Electrification of industrial processes as an alternative to replace conventional thermal power sources.
The electrification of industrial processes offers sustainable opportunities for reducing carbon footprints and enhancing energy efficiency in the chemical industry. This paper presents an overview of recent research developments in incorporating electrical energy as a replacement for conventional t...
- Autores:
-
Muñoz Maldonado, Yecid
Correa Quintana, Edgar
Ospino Castro, Adalberto
Ospino C., Adalberto
- Tipo de recurso:
- Article of investigation
- Fecha de publicación:
- 2023
- Institución:
- Corporación Universidad de la Costa
- Repositorio:
- REDICUC - Repositorio CUC
- Idioma:
- eng
- OAI Identifier:
- oai:repositorio.cuc.edu.co:11323/13608
- Acceso en línea:
- https://hdl.handle.net/11323/13608
https://repositorio.cuc.edu.co/
- Palabra clave:
- Chemical process electrification
Electric–magnetic fields
Heat pumps
Microwaves
Plasma
- Rights
- openAccess
- License
- Atribución 4.0 Internacional (CC BY 4.0)
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| dc.title.eng.fl_str_mv |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| title |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| spellingShingle |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. Chemical process electrification Electric–magnetic fields Heat pumps Microwaves Plasma |
| title_short |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| title_full |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| title_fullStr |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| title_full_unstemmed |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| title_sort |
Electrification of industrial processes as an alternative to replace conventional thermal power sources. |
| dc.creator.fl_str_mv |
Muñoz Maldonado, Yecid Correa Quintana, Edgar Ospino Castro, Adalberto Ospino C., Adalberto |
| dc.contributor.author.none.fl_str_mv |
Muñoz Maldonado, Yecid Correa Quintana, Edgar Ospino Castro, Adalberto Ospino C., Adalberto |
| dc.subject.proposal.eng.fl_str_mv |
Chemical process electrification Electric–magnetic fields Heat pumps Microwaves Plasma |
| topic |
Chemical process electrification Electric–magnetic fields Heat pumps Microwaves Plasma |
| description |
The electrification of industrial processes offers sustainable opportunities for reducing carbon footprints and enhancing energy efficiency in the chemical industry. This paper presents an overview of recent research developments in incorporating electrical energy as a replacement for conventional thermal sources like gas and coal in industrial sectors. A literature review was conducted, identifying 70 relevant articles published until September 2020. The topics cover applications for industrial hydrogen generation processes and others, heat pumps, heat pumps, vapor re-compression systems, electric and magnetic fields as heat sources, nanoparticles for improved heat exchange, and ionized gases (plasma) in heating systems. While the application of industrial electrification shows promise globally, its sustainability depends on the efficiency and cost of electrical energy production and transportation at the regional and national levels. Among the various technologies, heat pumps integrated with vapor re-compression systems (VCR) for chemical processes, particularly in industrial distillation product separation columns, appear to be the most viable and widely applicable for waste heat recovery in the near future. Other technologies like electrochemical, plasma, microwave, magnetic, and electric field heating are still in the early stages of development or are limited to specific pilot or laboratory-scale processes. |
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2023 |
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2023-09-29 |
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2024-10-30T15:49:54Z |
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2024-10-30T15:49:54Z |
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Artículo de revista |
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Muñoz-Maldonado, Y.; Correa-Quintana, E.; Ospino-Castro, A. Electrification of Industrial Processes as an Alternative to Replace Conventional Thermal Power Sources. Energies 2023, 16, 6894. https://doi.org/10.3390/en16196894. |
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https://hdl.handle.net/11323/13608 |
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10.3390/en16196894 |
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1996-1073 |
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Corporación Universidad de la Costa |
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REDICUC - Repositorio CUC |
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https://repositorio.cuc.edu.co/ |
| identifier_str_mv |
Muñoz-Maldonado, Y.; Correa-Quintana, E.; Ospino-Castro, A. Electrification of Industrial Processes as an Alternative to Replace Conventional Thermal Power Sources. Energies 2023, 16, 6894. https://doi.org/10.3390/en16196894. 10.3390/en16196894 1996-1073 Corporación Universidad de la Costa REDICUC - Repositorio CUC |
| url |
https://hdl.handle.net/11323/13608 https://repositorio.cuc.edu.co/ |
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eng |
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eng |
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Energies |
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Rissman, J.; Bataille, C.; Masanet, E.; Aden, N.; Morrow, W.R.; Zhou, N.; Elliott, N.; Dell, R.; Heeren, N.; Huckestein, B.; et al. Technologies and policies to decarbonize global industry: Review and assessment of mitigation drivers through 2070. Appl. Energy 2020, 266, 114848. [CrossRef] Kleidon, A. Energy Balance. In Encyclopedia of Ecology, 2nd ed.; Elsevier B.V.: Amsterdam, The Netherlands, 2019; pp. 50–63. [CrossRef] Energy Transition Commission. Reaching Net-Zero Carbon Emissions from Harder-to-Abate Sectors by Mid-Century; Energy Transition Commission: London, UK, 2018. U.S. DOE; EERE Advanced Manufacturing Office. Manufacturing Energy and Carbon Footprints (2014 MECS). 