Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures

Objetivo: aplicar los enfoques de los modelos de Solubilidad Extendido de Hildebrand (EHSA) y Yalkowsky Roseman (YR) para evaluar la solubilidad de sulfadiazina y sulfametazina en mezclas de etilenglicol + agua. Metodología: para los cálculos se utilizaron las solubilidades experimentales en equilib...

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Autores:: Delgado, Daniel Ricardo
Vargas-Santana, Martha Sofía
Cruz-González, Ana Marías
Cerquera, Nestor
Escobar Rodriguez, Alana Sofía
Cardenas, Rossember E.
Ortiz, Claudia Patricia
Calderón-Losada, Omar
Delgado, Daniel Ricardo

Tipo de recurso:: Article of journal

Fecha de publicación:: 2022

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

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network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
dc.title.none.fl_str_mv	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
title	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
spellingShingle	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures Sulfadiazine sulfamethazine extended Hildebrand model 2 o mas bases de datos Sulfadiazina sulfametazina Extended Hildebrand model
title_short	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
title_full	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
title_fullStr	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
title_full_unstemmed	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
title_sort	Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures
dc.creator.fl_str_mv	Delgado, Daniel Ricardo Vargas-Santana, Martha Sofía Cruz-González, Ana Marías Cerquera, Nestor Escobar Rodriguez, Alana Sofía Cardenas, Rossember E. Ortiz, Claudia Patricia Calderón-Losada, Omar Delgado, Daniel Ricardo
dc.contributor.advisor.none.fl_str_mv	Delgado, Daniel
dc.contributor.author.none.fl_str_mv	Delgado, Daniel Ricardo Vargas-Santana, Martha Sofía Cruz-González, Ana Marías Cerquera, Nestor Escobar Rodriguez, Alana Sofía Cardenas, Rossember E. Ortiz, Claudia Patricia Calderón-Losada, Omar Delgado, Daniel Ricardo
dc.subject.none.fl_str_mv	Sulfadiazine sulfamethazine extended Hildebrand model
topic	Sulfadiazine sulfamethazine extended Hildebrand model 2 o mas bases de datos Sulfadiazina sulfametazina Extended Hildebrand model
dc.subject.classification.none.fl_str_mv	2 o mas bases de datos
dc.subject.other.none.fl_str_mv	Sulfadiazina sulfametazina Extended Hildebrand model
description	Objetivo: aplicar los enfoques de los modelos de Solubilidad Extendido de Hildebrand (EHSA) y Yalkowsky Roseman (YR) para evaluar la solubilidad de sulfadiazina y sulfametazina en mezclas de etilenglicol + agua. Metodología: para los cálculos se utilizaron las solubilidades experimentales en equilibrio reportadas y algunas propiedades de fusión de estos fármacos. Resultados: en particular, se encontró un buen carácter predictivo de EHSA (con desviaciones medias inferiores al 3,0%) utilizando polinomios regulares en orden dos correlacionando el parámetro de interacción W con el parámetro de solubilidad de Hildebrand de mezclas de disolventes sin fármaco; sin embargo, los resultados obtenidos del modelo YR muestran desviaciones relativamente altas superiores al 50%.
