230 (2019) 1–12, https://doi.org/10.1007/S11270-019- 4327-2/TABLES/6J. Tang, J. Wang, Fenton-like degradation of sulfamethoxazole using Fe-based magnetic nanoparticles embedded into mesoporous carbon hybrid as an efficient catalyst, Chem. Eng. J. 351 (2018) 1085–1094, https://doi.org/ 10.1016/J.CEJ.2018.06.169E.M. Hulzebos, E.M. Dirven-Van Breemen, W.A. van Dis, H.A. Herbold, J.A. Hoekstra, R. Baerselman, C.A.M. van Gestel, D.M.M. Adema, L. Henzen, Phytotoxicity studies with Lactuca sativa in soil and nutrient solution, Environ. Toxicol. Chem. 12 (6) (1993) 1079–1094W. Wang, Root elongation method for toxicity testing of organic and inorganic pollutants, Environ. Toxicol. Chem. 6 (5) (1987) 409–41F. Zucconi, A. Monaco, M. Forte, M. de Bertoldi, Phytotoxins during the stabilization of organic matter, Compost. Agric. Other Wastes. (1985) 73–86C. Paredes, M.P. Bernal, A. Roig, J. Cegarra, M.A. Sánchez-Monedero, Influence of the bulking agent on the degradation of olive-mill wastewater sludge during composting, Int. Biodeterior. 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
 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