2018. Available online: https://www.energy.gov/eere/amo/%0Amanufacturing-energy-and-carbon-footprints-2014-mecs (accessed on 18 October 2020) U.S. Department. of Energy. Quadrennial Technology Review: Process Heating Technology Assessment; U.S. Department of Energy: Washington, DC, USA, 2019. Available online: https://energy.gov/sites/prod/files/2016/06/f32/%0AQTR2015-6I-Process-Hea ting.pdf (accessed on 10 August 2019). Van Kranenburg, K.; Schols, E.; Gelevert, H.; De Kler, R.; Van Delft, Y.; Weeda, M. Empowering the Chemical Industry. Opportunities for Electrification; Tno-Ecn. 2016, p. 32. Available online: https://www.tno.nl/media/7514/voltachem_electrificat ion_whitepaper_2016.pdf (accessed on 5 July 2023) Gerres, T.; Ávila, J.P.C.; Llamas, P.L.; Román, T.G.S. A review of cross-sector decarbonisation potentials in the European energy intensive industry. J. Clean. Prod. 2019, 210, 585–601. [CrossRef] Rajabloo, T.; De Ceuninck, W.; Van Wortswinkel, L.; Rezakazemi, M.; Aminabhavi, T. Environmental management of industrial decarbonization with focus on chemical sectors: A review. J. Environ. Manag. 2022, 302, 114055. [CrossRef] Wei, M.; McMillan, C.A.; Can, S.D.L.R.D. Electrification of industry: Potential, challenges and outlook. Curr. Sustain. Energy Rep. 2019, 6, 140–148. [CrossRef] Van Geem, K.M.; Weckhuysen, B.M. Toward an e-chemistree: Materials for electrification of the chemical industry. MRS Bull. 2021, 46, 1187–1196. [CrossRef] Hassan, A.; Patel, M.K.; Parra, D. An assessment of the impacts of renewable and conventional electricity supply on the cost and value of power-to-gas. Int. J. Hydrogen Energy 2019, 44, 9577–9593. [CrossRef] Arpagaus, C.; Bless, F.; Uhlmann, M.; Schiffmann, J.; Bertsch, S.S. High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials. Energy 2018, 152, 985–1010. [CrossRef] van de Bor, D.; Ferreira, C.I. Quick selection of industrial heat pump types including the impact of thermodynamic losses. Energy 2013, 53, 312–322. [CrossRef] Waite, M.; Modi, V. Electricity Load Implications of Space Heating Decarbonization Pathways. Joule 2020, 4, 376–394. [CrossRef] Nellissen, P.; Wolf, S. Heat Pumps in Non-Domestic Applications in Europe: Potential for an Energy Revolution. 8th EHPA Eur. Heat Pump Forum, 28 May 2015, Brussels, no. 2015. 2015, pp. 1–17. Available online: https://docplayer.net/41987374-Heat-pu mps-in-non-domestic-applications-in-europe-potential-for-an-energy-revolution.html (accessed on 5 July 2023) Kosmadakis, G. Estimating the potential of industrial (high-temperature) heat pumps for exploiting waste heat in EU industries. Appl. Therm. Eng. 2019, 156, 287–298. [CrossRef] Motasemi, F.; Afzal, M.T. A review on the microwave-assisted pyrolysis technique. Renew. Sustain. Energy Rev. 2013, 28, 317–330. [CrossRef] Wang, Z.; Gao, D.; Diao, B.; Tan, L.; Zhang, W.; Liu, K. Comparative performance of electric heater vs. RF heating for heavy oil recovery. Appl. Therm. Eng. 2019, 160, 114105. [CrossRef] Siesing, L.; Lundström, F.; Frogner, K.; Cedell, T.; Andersson, M. Towards energy efficient heating in industrial processes—Three steps to achieve maximized efficiency in an induction heating system. Procedia Manuf. 2018, 25, 404–411. [CrossRef] Bendixen, F.B.; Eriksen, W.L.; Aasberg-petersen, K.; Frandsen, C.; Chorkendorff, I.; Mortensen, P.M. Industrial Hydrogen Production. Science 2019, 759, 756–759 Pacheco, J.; Valdivia, R.; Pacheco, M.; Clemente, A. H2 yielding rate comparison in a warm plasma reactor and thermal cracking furnace. Int. J. Hydrogen Energy 2020, 45, 31243–31254. [CrossRef] Chen, F. Introduction to Plasma Physics; Springer Science & Business Media: New York, NY, USA, 2012. Sikarwar, V.S.; Hrabovský, M.; Van Oost, G.; Pohoˇrelý, M.; Jeremiáš, M. Progress in waste utilization via thermal plasma. Prog. Energy Combust. Sci. 2020, 81, 100873. [CrossRef] Robinson, J.; Kingman, S.; Snape, C.; Barranco, R.; Shang, H.; Bradley, M.; Bradshaw, S. Remediation of oil-contaminated drill cuttings using continuous microwave heating. Chem. Eng. J. 2009, 152, 458–463. [CrossRef] Hou, Y.; Qi, S.; You, H.; Huang, Z.; Niu, Q. The study on pyrolysis of oil-based drilling cuttings by microwave and electric heating. J. Environ. Manag. 2018, 228, 312–318. [CrossRef] Li, Z.; Khaled, U.; Al-Rashed, A.A.; Goodarzi, M.; Sarafraz, M.; Meer, R. Heat transfer evaluation of a micro heat exchanger cooling with spherical carbon-acetone nanofluid. Int. J. Heat Mass Transf. 2020, 149, 119124. [CrossRef] Safaei, A.; Nezhad, A.H.; Rashidi, A. High temperature nanofluids based on therminol 66 for improving the heat exchangers power in gas refineries. Appl. Therm. Eng. 2020, 170, 114991. [CrossRef] Shakiba, A.; Vahedi, K. Numerical analysis of magnetic field effects on hydro-thermal behavior of a magnetic nanofluid in a double pipe heat exchanger. J. Magn. Magn. Mater. 2016, 402, 131–142. [CrossRef] Creswell, J.W.; Creswell, J.D. Research Design,Qualitative,Quantitative,and Mixed Methods Approaches, 5th ed.; SAGE: Newcastle upon Tyne, UK, 2018. Sugiyama, M. Climate change mitigation and electrification. Energy Policy 2012, 44, 464–468. [CrossRef] Kafandaris, S.; Manne, A.S.; Richels, R.G. Buying Greenhouse Insurance: The Economic Costs of CO2 Emission Limits; MIT Press: Cambridge, MA, USA, 1992. Lechtenböhmer, S.; Nilsson, L.J.; Åhman, M.; Schneider, C. Decarbonising the energy intensive basic materials industry through electrification—Implications for future EU electricity demand. Energy 2016, 115, 1623–1631. [CrossRef] Timmerberg, S.; Kaltschmitt, M.; Finkbeiner, M. Hydrogen and hydrogen-derived fuels through methane decomposition of natural gas—GHG emissions and costs. Energy Convers. Manag. X 2020, 7, 100043. [CrossRef] Götz, M.; Lefebvre, J.; Mörs, F.; McDaniel Koch, A.; Graf, F.; Bajohr, S.; Reimert, R.; Kolb, T. Renewable Power-to-Gas: A technological and economic review. Renew. Energy 2016, 85, 1371–1390. [CrossRef] Leonelli, C.; Mason, T.J. Microwave and ultrasonic processing: Now a realistic option for industry. Chem. Eng. Process.—Process. Intensif. 2010, 49, 885–900. [CrossRef] U.S Department of Energy. Innovating Clean Energy Technologies in Advanced Manufacturing; U.S Department of Energy: Washington, DC, USA, 2015 Liang, C.-H.; Zhang, X.-S.; Li, X.-W.; Zhu, X. Study on the performance of a solar assisted air source heat pump system for building heating. Energy Build. 2011, 43, 2188–2196. [CrossRef] IEA Launches Industrial Heat Pump Project. 2010. Available online: http://www.ammonia21.com/news/view/1870 (accessed on 5 July 2023). Zhang, J.; Zhang, H.-H.; He, Y.-L.; Tao, W.