publishDate	2022
dc.date.issued.none.fl_str_mv	2022-02-04
dc.date.accessioned.none.fl_str_mv	2023-03-16T15:19:11Z
dc.date.available.none.fl_str_mv	2023-03-16T15:19:11Z
dc.type.none.fl_str_mv	Artículo
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dc.identifier.issn.none.fl_str_mv	1909-6356
dc.identifier.uri.none.fl_str_mv	10.15446/rcciquifa.v50n3.100240 https://hdl.handle.net/20.500.12494/48974
dc.identifier.bibliographicCitation.none.fl_str_mv	M.d.M. Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez, Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15 K, J. Mol. Liq., 204, 132-136 (2015), doi: 10.1016/j.molliq.2015.01.047. B. Aday, P. Sola, F. Çolak, M. Kaya, Synthesis of novel sulfonamide analogs containing sulfamerazine/sulfaguanidine and their biological activities, J. Enzym. Inhib. Med. Chem., 31, 1005-1010 (2016), doi: 10.3109/14756366.2015.1079183. D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021. Regulation on Maximum Residue Limits, Salud pública, (n.d.)., URL: https:// ec.europa.eu/health/veterinary-use/maximum-residue-limits/regulations_es, accessed January 29, 2021. European Commission, EEC Regulation 90/2377/EEC incorporating amending regulation 92/675/EEC, Brussels, 1997, URL: https://eur-lex.europa.eu/legalcontent/ EN/TXT/PDF/?uri=CELEX:31997L0078&from=LV, accessed January 29, 2021. A.M. Cruz-González, M.S. Vargas-Santana, C.P. Ortiz, N.E. Cerquera, D.R. Delgado, F. Martínez, A. Jouyban, W.E. Acree Jr., Solubility of sulfadiazine in (ethylene glycol + water) mixtures: Measurement, correlation, thermodynamics and preferential solvation, J. Mol. Liq., 323, 115058 (2021), doi: 10.1016/j. molliq.2020.115058. D.R. Delgado, O. Bahamón-Hernandez, N.E. Cerquera, C.P. Ortiz, F. Martínez, E. Rahimpour, A. Jouyban, W.E. Acree, Solubility of sulfadiazine in (acetonitrile + methanol) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation, J. Mol. Liq., 322, 114979 (2021), doi: 10.1016/j. molliq.2020.114979. M.M. Muñoz, F. Martinez, D.R. Delgado, A. Jouyban, W.E. Acree, Equilibrium solubility and apparent specific volume at saturation of sodium sulfadiazine in some aqueous cosolvent mixtures at 298.2 K, Phys. Chem. Liq., 59, 40-52 (2021), doi: 10.1080/00319104.2019.1675158. D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, M.T. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in ,4-dioxane+water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015), doi: 10.1016/j.fluid.2015.03.046. D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol+water mixtures at several temperatures, Fluid Phase Equilib., 379, -138 (2014), doi: 10.1016/j.fluid.2014.07.013. D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021. D.R. Delgado, F. Martínez, Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013), doi: 10.1016/j. molliq.2013.06.011. D.R. Delgado, F. Martínez R., Thermodynamic study of the solubility of sodium sulfadiazine in some ethanol + water cosolvent mixtures, Vitae, 17, 191-198 (2010). KJ. Deng, X.H. Lan, G. Sun, L.Y. Ji, X. lian Zheng, Determination of sulfonamide residues in chicken liver using high-performance liquid chromatography, Food Anal. Methods, 9, 3337-3344 (2016), doi: 10.1007/s12161-016-0514-6. R. Galarini, F. Diana, S. Moretti, B. Puppini, G. Saluti, L. Persic, Development and validation of a new qualitative ELISA screening for multiresidue detection of sulfonamides in food and feed, Food Control, 35, 300-310 (2014), doi: 1016/j.foodcont.2013.07.014. A. Barani, A.A. Fallah, Occurrence of tetracyclines, sulfonamides, fluoroquinolones and florfenicol in farmed rainbow trout in Iran, Food Agr. Immunol., 26, -429 (2015), doi: 10.1080/09540105.2014.950199. R.E. Cárdenas, L.E. Tinoco, D.M. Galindres, A. Beltrán, C.D. Oviedo, J. Osorio, Prediction of sulfadiazine solubility in some cosolvent mixtures using non-ideal solution models, Rev. Colomb. Cienc. Quím. Farm., 49, 822-842 (2020), doi: 15446/rcciquifa.v49n3.91347. M.A. Ruidiaz, D.R. Delgado, F. Martínez, Performance of the Jouyban-Acree and Yalkowsky-Roseman models for estimating the solubility of indomethacin in ethanol+ water mixtures, Rev. Acad. Colomb. Cienc. Exact. Fis. Nat., 35, 329- (2011). J.T. Rubino, S.H. Yalkowsky, Cosolvency and deviations from log-linear solubilization, Pharm. Res., 4, 231-236 (1987), doi: 10.1023/A:1016408211963. J.L. Gómez, G.A. Rodríguez, D.M. Cristancho, D.R. Delgado, A. Yurquina, F. Martínez, Extended Hildebrand Solubility Approach applied to nimodipine in PEG 400 + ethanol mixtures, Rev. Colomb. Cienc. Quim. Farm., 42, 103- (2013). Z.J. Cárdenas, D.M. Jiménez, D.R. Delgado, M.Á. Peña, F. Martínez, Extended Hildebrand solubility approach applied to some sulphonamides in propylene glycol + water mixtures, Phys. Chem. Liq., 53, 763-775 (2015), doi: 1080/00319104.2015.1048247. G.R. Rojas, A.F. Rivera, D.R. Delgado, Application of the Extended Hildebrand solubility approach applied to mitomycin C in ethanol+ water mixtures, Revista Ingeniería y Región, 13, 149-157 (2015), doi: 25054/22161325.716. D.M. Cristancho, D.R. Delgado, F. Martínez, Meloxicam solubility in ethanol+water mixtures according to the extended Hildebrand solubility approach, J. Solution Chem., 42, 1706-1716 (2013), doi: 10.1007/s10953-013- -y. A. Aydi, C.P. Ortiz, D.I. Caviedes-Rubio, C. Ayadi, S. Hbaieb, D.R. Delgado, Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures, J. Taiwan Inst. Chem. Eng., 118, 68-77 (2021), doi: 10.1016/j.jtice.2020.12.031. J.W. Millard, F.A. Alvarez-Núñez, S.H. Yalkowsky, Solubilization by cosolvents: Establishing useful constants for the log-linear model, Int. J. Pharm., 245, 153- (2002), doi: 10.1016/S0378-5173(02)00334-4.
