Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras

In the present work, an evaluation was made of clam (Polymesoda sp.), oyster (Crassostrea rhizophorae) and coral rock (Coquina) shells as bioadsorbent materials for dye removal in wastewater from the textile industry. These materials were prepared and brought to different particle diameters (300 um...

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Autores:
Coronado Herrera, Carolanne
Rhenals Navarro, Jean Carlos
Tipo de recurso:
Trabajo de grado de pregrado
Fecha de publicación:
2024
Institución:
Corporación Universidad de la Costa
Repositorio:
REDICUC - Repositorio CUC
Idioma:
OAI Identifier:
oai:repositorio.cuc.edu.co:11323/13446
Acceso en línea:
https://hdl.handle.net/11323/13446
https://repositorio.cuc.edu.co/
Palabra clave:
Bioadsorbent
Colorant
Oyster shells
Coquina rock
Removal
Bioadsorbente
Colorante
Conchas de ostras
Roca coquina
Remoción
Rights
openAccess
License
Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)
id RCUC2_a5800e4f58abef4942c947c4218d7d2d
oai_identifier_str oai:repositorio.cuc.edu.co:11323/13446
network_acronym_str RCUC2
network_name_str REDICUC - Repositorio CUC
repository_id_str
dc.title.spa.fl_str_mv Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
title Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
spellingShingle Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
Bioadsorbent
Colorant
Oyster shells
Coquina rock
Removal
Bioadsorbente
Colorante
Conchas de ostras
Roca coquina
Remoción
title_short Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
title_full Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
title_fullStr Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
title_full_unstemmed Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
title_sort Remoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostras
dc.creator.fl_str_mv Coronado Herrera, Carolanne
Rhenals Navarro, Jean Carlos
dc.contributor.advisor.none.fl_str_mv Gómez Plata Leandro
Moreno Ríos Andrea
dc.contributor.author.none.fl_str_mv Coronado Herrera, Carolanne
Rhenals Navarro, Jean Carlos
dc.contributor.jury.none.fl_str_mv Cantero Ruben
Yanes Andrea
dc.subject.proposal.eng.fl_str_mv Bioadsorbent
Colorant
Oyster shells
Coquina rock
Removal
topic Bioadsorbent
Colorant
Oyster shells
Coquina rock
Removal
Bioadsorbente
Colorante
Conchas de ostras
Roca coquina
Remoción
dc.subject.proposal.spa.fl_str_mv Bioadsorbente
Colorante
Conchas de ostras
Roca coquina
Remoción
description In the present work, an evaluation was made of clam (Polymesoda sp.), oyster (Crassostrea rhizophorae) and coral rock (Coquina) shells as bioadsorbent materials for dye removal in wastewater from the textile industry. These materials were prepared and brought to different particle diameters (300 um and less than 300 um). Subsequently, a thermal modification of the bio-adsorbent material was carried out using an initial drying at 120°C and then a calcination at temperatures: 200°C, 400°C and 600°C, to later be analyzed through different characterization techniques. (PZC, XRD, FTIR, TGA and BET). Mounts were made in the laboratory using a brilliant green dye stock solution. From this solution solutions were prepared at different concentrations (25, 50 and 75 mg/L) which were put in contact with the bioadsorbent at different pH values (between 2 and 12) with different doses of adsorbent material (between 0.2 at 0.6 g/L) and kept under constant stirring. Aliquots were taken from each experiment at different time intervals and the dye adsorption process was measured by visible ultraviolet radiation at a wavelength of 640 nm. Coquina rock was selected as the best material at a temperature of 120ºC and with a diameter greater than 300 um, with which a removal percentage of 90% was obtained in a given time between 15 and 20 minutes at pH 7. The foregoing allows us to conclude that Coquina rock is a viable and easily accessible bioadsorbent material for dye removal in textile wastewater.
publishDate 2024
dc.date.accessioned.none.fl_str_mv 2024-10-16T20:58:37Z
dc.date.available.none.fl_str_mv 2024-10-16T20:58:37Z
dc.date.issued.none.fl_str_mv 2024
dc.type.none.fl_str_mv Trabajo de grado - Pregrado
dc.type.coar.none.fl_str_mv http://purl.org/coar/resource_type/c_7a1f
dc.type.content.none.fl_str_mv Text
dc.type.driver.none.fl_str_mv info:eu-repo/semantics/bachelorThesis
dc.type.redcol.none.fl_str_mv http://purl.org/redcol/resource_type/TP
dc.type.version.none.fl_str_mv info:eu-repo/semantics/acceptedVersion
format http://purl.org/coar/resource_type/c_7a1f
status_str acceptedVersion
dc.identifier.uri.none.fl_str_mv https://hdl.handle.net/11323/13446
dc.identifier.instname.none.fl_str_mv Corporación Universidad de la Costa
dc.identifier.reponame.none.fl_str_mv REDICUC - Repositorio CUC
dc.identifier.repourl.none.fl_str_mv https://repositorio.cuc.edu.co/
url https://hdl.handle.net/11323/13446
https://repositorio.cuc.edu.co/
identifier_str_mv Corporación Universidad de la Costa
REDICUC - Repositorio CUC