-Q. A comprehensive review on advances and applications of industrial heat pumps based on the practices in China. Appl. Energy 2016, 178, 800–825. [CrossRef] Wu, X.; Xing, Z.; He, Z.; Wang, X.; Chen, W. Performance evaluation of a capacity-regulated high temperature heat pump for waste heat recovery in dyeing industry. Appl. Therm. Eng. 2016, 93, 1193–1201. [CrossRef] Xie, Y.; Song, L.; Liu, C. Analysis of a solar assisted heat pump dryer with a storage tank. In Proceedings of the 2006 ASME International of Solar Energy Conference, Denver, CO, USA, 8–13 July 2006. Rubin, I. Materiales Plásticos,Propiedades y Aplicaciones. Mexico. 2004. Available online: https://buscaenbuja.ujaen.es/discove ry/fulldisplay?docid=alma991003081879704994&context=L&vid=34CBUA_UJA:VU1&lang=es&search_scope=CATALOGO& adaptor=Local%20Search%20Engine&tab=Jaen&offset=0 (accessed on 5 July 2023). Mohai, I.; Szépvölgyi, J. Treatment of particulate metallurgical wastes in thermal plasmas. Chem. Eng. Process.—Process. Intensif. 2005, 44, 225–229. [CrossRef] Tzeng, C.-C.; Kuo, Y.-Y.; Huang, T.-F.; Lin, D.-L.; Yu, Y.-J. Treatment of radioactive wastes by plasma incineration and vitrification for final disposal. J. Hazard. Mater. 1998, 58, 207–220. [CrossRef] Boulos, M.; Fauchais, P.; Pfender, E. Thermal Plasmas: Fundamentals and Applications; Springer Science & Business Media: New York, NY, USA, 2013. Aminian, J.; Arshad, A.K. Performance analysis of syngas production in a water thermal plasma reactor. Int. J. Hydrogen Energy 2020, 45, 30017–30028. [CrossRef] Tamošiunas, A.; Grigaitien ¯ e, V.; Valatkeviˇcius, P.; Valinˇcius, V. Syngas production from hydrocarbon-containing gas in ambient of ˙ water vapor plasma. Catal. Today 2012, 196, 81–85. [CrossRef] Cai, X.; Wei, X.; Wu, J.; Ding, J.; Du, C. Plasma pyrolysis and gasification of carambola leaves using non-thermal arc plasma. Waste Dispos. Sustain. Energy 2020, 2, 193–207. [CrossRef] Shie, J.-L.; Chen, L.-X.; Lin, K.-L.; Chang, C.-Y. Plasmatron gasification of biomass lignocellulosic waste materials derived from municipal solid waste. Energy 2014, 66, 82–89. [CrossRef] Rong, F.; Victor, D.G. Coal liquefaction policy in China: Explaining the policy reversal since 2006. Energy Policy 2011, 39, 8175–8184. [CrossRef] Andersen, J.; Christensen, J.; Østberg, M.; Bogaerts, A.; Jensen, A. Plasma-catalytic dry reforming of methane: Screening of catalytic materials in a coaxial packed-bed DBD reactor. Chem. Eng. J. 2020, 397, 125519. [CrossRef] Jamróz, P.; Kordylewski, W.; Wnukowski, M. Microwave plasma application in decomposition and steam reforming of model tar compounds. Fuel Process. Technol. 2018, 169, 1–14. [CrossRef] Pozar, D. Microwave Engineering; John Wiley & Sons: Hoboken, NJ, USA, 1998 Metaxas, A. Foundations of Electroheat: A Unified Approach; John Wiley & Sons: Hoboken, NJ, USA, 1996. Hong, Y.C.; Lee, S.J.; Shin, D.H.; Kim, Y.J.; Lee, B.J.; Cho, S.Y.; Chang, H.S. Syngas production from gasification of brown coal in a microwave torch plasma. Energy 2012, 47, 36–40. [CrossRef] Arshad, R.N.; Abdul-Malek, Z.; Munir, A.; Buntat, Z.; Ahmad, M.H.; Jusoh, Y.M.; Bekhit, A.E.-D.; Roobab, U.; Manzoor, M.F.; Aadil, R.M. Electrical systems for pulsed electric field applications in the food industry: An engineering perspective. Trends Food Sci. Technol. 2020, 104, 1–13. [CrossRef] Shahriari, A.; Birbarah, P.; Oh, J.; Miljkovic, N.; Bahadur, V. Electric Field–Based Control and Enhancement of Boiling and Condensation. Nanoscale Microscale Thermophys. Eng. 2016, 21, 102–121. [CrossRef] Di Marco, P. Influence of force fields and flow patterns on boiling heat transfer performance: A review. J. Heat Transf. 2012, 134, 030801. [CrossRef] Zonouzi, S.A.; Aminfar, H.; Mohammadpourfard, M. A review on effects of magnetic fields and electric fields on boiling heat transfer and CHF. Appl. Therm. Eng. 2019, 151, 11–25. [CrossRef] Takise, K.; Sato, A.; Muraguchi, K.; Ogo, S.; Sekine, Y. Steam reforming of aromatic hydrocarbon at low temperature in electric field. Appl. Catal. A: Gen. 2019, 573, 56–63. [CrossRef] Kucherov, A.V.; Finashina, E.D.; Kustov, L.M.; Simanzhenkov, V. Electric heating of the Mo–V–Fe–Nb–O catalyst bed in oxidative dehydrogenation of ethane. Mendeleev Commun. 2020, 30, 657–659. [CrossRef] Yongphet, P.; Wang, J.; Kiatsiriroat, T.; Wang, D.; Deethayat, T.; Quaye, E.K.; Zhang, W.; Yang, S. Enhancement of biodiesel production from soybean oil by electric field and its chemical kinetics. Chem. Eng. Process.—Process. Intensif. 2020, 153, 107997. [CrossRef] Choi, S.U.; Siginer, D.; Wang, H. Enhancing Thermal Conductivity of Fluids with Nanoparticles Developments and Applications of Non-Newtonian Flows; ASME: New York, NY, USA, 1995 Quan, X.; Gao, M.; Cheng, P.; Li, J. An experimental investigation of pool boiling heat transfer on smooth/rib surfaces under an electric field. Int. J. Heat Mass Transf. 2015, 85, 595–608. [CrossRef] Gavahian, M.; Tiwari, B.K. Moderate electric fields and ohmic heating as promising fermentation tools. Innov. Food Sci. Emerg. Technol. 2020, 64, 102422. [CrossRef] Dou, L.; Fu, M.; Gao, Y.; Wang, L.; Yan, C.; Ma, T.; Zhang, Q.; Li, X. Efficient sulfur resistance of Fe, La and Ce doped hierarchically structured catalysts for low-temperature methanation integrated with electric internal heating. Fuel 2021, 283, 118984. [CrossRef] Primo, A.; He, J.; Jurca, B.; Cojocaru, B.; Bucur, C.; Parvulescu, V.I.; Garcia, H. CO2 methanation catalyzed by oriented MoS2 nanoplatelets supported on few layers graphene. Appl. Catal. B Environ. 2019, 245, 351–359. [CrossRef] Wang, Y.; Liao, B.; Qiu, L.; Wang, D.; Xue, Q. Numerical simulation of enhancing shale gas recovery using electrical resistance heating method. Int. J. Heat Mass Transf. 2019, 128, 1218–1228. [CrossRef] Wismann, S.T.; Engbæk, J.S.; Vendelbo, S.B.; Bendixen, F.B.; Eriksen, W.L.; Aasberg-Petersen, K.; Frandsen, C.; Chorkendorff, I.B.; Mortensen, P.M. Electrified methane reforming: A compact approach to greener industrial hydrogen production Science. Science 2019, 364, 756–759. [CrossRef] [PubMed] Qin, P.; Xu, H.; Liu, M.; Xiao, C.; Forrest, K.E.; Samuelsen, S.; Tarroja, B. Assessing concurrent effects of climate change on hydropower supply, electricity demand, and greenhouse gas emissions in the Upper Yangtze River Basin of China. Appl. Energy 2020, 279, 115694. [CrossRef] Grasso, M. Towards a broader climate ethics: Confronting the oil industry with morally relevant facts. Energy Res. Soc. Sci. 2020, 62, 101383. [CrossRef] Navas-Anguita, Z.; García-Gusano, D.; Dufour, J.; Iribarren, D. Prospective techno-economic and environmental assessment of a national hydrogen production mix for road transport. Appl. Energy 2020, 259, 114121. [CrossRef] Goeppert, A.; Olah, G.A.; Prakash, G.K.S. Chapter 3.26—Toward a Sustainable Carbon Cycle: The Methanol Economy. In Green Chemistry; Török, B., Dransfield, T.B.T.-G.C., Eds.; Elsevier: Amsterdam, The Netherlands, 2018; pp. 919–962 Wolf, S.; Blesl, M. Model-based quantification of the contribution of industrial heat pumps to the European climate change mitigation strategy. ECEEE Ind. Summer Study Proc. 2016, 477–488. Available online: https://www.eceee.org/library/conference _proceedings/eceee_Industrial_Summer_Study/2016/4-technology-products-and-systems/model-based-quantification-of-t he-contribution-of-industrial-heat-pumps-to-the-european-climate-change-mitigation-strategy/ (accessed on 5 July 2023). |