identifier_str_mv	1909-6356 10.15446/rcciquifa.v50n3.100240 M.d.M. Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez, Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15 K, J. Mol. Liq., 204, 132-136 (2015), doi: 10.1016/j.molliq.2015.01.047. B. Aday, P. Sola, F. Çolak, M. Kaya, Synthesis of novel sulfonamide analogs containing sulfamerazine/sulfaguanidine and their biological activities, J. Enzym. Inhib. Med. Chem., 31, 1005-1010 (2016), doi: 10.3109/14756366.2015.1079183. D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021. Regulation on Maximum Residue Limits, Salud pública, (n.d.)., URL: https:// ec.europa.eu/health/veterinary-use/maximum-residue-limits/regulations_es, accessed January 29, 2021. European Commission, EEC Regulation 90/2377/EEC incorporating amending regulation 92/675/EEC, Brussels, 1997, URL: https://eur-lex.europa.eu/legalcontent/ EN/TXT/PDF/?uri=CELEX:31997L0078&from=LV, accessed January 29, 2021. A.M. Cruz-González, M.S. Vargas-Santana, C.P. Ortiz, N.E. Cerquera, D.R. Delgado, F. Martínez, A. Jouyban, W.E. Acree Jr., Solubility of sulfadiazine in (ethylene glycol + water) mixtures: Measurement, correlation, thermodynamics and preferential solvation, J. Mol. Liq., 323, 115058 (2021), doi: 10.1016/j. molliq.2020.115058. D.R. Delgado, O. Bahamón-Hernandez, N.E. Cerquera, C.P. Ortiz, F. Martínez, E. Rahimpour, A. Jouyban, W.E. Acree, Solubility of sulfadiazine in (acetonitrile + methanol) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation, J. Mol. Liq., 322, 114979 (2021), doi: 10.1016/j. molliq.2020.114979. M.M. Muñoz, F. Martinez, D.R. Delgado, A. Jouyban, W.E. Acree, Equilibrium solubility and apparent specific volume at saturation of sodium sulfadiazine in some aqueous cosolvent mixtures at 298.2 K, Phys. Chem. Liq., 59, 40-52 (2021), doi: 10.1080/00319104.2019.1675158. D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, M.T. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in ,4-dioxane+water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015), doi: 10.1016/j.fluid.2015.03.046. D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol+water mixtures at several temperatures, Fluid Phase Equilib., 379, -138 (2014), doi: 10.1016/j.fluid.2014.07.013. D.R. Delgado, F. Martínez, Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013), doi: 10.1016/j. molliq.2013.06.011. D.R. Delgado, F. Martínez R., Thermodynamic study of the solubility of sodium sulfadiazine in some ethanol + water cosolvent mixtures, Vitae, 17, 191-198 (2010). KJ. Deng, X.H. Lan, G. Sun, L.Y. Ji, X. lian Zheng, Determination of sulfonamide residues in chicken liver using high-performance liquid chromatography, Food Anal. Methods, 9, 3337-3344 (2016), doi: 10.1007/s12161-016-0514-6. R. Galarini, F. Diana, S. Moretti, B. Puppini, G. Saluti, L. Persic, Development and validation of a new qualitative ELISA screening for multiresidue detection of sulfonamides in food and feed, Food Control, 35, 300-310 (2014), doi: 1016/j.foodcont.2013.07.014. A. Barani, A.A. Fallah, Occurrence of tetracyclines, sulfonamides, fluoroquinolones and florfenicol in farmed rainbow trout in Iran, Food Agr. Immunol., 26, -429 (2015), doi: 10.1080/09540105.2014.950199. R.E. Cárdenas, L.E. Tinoco, D.M. Galindres, A. Beltrán, C.D. Oviedo, J. Osorio, Prediction of sulfadiazine solubility in some cosolvent mixtures using non-ideal solution models, Rev. Colomb. Cienc. Quím. Farm., 49, 822-842 (2020), doi: 15446/rcciquifa.v49n3.91347. M.A. Ruidiaz, D.R. Delgado, F. Martínez, Performance of the Jouyban-Acree and Yalkowsky-Roseman models for estimating the solubility of indomethacin in ethanol+ water mixtures, Rev. Acad. Colomb. Cienc. Exact. Fis. Nat., 35, 329- (2011). J.T. Rubino, S.H. Yalkowsky, Cosolvency and deviations from log-linear solubilization, Pharm. Res., 4, 231-236 (1987), doi: 10.1023/A:1016408211963. J.L. Gómez, G.A. Rodríguez, D.M. Cristancho, D.R. Delgado, A. Yurquina, F. Martínez, Extended Hildebrand Solubility Approach applied to nimodipine in PEG 400 + ethanol mixtures, Rev. Colomb. Cienc. Quim. Farm., 42, 103- (2013). Z.J. Cárdenas, D.M. Jiménez, D.R. Delgado, M.