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spelling Atribución-NoComercial-CompartirIgual 4.0 Internacional (CC BY-NC-SA 4.0)https://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Gómez Plata LeandroMoreno Ríos AndreaCoronado Herrera, CarolanneRhenals Navarro, Jean CarlosCantero RubenYanes Andrea2024-10-16T20:58:37Z2024-10-16T20:58:37Z2024https://hdl.handle.net/11323/13446Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/In the present work, an evaluation was made of clam (Polymesoda sp.), oyster (Crassostrea rhizophorae) and coral rock (Coquina) shells as bioadsorbent materials for dye removal in wastewater from the textile industry. These materials were prepared and brought to different particle diameters (300 um and less than 300 um). Subsequently, a thermal modification of the bio-adsorbent material was carried out using an initial drying at 120°C and then a calcination at temperatures: 200°C, 400°C and 600°C, to later be analyzed through different characterization techniques. (PZC, XRD, FTIR, TGA and BET). Mounts were made in the laboratory using a brilliant green dye stock solution. From this solution solutions were prepared at different concentrations (25, 50 and 75 mg/L) which were put in contact with the bioadsorbent at different pH values (between 2 and 12) with different doses of adsorbent material (between 0.2 at 0.6 g/L) and kept under constant stirring. Aliquots were taken from each experiment at different time intervals and the dye adsorption process was measured by visible ultraviolet radiation at a wavelength of 640 nm. Coquina rock was selected as the best material at a temperature of 120ºC and with a diameter greater than 300 um, with which a removal percentage of 90% was obtained in a given time between 15 and 20 minutes at pH 7. The foregoing allows us to conclude that Coquina rock is a viable and easily accessible bioadsorbent material for dye removal in textile wastewater.En el presente trabajo se realizó la evaluación de materiales provenientes de conchas de ostra (roca coralina: Coquina) como bioadsorbentes para la remoción de colorante en aguas residuales de la industria textil. Dichos materiales fueron llevados a diferentes diámetros de partícula (300 um y menor a 300 um) y posteriormente modificados térmicamente utilizando un secado a 120°C y calcinación a temperaturas entre200°Cy 800 °C, para luego ser analizadas a través de diferentes técnicas de caracterización (PZC, DRX, FTIR, TGA y BET).Para evaluar la capacidad de remoción, así como la cinética de adsorción de los bioadsorbentes, se realizaron montajes en el laboratorio utilizando el colorante verde brillante. Para lo anterior, se evaluaron concentraciones de colorante de 25, 50 y 75 mg/L; pH entre 2 y 12 y dosis de material bioadsorbente entre 0.2 a 0.6 g/L, con agitación constante. De cada experimento se tomaron alícuotas a diferentes intervalos de tiempo a las que se les realizó medición de la absorbancia a una longitud de onda de 640 nm para la posterior determinación de la concentración de colorante en cada instante de tiempo y determinación del porcentaje y capacidad de remoción. . Se seleccionó como mejor material la roca coquina a temperatura de 120ºC y a un diámetro mayor a 300 um, con la cual se obtuvo un porcentaje de remoción del 90% en un tiempo determinado ente 15 y 20 minutos a pH 7. Lo anterior permite concluir que la roca coquina es un material bioadsorbente viable y de fácil acceso para la remoción de colorante en agua residual textilLista de tablas y figuras 11 -- Planteamiento del problema 17 – Justificación 26 –Objetivos 28 -- General 28 -- Específicos 28 –Antecedentes 29 -- Marco teórico 33 --Contaminación de los cuerpos de agua por aguas residuales textiles 33 -- Colorantes textiles 34 -- Colorante Verde Brillante 39 -- Tratamiento de colorantes textiles 40 --Remediación física y química 41 -- Adsorción 42 -- Factores que influyen en la adsorción 42 -- Punto de carga cero 42 -- Tamaño de partícula 43 -- Concentración inicial de colorante 43 -- Cantidad de adsorbente 43 -- Tiempo de contacto 44 – pH 44 -- Temperatura 44 -- Técnicas de caracterización 45 -- Difracción de rayos X (DRX o XRD 45 -- Irradiación infrarroja por transformada de Fourier (FT-IR 46 -- Análisis Termogravimétrico (TGA 46 -- Análisis de área superficial y porosidad (BET) 46 -- Materiales bioadsorbentes 48 -- Ostra (Crassostrea rhizophorae 49 -- Almeja (Polymesoda 49 -- Roca coralina (Coquina). 50 -- Estudio Cinético 50 -- Modelos cinéticos empleados 51 -- Pseudo primer orden 51 -- Pseudo-segundo orden 52 -- Modelo Elovich 52 -- Modelo de Intraparticula 53 -- Diseño metodológico 54 -- Obtención de materiales 54 -- Fase I: preparación de materiales bioadsorbentes 54 -- Fase II: Caracterización del material bioadsorbente 56 -- Estudio de carga Zero (pH 56 -- Análisis DRX 58 -- Análisis FTIR 58 -- Análisis TGA 59 -- Análisis BET 59 -- Fase III: Cinética de adsorción 60 -- Evaluación de la remoción de los colorantes 60 -- Pruebas realizadas en el laboratorio - cinética de adsorción 61 -- Resultados y discusión 64 -- Caracterización del material 64 -- Análisis DRX 65 -- Análisis FTIR 67 -- Análisis TGA 69 -- Análisis BET 71 -- Determinación de datos preliminares 73 -- Punto de carga cero (PCZ 75 -- Análisis de determinación de pH 75 -- Variación de concentración inicial de colorante 77 -- Variación de dosis de adsorbente 79 -- 10 Cinética de adsorción 81 – Conclusiones 88 – Recomendaciones 90—Referencias 92 – Anexos 108 --Ingeniero(a) AmbientalPregrado110 páginasapplication/pdfCorporacion Universidad de la CostaCivil y AmbientalBarranquillaIngeniería AmbientalRemoción de colorantes en aguas residuales de la industria textil por medio de material bioadsorbente proveniente de concha de ostrasTrabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_7a1fTextinfo:eu-repo/semantics/bachelorThesishttp://purl.org/redcol/resource_type/TPinfo:eu-repo/semantics/acceptedVersionAdeleke, O. 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