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Atribución 4.0 Internacional (CC BY 4.0)© 2023 by the authors.https://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2Muñoz Maldonado, YecidCorrea Quintana, EdgarOspino Castro, AdalbertoOspino C., Adalbertovirtual::910-12024-10-30T15:49:54Z2024-10-30T15:49:54Z2023-09-29Muñoz-Maldonado, Y.; Correa-Quintana, E.; Ospino-Castro, A. Electrification of Industrial Processes as an Alternative to Replace Conventional Thermal Power Sources. Energies 2023, 16, 6894. https://doi.org/10.3390/en16196894.https://hdl.handle.net/11323/1360810.3390/en161968941996-1073Corporación Universidad de la CostaREDICUC - Repositorio CUChttps://repositorio.cuc.edu.co/The electrification of industrial processes offers sustainable opportunities for reducing carbon footprints and enhancing energy efficiency in the chemical industry. This paper presents an overview of recent research developments in incorporating electrical energy as a replacement for conventional thermal sources like gas and coal in industrial sectors. A literature review was conducted, identifying 70 relevant articles published until September 2020. The topics cover applications for industrial hydrogen generation processes and others, heat pumps, heat pumps, vapor re-compression systems, electric and magnetic fields as heat sources, nanoparticles for improved heat exchange, and ionized gases (plasma) in heating systems. While the application of industrial electrification shows promise globally, its sustainability depends on the efficiency and cost of electrical energy production and transportation at the regional and national levels. Among the various technologies, heat pumps integrated with vapor re-compression systems (VCR) for chemical processes, particularly in industrial distillation product separation columns, appear to be the most viable and widely applicable for waste heat recovery in the near future. Other technologies like electrochemical, plasma, microwave, magnetic, and electric field heating are still in the early stages of development or are limited to specific pilot or laboratory-scale processes.20 páginasapplication/pdfengMultidisciplinary Digital Publishing Institute (MDPI)Switzerlandhttps://www.mdpi.com/1996-1073/16/19/6894Electrification of industrial processes as an alternative to replace conventional thermal power sources.Artículo de revistahttp://purl.org/coar/resource_type/c_2df8fbb1Textinfo:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/version/c_970fb48d4fbd8a85EnergiesRissman, J.; Bataille, C.; Masanet, E.; Aden, N.; Morrow, W.R.; Zhou, N.; Elliott, N.; Dell, R.; Heeren, N.; Huckestein, B.; et al. Technologies and policies to decarbonize global industry: Review and assessment of mitigation drivers through 2070. Appl. Energy 2020, 266, 114848. [CrossRef]Kleidon, A. Energy Balance. In Encyclopedia of Ecology, 2nd ed.; Elsevier B.V.: Amsterdam, The Netherlands, 2019; pp. 50–63. [CrossRef]Energy Transition Commission. Reaching Net-Zero Carbon Emissions from Harder-to-Abate Sectors by Mid-Century; Energy Transition Commission: London, UK, 2018.U.S. DOE; EERE Advanced Manufacturing Office. Manufacturing Energy and Carbon Footprints (2014 MECS). 2018. Available online: https://www.energy.gov/eere/amo/%0Amanufacturing-energy-and-carbon-footprints-2014-mecs (accessed on 18 October 2020)U.S. Department. of Energy. Quadrennial Technology Review: Process Heating Technology Assessment; U.S. Department of Energy: Washington, DC, USA, 2019. Available online: https://energy.gov/sites/prod/files/2016/06/f32/%0AQTR2015-6I-Process-Hea ting.pdf (accessed on 10 August 2019).Van Kranenburg, K.; Schols, E.; Gelevert, H.; De Kler, R.; Van Delft, Y.; Weeda, M. Empowering the Chemical Industry. Opportunities for Electrification; Tno-Ecn. 2016, p. 32. Available online: https://www.tno.nl/media/7514/voltachem_electrificat ion_whitepaper_2016.pdf (accessed on 5 July 2023)Gerres, T.; Ávila, J.P.C.; Llamas, P.L.; Román, T.G.S. A review of cross-sector decarbonisation potentials in the European energy intensive industry. J. Clean. Prod. 2019, 210, 585–601. [CrossRef]Rajabloo, T.; De Ceuninck, W.; Van Wortswinkel, L.; Rezakazemi, M.; Aminabhavi, T. Environmental management of industrial decarbonization with focus on chemical sectors: A review. J. Environ. Manag. 2022, 302, 114055. [CrossRef]Wei, M.; McMillan, C.A.; Can, S.D.L.R.D. Electrification of industry: Potential, challenges and outlook. Curr. Sustain. Energy Rep. 2019, 6, 140–148. [CrossRef]Van Geem, K.M.; Weckhuysen, B.M. Toward an e-chemistree: Materials for electrification of the chemical industry. MRS Bull. 2021, 46, 1187–1196. [CrossRef]Hassan, A.; Patel, M.K.; Parra, D. An assessment of the impacts of renewable and conventional electricity supply on the cost and value of power-to-gas. Int. J. Hydrogen Energy 2019, 44, 9577–9593. [CrossRef]Arpagaus, C.; Bless, F.; Uhlmann, M.; Schiffmann, J.; Bertsch, S.S. High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials. Energy 2018, 152, 985–1010. [CrossRef]van de Bor, D.; Ferreira, C.I. Quick selection of industrial heat pump types including the impact of thermodynamic losses. Energy 2013, 53, 312–322. [CrossRef]Waite, M.; Modi, V. Electricity Load Implications of Space Heating Decarbonization Pathways. Joule 2020, 4, 376–394. [CrossRef]Nellissen, P.; Wolf, S. Heat Pumps in Non-Domestic Applications in Europe: Potential for an Energy Revolution. 8th EHPA Eur. Heat Pump Forum, 28 May 2015, Brussels, no. 2015. 