Á. Peña, F. Martínez, Extended Hildebrand solubility approach applied to some sulphonamides in propylene glycol + water mixtures, Phys. Chem. Liq., 53, 763-775 (2015), doi: 1080/00319104.2015.1048247. G.R. Rojas, A.F. Rivera, D.R. Delgado, Application of the Extended Hildebrand solubility approach applied to mitomycin C in ethanol+ water mixtures, Revista Ingeniería y Región, 13, 149-157 (2015), doi: 25054/22161325.716. D.M. Cristancho, D.R. Delgado, F. Martínez, Meloxicam solubility in ethanol+water mixtures according to the extended Hildebrand solubility approach, J. Solution Chem., 42, 1706-1716 (2013), doi: 10.1007/s10953-013- -y. A. Aydi, C.P. Ortiz, D.I. Caviedes-Rubio, C. Ayadi, S. Hbaieb, D.R. Delgado, Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures, J. Taiwan Inst. Chem. Eng., 118, 68-77 (2021), doi: 10.1016/j.jtice.2020.12.031. J.W. Millard, F.A. Alvarez-Núñez, S.H. Yalkowsky, Solubilization by cosolvents: Establishing useful constants for the log-linear model, Int. J. Pharm., 245, 153- (2002), doi: 10.1016/S0378-5173(02)00334-4.
url	https://hdl.handle.net/20.500.12494/48974
dc.relation.isversionof.none.fl_str_mv	Vargas-Santana, M. S. ., Cruz-González, A. M., Cerquera, N. E. ., Escobar Rodriguez, A. S., Cardenas, R. E. ., Calderón-Losada, O. ., Ortiz, C. P. ., & Delgado, D. R. (2022). Método extendido de Hildebrand y modelo de Yalkowsky- Roseman en la estimación de la solubilidad de sulfadiazina y sulfametazina en algunas mezclas {etilenglicol (1) + agua (2)} a varias temperaturas. Revista Colombiana De Ciencias Químico-Farmacéuticas, 50(3). https://doi.org/10.15446/rcciquifa.v50n3.100240
dc.relation.ispartofjournal.none.fl_str_mv	Revista Colombiana de Ciencias Químico-Farmacéuticas
dc.relation.references.none.fl_str_mv	M.d.M. Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez, Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15 K, J. Mol. Liq., 204, 132-136 (2015), doi: 10.1016/j.molliq.2015.01.047. D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021. A.M. Cruz-González, M.S. Vargas-Santana, C.P. Ortiz, N.E. Cerquera, D.R. Delgado, F. Martínez, A. Jouyban, W.E. Acree Jr., Solubility of sulfadiazine in (ethylene glycol + water) mixtures: Measurement, correlation, thermodynamics and preferential solvation, J. Mol. Liq., 323, 115058 (2021), doi: 10.1016/j. molliq.2020.115058. D.R. Delgado, O. Bahamón-Hernandez, N.E. Cerquera, C.P. Ortiz, F. Martínez, E. Rahimpour, A. Jouyban, W.E. Acree, Solubility of sulfadiazine in (acetonitrile + methanol) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation, J. Mol. Liq., 322, 114979 (2021), doi: 10.1016/j. molliq.2020.114979. M.M. Muñoz, F. Martinez, D.R. Delgado, A. Jouyban, W.E. Acree, Equilibrium solubility and apparent specific volume at saturation of sodium sulfadiazine in some aqueous cosolvent mixtures at 298.2 K, Phys. Chem. Liq., 59, 40-52 (2021), doi: 10.1080/00319104.2019.1675158. D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, M.T. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in ,4-dioxane+water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015), doi: 10.1016/j.fluid.2015.03.046. D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol+water mixtures at several temperatures, Fluid Phase Equilib., 379, -138 (2014), doi: 10.1016/j.fluid.2014.07.013. D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021. D.R. Delgado, F. Martínez, Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013), doi: 10.1016/j. molliq.2013.06.011.