2015, pp. 1–17. Available online: https://docplayer.net/41987374-Heat-pu mps-in-non-domestic-applications-in-europe-potential-for-an-energy-revolution.html (accessed on 5 July 2023)Kosmadakis, G. Estimating the potential of industrial (high-temperature) heat pumps for exploiting waste heat in EU industries. Appl. Therm. Eng. 2019, 156, 287–298. [CrossRef]Motasemi, F.; Afzal, M.T. A review on the microwave-assisted pyrolysis technique. Renew. Sustain. Energy Rev. 2013, 28, 317–330. [CrossRef]Wang, Z.; Gao, D.; Diao, B.; Tan, L.; Zhang, W.; Liu, K. Comparative performance of electric heater vs. RF heating for heavy oil recovery. Appl. Therm. Eng. 2019, 160, 114105. [CrossRef]Siesing, L.; Lundström, F.; Frogner, K.; Cedell, T.; Andersson, M. Towards energy efficient heating in industrial processes—Three steps to achieve maximized efficiency in an induction heating system. Procedia Manuf. 2018, 25, 404–411. [CrossRef]Bendixen, F.B.; Eriksen, W.L.; Aasberg-petersen, K.; Frandsen, C.; Chorkendorff, I.; Mortensen, P.M. Industrial Hydrogen Production. Science 2019, 759, 756–759Pacheco, J.; Valdivia, R.; Pacheco, M.; Clemente, A. H2 yielding rate comparison in a warm plasma reactor and thermal cracking furnace. Int. J. Hydrogen Energy 2020, 45, 31243–31254. [CrossRef]Chen, F. Introduction to Plasma Physics; Springer Science & Business Media: New York, NY, USA, 2012.Sikarwar, V.S.; Hrabovský, M.; Van Oost, G.; Pohoˇrelý, M.; Jeremiáš, M. Progress in waste utilization via thermal plasma. Prog. Energy Combust. Sci. 2020, 81, 100873. [CrossRef]Robinson, J.; Kingman, S.; Snape, C.; Barranco, R.; Shang, H.; Bradley, M.; Bradshaw, S. Remediation of oil-contaminated drill cuttings using continuous microwave heating. Chem. Eng. J. 2009, 152, 458–463. [CrossRef]Hou, Y.; Qi, S.; You, H.; Huang, Z.; Niu, Q. The study on pyrolysis of oil-based drilling cuttings by microwave and electric heating. J. Environ. Manag. 2018, 228, 312–318. [CrossRef]Li, Z.; Khaled, U.; Al-Rashed, A.A.; Goodarzi, M.; Sarafraz, M.; Meer, R. Heat transfer evaluation of a micro heat exchanger cooling with spherical carbon-acetone nanofluid. Int. J. Heat Mass Transf. 2020, 149, 119124. [CrossRef]Safaei, A.; Nezhad, A.H.; Rashidi, A. High temperature nanofluids based on therminol 66 for improving the heat exchangers power in gas refineries. Appl. Therm. Eng. 2020, 170, 114991. [CrossRef]Shakiba, A.; Vahedi, K. Numerical analysis of magnetic field effects on hydro-thermal behavior of a magnetic nanofluid in a double pipe heat exchanger. J. Magn. Magn. Mater. 2016, 402, 131–142. [CrossRef]Creswell, J.W.; Creswell, J.D. Research Design,Qualitative,Quantitative,and Mixed Methods Approaches, 5th ed.; SAGE: Newcastle upon Tyne, UK, 2018.Sugiyama, M. Climate change mitigation and electrification. Energy Policy 2012, 44, 464–468. [CrossRef]Kafandaris, S.; Manne, A.S.; Richels, R.G. Buying Greenhouse Insurance: The Economic Costs of CO2 Emission Limits; MIT Press: Cambridge, MA, USA, 1992.Lechtenböhmer, S.; Nilsson, L.J.; Åhman, M.; Schneider, C. Decarbonising the energy intensive basic materials industry through electrification—Implications for future EU electricity demand. Energy 2016, 115, 1623–1631. [CrossRef]Timmerberg, S.; Kaltschmitt, M.; Finkbeiner, M. Hydrogen and hydrogen-derived fuels through methane decomposition of natural gas—GHG emissions and costs. Energy Convers. Manag. X 2020, 7, 100043. [CrossRef]Götz, M.; Lefebvre, J.; Mörs, F.; McDaniel Koch, A.; Graf, F.; Bajohr, S.; Reimert, R.; Kolb, T. Renewable Power-to-Gas: A technological and economic review. Renew. Energy 2016, 85, 1371–1390. [CrossRef]Leonelli, C.; Mason, T.J. Microwave and ultrasonic processing: Now a realistic option for industry. Chem. Eng. Process.—Process. Intensif. 2010, 49, 885–900. [CrossRef]U.S Department of Energy. Innovating Clean Energy Technologies in Advanced Manufacturing; U.S Department of Energy: Washington, DC, USA, 2015Liang, C.-H.; Zhang, X.-S.; Li, X.-W.; Zhu, X. Study on the performance of a solar assisted air source heat pump system for building heating. Energy Build. 2011, 43, 2188–2196. [CrossRef]IEA Launches Industrial Heat Pump Project. 2010. Available online: http://www.ammonia21.com/news/view/1870 (accessed on 5 July 2023).Zhang, J.; Zhang, H.-H.; He, Y.-L.; Tao, W.-Q. A comprehensive review on advances and applications of industrial heat pumps based on the practices in China. Appl. Energy 2016, 178, 800–825. [CrossRef]Wu, X.; Xing, Z.; He, Z.; Wang, X.; Chen, W. Performance evaluation of a capacity-regulated high temperature heat pump for waste heat recovery in dyeing industry. Appl. Therm. Eng. 2016, 93, 1193–1201. [CrossRef]Xie, Y.; Song, L.; Liu, C. Analysis of a solar assisted heat pump dryer with a storage tank. In Proceedings of the 2006 ASME International of Solar Energy Conference, Denver, CO, USA, 8–13 July 2006.Rubin, I. Materiales Plásticos,Propiedades y Aplicaciones. Mexico. 2004. Available online: https://buscaenbuja.ujaen.es/discove ry/fulldisplay?docid=alma991003081879704994&context=L&vid=34CBUA_UJA:VU1&lang=es&search_scope=CATALOGO& adaptor=Local%20Search%20Engine&tab=Jaen&offset=0 (accessed on 5 July 2023).Mohai, I.; Szépvölgyi, J. Treatment of particulate metallurgical wastes in thermal plasmas. Chem. Eng. Process.—Process. Intensif. 2005, 44, 225–229. [CrossRef]Tzeng, C.-C.; Kuo, Y.-Y.; Huang, T.-F.; Lin, D.-L.; Yu, Y.-J. Treatment of radioactive wastes by plasma incineration and vitrification for final disposal. J. Hazard. Mater. 1998, 58, 207–220. [CrossRef]Boulos, M.; Fauchais, P.; Pfender, E. Thermal Plasmas: Fundamentals and Applications; Springer Science & Business Media: New York, NY, USA, 2013.Aminian, J.; Arshad, A.K. Performance analysis of syngas production in a water thermal plasma reactor. Int. J. Hydrogen Energy 2020, 45, 30017–30028. [CrossRef]Tamošiunas, A.; Grigaitien ¯ e, V.; Valatkeviˇcius, P.; Valinˇcius, V. Syngas production from hydrocarbon-containing gas in ambient of ˙ water vapor plasma. Catal. Today 2012, 196, 81–85. [CrossRef]Cai, X.; Wei, X.; Wu, J.; Ding, J.; Du, C. Plasma pyrolysis and gasification of carambola leaves using non-thermal arc plasma. Waste Dispos. Sustain. Energy 2020, 2, 193–207. [CrossRef]Shie, J.-L.; Chen, L.-X.; Lin, K.-L.; Chang, C.-Y. Plasmatron gasification of biomass lignocellulosic waste materials derived from municipal solid waste. Energy 2014, 66, 82–89. [CrossRef]Rong, F.; Victor, D.G. Coal liquefaction policy in China: Explaining the policy reversal since 2006. Energy Policy 2011, 39, 8175–8184. [CrossRef]Andersen, J.; Christensen, J.; Østberg, M.; Bogaerts, A.; Jensen, A. Plasma-catalytic dry reforming of methane: Screening of catalytic materials in a coaxial packed-bed DBD reactor. Chem. Eng. J. 2020, 397, 125519. [CrossRef]Jamróz, P.; Kordylewski, W.; Wnukowski, M. Microwave plasma application in decomposition and steam reforming of model tar compounds. Fuel Process. Technol. 2018, 169, 1–14. [CrossRef]Pozar, D. Microwave Engineering; John Wiley & Sons: Hoboken, NJ, USA, 1998Metaxas, A. Foundations of Electroheat: A Unified Approach; John Wiley & Sons: Hoboken, NJ, USA, 1996.Hong, Y.C.; Lee, S.J.; Shin, D.H.; Kim, Y.J.; Lee, B.J.; Cho, S.Y.; Chang, H.S. Syngas production from gasification of brown coal in a microwave torch plasma. Energy 2012, 47, 36–40. [CrossRef]Arshad, R.N.; Abdul-Malek, Z.; Munir, A.; Buntat, Z.; Ahmad, M.H.; Jusoh, Y.M.; Bekhit, A.E.-D.; Roobab, U.; Manzoor, M.F.; Aadil, R.M. Electrical systems for pulsed electric field applications in the food industry: An engineering perspective. Trends Food Sci. Technol. 2020, 104, 1–13. [CrossRef]Shahriari, A.; Birbarah, P.; Oh, J.; Miljkovic, N.; Bahadur, V. Electric Field–Based Control and Enhancement of Boiling and Condensation. Nanoscale Microscale Thermophys. Eng. 2016, 21, 102–121. [CrossRef]Di Marco, P. Influence of force fields and flow patterns on boiling heat transfer performance: A review. J. Heat Transf. 2012, 134, 030801. [CrossRef]Zonouzi, S.A.; Aminfar, H.; Mohammadpourfard, M. A review on effects of magnetic fields and electric fields on boiling heat transfer and CHF. Appl. Therm. Eng. 2019, 151, 11–25. [CrossRef]Takise, K.; Sato, A.; Muraguchi, K.; Ogo, S.; Sekine, Y. Steam reforming of aromatic hydrocarbon at low temperature in electric field. Appl. Catal. A: Gen. 2019, 573, 56–63. [CrossRef]Kucherov, A.V.; Finashina, E.D.; Kustov, L.M.; Simanzhenkov, V. Electric heating of the Mo–V–Fe–Nb–O catalyst bed in oxidative dehydrogenation of ethane. Mendeleev Commun. 2020, 30, 657–659. [CrossRef]Yongphet, P.; Wang, J.; Kiatsiriroat, T.; Wang, D.; Deethayat, T.; Quaye, E.K.; Zhang, W.; Yang, S. Enhancement of biodiesel production from soybean oil by electric field and its chemical kinetics. Chem. Eng. Process.—Process. Intensif. 2020, 153, 107997. [CrossRef]Choi, S.U.; Siginer, D.; Wang, H. Enhancing Thermal Conductivity of Fluids with Nanoparticles Developments and Applications of Non-Newtonian Flows; ASME: New York, NY, USA, 1995Quan, X.; Gao, M.; Cheng, P.; Li, J. An experimental investigation of pool boiling heat transfer on smooth/rib surfaces under an electric field. Int. J. Heat Mass Transf. 2015, 85, 595–608. [CrossRef]Gavahian, M.; Tiwari, B.K. Moderate electric fields and ohmic heating as promising fermentation tools. Innov. Food Sci. Emerg. Technol. 2020, 64, 102422. [CrossRef]Dou, L.; Fu, M.; Gao, Y.; Wang, L.; Yan, C.; Ma, T.; Zhang, Q.; Li, X. Efficient sulfur resistance of Fe, La and Ce doped hierarchically structured catalysts for low-temperature methanation integrated with electric internal heating. Fuel 2021, 283, 118984. [CrossRef]Primo, A.; He, J.; Jurca, B.; Cojocaru, B.; Bucur, C.; Parvulescu, V.I.; Garcia, H. CO2 methanation catalyzed by oriented MoS2 nanoplatelets supported on few layers graphene. Appl. Catal. B Environ. 2019, 245, 351–359. [CrossRef]Wang, Y.; Liao, B.; Qiu, L.; Wang, D.; Xue, Q. Numerical simulation of enhancing shale gas recovery using electrical resistance heating method. Int. J. Heat Mass Transf. 2019, 128, 1218–1228. [CrossRef]Wismann, S.T.; Engbæk, J.S.; Vendelbo, S.B.; Bendixen, F.B.; Eriksen, W.L.; Aasberg-Petersen, K.; Frandsen, C.; Chorkendorff, I.B.; Mortensen, P.M. Electrified methane reforming: A compact approach to greener industrial hydrogen production Science. Science 2019, 364, 756–759. [CrossRef] [PubMed]Qin, P.; Xu, H.; Liu, M.; Xiao, C.; Forrest, K.E.; Samuelsen, S.; Tarroja, B. Assessing concurrent effects of climate change on hydropower supply, electricity demand, and greenhouse gas emissions in the Upper Yangtze River Basin of China. Appl. Energy 2020, 279, 115694. [CrossRef]Grasso, M. Towards a broader climate ethics: Confronting the oil industry with morally relevant facts. Energy Res. Soc. Sci. 2020, 62, 101383. [CrossRef]Navas-Anguita, Z.; García-Gusano, D.; Dufour, J.; Iribarren, D. Prospective techno-economic and environmental assessment of a national hydrogen production mix for road transport. Appl. Energy 2020, 259, 114121. [CrossRef]Goeppert, A.; Olah, G.A.; Prakash, G.K.S. Chapter 3.26—Toward a Sustainable Carbon Cycle: The Methanol Economy. In Green Chemistry; Török, B., Dransfield, T.B.T.-G.C., Eds.; Elsevier: Amsterdam, The Netherlands, 2018; pp. 919–962Wolf, S.; Blesl, M. Model-based quantification of the contribution of industrial heat pumps to the European climate change mitigation strategy. ECEEE Ind. Summer Study Proc. 2016, 477–488. Available online: https://www.eceee.org/library/conference _proceedings/eceee_Industrial_Summer_Study/2016/4-technology-products-and-systems/model-based-quantification-of-t he-contribution-of-industrial-heat-pumps-to-the-european-climate-change-mitigation-strategy/ (accessed on 5 July 2023).201689416Chemical process electrificationElectric–magnetic fieldsHeat pumpsMicrowavesPlasmaPublicationaf89e44d-2c08-45ae-b01c-cd941b86fa8avirtual::910-1af89e44d-2c08-45ae-b01c-cd941b86fa8avirtual::910-1https://scholar.google.es/citations?user=ODmDjToAAAAJ&hl=esvirtual::910-10000-0003-1466-0424virtual::910-1ORIGINALElectrification of industrial processes as an alternative to replace conventional thermal power sources..pdfElectrification of industrial processes as an alternative to replace conventional thermal power 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ara ejercer estos derechos sobre la Obra tal y como se indica a continuación:</p>
    <ol type="a">
      <li>Reproducir la Obra, incorporar la Obra en una o más Obras Colectivas, y reproducir la Obra incorporada en las Obras Colectivas.</li>
      <li>Distribuir copias o fonogramas de las Obras, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública, incluyéndolas como incorporadas en Obras Colectivas, según corresponda.</li>
      <li>Distribuir copias de las Obras Derivadas que se generen, exhibirlas públicamente, ejecutarlas públicamente y/o ponerlas a disposición pública.</li>
    </ol>
    <p>Los derechos mencionados anteriormente pueden ser ejercidos en todos los medios y formatos, actualmente conocidos o que se inventen en el futuro. Los derechos antes mencionados incluyen el derecho a realizar dichas modificaciones en la medida que sean técnicamente necesarias para ejercer los derechos en otro medio o formatos, pero de otra manera usted no está autorizado para realizar obras derivadas. Todos los derechos no otorgados expresamente por el Licenciante quedan por este medio reservados, incluyendo pero sin limitarse a aquellos que se mencionan en las secciones 4(d) y 4(e).</p>
  </li>
  <br/>
  <li>
    Restricciones.
    <p>La licencia otorgada en la anterior Sección 3 está expresamente sujeta y limitada por las siguientes restricciones:</p>
    <ol type="a">
      <li>Usted puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra sólo bajo las condiciones de esta Licencia, y Usted debe incluir una copia de esta licencia o del Identificador Universal de Recursos de la misma con cada copia de la Obra que distribuya, exhiba públicamente, ejecute públicamente o ponga a disposición pública. No es posible ofrecer o imponer ninguna condición sobre la Obra que altere o limite las condiciones de esta Licencia o el ejercicio de los derechos de los destinatarios otorgados en este documento. No es posible sublicenciar la Obra. Usted debe mantener intactos todos los avisos que hagan referencia a esta Licencia y a la cláusula de limitación de garantías. Usted no puede distribuir, exhibir públicamente, ejecutar públicamente, o poner a disposición pública la Obra con alguna medida tecnológica que controle el acceso o la utilización de ella de una forma que sea inconsistente con las condiciones de esta Licencia. Lo anterior se aplica a la Obra incorporada a una Obra Colectiva, pero esto no exige que la Obra Colectiva aparte de la obra misma quede sujeta a las condiciones de esta Licencia. Si Usted crea una Obra Colectiva, previo aviso de cualquier Licenciante debe, en la medida de lo posible, eliminar de la Obra Colectiva cualquier referencia a dicho Licenciante o al Autor Original, según lo solicitado por el Licenciante y conforme lo exige la cláusula 4(c).</li>
      <li>Usted no puede ejercer ninguno de los derechos que le han sido otorgados en la Sección 3 precedente de modo que estén principalmente destinados o directamente dirigidos a conseguir un provecho comercial o una compensación monetaria privada. El intercambio de la Obra por otras obras protegidas por derechos de autor, ya sea a través de un sistema para compartir archivos digitales (digital file-sharing) o de cualquier otra manera no será considerado como estar destinado principalmente o dirigido directamente a conseguir un provecho comercial o una compensación monetaria privada, siempre que no se realice un pago mediante una compensación monetaria en relación con el intercambio de obras protegidas por el derecho de autor.</li>
      <li>Si usted distribuye, exhibe públicamente, ejecuta públicamente o ejecuta públicamente en forma digital la Obra o cualquier Obra Derivada u Obra Colectiva, Usted debe mantener intacta toda la información de derecho de autor de la Obra y proporcionar, de forma razonable según el medio o manera que Usted esté utilizando: (i) el nombre del Autor Original si está provisto (o seudónimo, si fuere aplicable), y/o (ii) el nombre de la parte o las partes que el Autor Original y/o el Licenciante hubieren designado para la atribución (v.g., un instituto patrocinador, editorial, publicación) en la información de los derechos de autor del Licenciante, términos de servicios o de otras formas razonables; el título de la Obra si está provisto; en la medida de lo razonablemente factible y, si está provisto, el Identificador Uniforme de Recursos (Uniform Resource Identifier) que el Licenciante especifica para ser asociado con la Obra, salvo que tal URI no se refiera a la nota sobre los derechos de autor o a la información sobre el licenciamiento de la Obra; y en el caso de una Obra Derivada, atribuir el crédito identificando el uso de la Obra en la Obra Derivada (v.g., "Traducción Francesa de la Obra del Autor Original," o "Guión Cinematográfico basado en la Obra original del Autor Original"). Tal crédito puede ser implementado de cualquier forma razonable; en el caso, sin embargo, de Obras Derivadas u Obras Colectivas, tal crédito aparecerá, como mínimo, donde aparece el crédito de cualquier otro autor comparable y de una manera, al menos, tan destacada como el crédito de otro autor comparable.</li>
      <li>
        Para evitar toda confusión, el Licenciante aclara que, cuando la obra es una composición musical:
        <ol type="i">
          <li>Regalías por interpretación y ejecución bajo licencias generales. El Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública o la ejecución pública digital de la obra y de recolectar, sea individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, SAYCO), las regalías por la ejecución pública o por la ejecución pública digital de la obra (por ejemplo Webcast) licenciada bajo licencias generales, si la interpretación o ejecución de la obra está primordialmente orientada por o dirigida a la obtención de una ventaja comercial o una compensación monetaria privada.</li>
          <li>Regalías por Fonogramas. El Licenciante se reserva el derecho exclusivo de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, los consagrados por la SAYCO), una agencia de derechos musicales o algún agente designado, las regalías por cualquier fonograma que Usted cree a partir de la obra (“versión cover”) y distribuya, en los términos del régimen de derechos de autor, si la creación o distribución de esa versión cover está primordialmente destinada o dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
        </ol>
      </li>
      <li>Gestión de Derechos de Autor sobre Interpretaciones y Ejecuciones Digitales (WebCasting). Para evitar toda confusión, el Licenciante aclara que, cuando la obra sea un fonograma, el Licenciante se reserva el derecho exclusivo de autorizar la ejecución pública digital de la obra (por ejemplo, webcast) y de recolectar, individualmente o a través de una sociedad de gestión colectiva de derechos de autor y derechos conexos (por ejemplo, ACINPRO), las regalías por la ejecución pública digital de la obra (por ejemplo, webcast), sujeta a las disposiciones aplicables del régimen de Derecho de Autor, si esta ejecución pública digital está primordialmente dirigida a obtener una ventaja comercial o una compensación monetaria privada.</li>
    </ol>
  </li>
  <br/>
  <li>
    Representaciones, Garantías y Limitaciones de Responsabilidad.
    <p>A MENOS QUE LAS PARTES LO ACORDARAN DE OTRA FORMA POR ESCRITO, EL LICENCIANTE OFRECE LA OBRA (EN EL ESTADO EN EL QUE SE ENCUENTRA) “TAL CUAL”, SIN BRINDAR GARANTÍAS DE CLASE ALGUNA RESPECTO DE LA OBRA, YA SEA EXPRESA, IMPLÍCITA, LEGAL O CUALQUIERA OTRA, INCLUYENDO, SIN LIMITARSE A ELLAS, GARANTÍAS DE TITULARIDAD, COMERCIABILIDAD, ADAPTABILIDAD O ADECUACIÓN A PROPÓSITO DETERMINADO, AUSENCIA DE INFRACCIÓN, DE AUSENCIA DE DEFECTOS LATENTES O DE OTRO TIPO, O LA PRESENCIA O AUSENCIA DE ERRORES, SEAN O NO DESCUBRIBLES (PUEDAN O NO SER ESTOS DESCUBIERTOS). ALGUNAS JURISDICCIONES NO PERMITEN LA EXCLUSIÓN DE GARANTÍAS IMPLÍCITAS, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Limitación de responsabilidad.
    <p>A MENOS QUE LO EXIJA EXPRESAMENTE LA LEY APLICABLE, EL LICENCIANTE NO SERÁ RESPONSABLE ANTE USTED POR DAÑO ALGUNO, SEA POR RESPONSABILIDAD EXTRACONTRACTUAL, PRECONTRACTUAL O CONTRACTUAL, OBJETIVA O SUBJETIVA, SE TRATE DE DAÑOS MORALES O PATRIMONIALES, DIRECTOS O INDIRECTOS, PREVISTOS O IMPREVISTOS PRODUCIDOS POR EL USO DE ESTA LICENCIA O DE LA OBRA, AUN CUANDO EL LICENCIANTE HAYA SIDO ADVERTIDO DE LA POSIBILIDAD DE DICHOS DAÑOS. ALGUNAS LEYES NO PERMITEN LA EXCLUSIÓN DE CIERTA RESPONSABILIDAD, EN CUYO CASO ESTA EXCLUSIÓN PUEDE NO APLICARSE A USTED.</p>
  </li>
  <br/>
  <li>
    Término.
    <ol type="a">
      <li>Esta Licencia y los derechos otorgados en virtud de ella terminarán automáticamente si Usted infringe alguna condición establecida en ella. Sin embargo, los individuos o entidades que han recibido Obras Derivadas o Colectivas de Usted de conformidad con esta Licencia, no verán terminadas sus licencias, siempre que estos individuos o entidades sigan cumpliendo íntegramente las condiciones de estas licencias. Las Secciones 1, 2, 5, 6, 7, y 8 subsistirán a cualquier terminación de esta Licencia.</li>
      <li>Sujeta a las condiciones y términos anteriores, la licencia otorgada aquí es perpetua (durante el período de vigencia de los derechos de autor de la obra). No obstante lo anterior, el Licenciante se reserva el derecho a publicar y/o estrenar la Obra bajo condiciones de licencia diferentes o a dejar de distribuirla en los términos de esta Licencia en cualquier momento; en el entendido, sin embargo, que esa elección no servirá para revocar esta licencia o que deba ser otorgada , bajo los términos de esta licencia), y esta licencia continuará en pleno vigor y efecto a menos que sea terminada como se expresa atrás. La Licencia revocada continuará siendo plenamente vigente y efectiva si no se le da término en las condiciones indicadas anteriormente.</li>
    </ol>
  </li>
  <br/>
  <li>
    Varios.
    <ol type="a">
      <li>Cada vez que Usted distribuya o ponga a disposición pública la Obra o una Obra Colectiva, el Licenciante ofrecerá al destinatario una licencia en los mismos términos y condiciones que la licencia otorgada a Usted bajo esta Licencia.</li>
      <li>Si alguna disposición de esta Licencia resulta invalidada o no exigible, según la legislación vigente, esto no afectará ni la validez ni la aplicabilidad del resto de condiciones de esta Licencia y, sin acción adicional por parte de los sujetos de este acuerdo, aquélla se entenderá reformada lo mínimo necesario para hacer que dicha disposición sea válida y exigible.</li>
      <li>Ningún término o disposición de esta Licencia se estimará renunciada y ninguna violación de ella será consentida a menos que esa renuncia o consentimiento sea otorgado por escrito y firmado por la parte que renuncie o consienta.</li>
      <li>Esta Licencia refleja el acuerdo pleno entre las partes respecto a la Obra aquí licenciada. No hay arreglos, acuerdos o declaraciones respecto a la Obra que no estén especificados en este documento. El Licenciante no se verá limitado por ninguna disposición adicional que pueda surgir en alguna comunicación emanada de Usted. Esta Licencia no puede ser modificada sin el consentimiento mutuo por escrito del Licenciante y Usted.</li>
    </ol>
  </li>
  <br/>
</ol>
 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