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spelling	Delgado, DanielDelgado, Daniel RicardoVargas-Santana, Martha SofíaCruz-González, Ana MaríasCerquera, NestorEscobar Rodriguez, Alana SofíaCardenas, Rossember E.Ortiz, Claudia PatriciaCalderón-Losada, OmarDelgado, Daniel Ricardo50/32023-03-16T15:19:11Z2023-03-16T15:19:11Z2022-02-041909-635610.15446/rcciquifa.v50n3.100240https://hdl.handle.net/20.500.12494/48974M.d.M. Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez, Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15 K, J. Mol. Liq., 204, 132-136 (2015), doi: 10.1016/j.molliq.2015.01.047.B. Aday, P. Sola, F. Çolak, M. Kaya, Synthesis of novel sulfonamide analogs containing sulfamerazine/sulfaguanidine and their biological activities, J. Enzym. Inhib. Med. Chem., 31, 1005-1010 (2016), doi: 10.3109/14756366.2015.1079183.D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021.Regulation on Maximum Residue Limits, Salud pública, (n.d.)., URL: https:// ec.europa.eu/health/veterinary-use/maximum-residue-limits/regulations_es, accessed January 29, 2021.European Commission, EEC Regulation 90/2377/EEC incorporating amending regulation 92/675/EEC, Brussels, 1997, URL: https://eur-lex.europa.eu/legalcontent/ EN/TXT/PDF/?uri=CELEX:31997L0078&from=LV, accessed January 29, 2021.A.M. Cruz-González, M.S. Vargas-Santana, C.P. Ortiz, N.E. Cerquera, D.R. Delgado, F. Martínez, A. Jouyban, W.E. Acree Jr., Solubility of sulfadiazine in (ethylene glycol + water) mixtures: Measurement, correlation, thermodynamics and preferential solvation, J. Mol. Liq., 323, 115058 (2021), doi: 10.1016/j. molliq.2020.115058.D.R. Delgado, O. Bahamón-Hernandez, N.E. Cerquera, C.P. Ortiz, F. Martínez, E. Rahimpour, A. Jouyban, W.E. Acree, Solubility of sulfadiazine in (acetonitrile + methanol) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation, J. Mol. Liq., 322, 114979 (2021), doi: 10.1016/j. molliq.2020.114979.M.M. Muñoz, F. Martinez, D.R. Delgado, A. Jouyban, W.E. Acree, Equilibrium solubility and apparent specific volume at saturation of sodium sulfadiazine in some aqueous cosolvent mixtures at 298.2 K, Phys. Chem. Liq., 59, 40-52 (2021), doi: 10.1080/00319104.2019.1675158.D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, M.T. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in ,4-dioxane+water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015), doi: 10.1016/j.fluid.2015.03.046.D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol+water mixtures at several temperatures, Fluid Phase Equilib., 379, -138 (2014), doi: 10.1016/j.fluid.2014.07.013.D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021.D.R. Delgado, F. Martínez, Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013), doi: 10.1016/j. molliq.2013.06.011.D.R. Delgado, F. Martínez R., Thermodynamic study of the solubility of sodium sulfadiazine in some ethanol + water cosolvent mixtures, Vitae, 17, 191-198 (2010).KJ. Deng, X.H. Lan, G. Sun, L.Y. Ji, X. lian Zheng, Determination of sulfonamide residues in chicken liver using high-performance liquid chromatography, Food Anal. Methods, 9, 3337-3344 (2016), doi: 10.1007/s12161-016-0514-6.R. Galarini, F. Diana, S. Moretti, B. Puppini, G. Saluti, L. Persic, Development and validation of a new qualitative ELISA screening for multiresidue detection of sulfonamides in food and feed, Food Control, 35, 300-310 (2014), doi: 1016/j.foodcont.2013.07.014.A. Barani, A.A. Fallah, Occurrence of tetracyclines, sulfonamides, fluoroquinolones and florfenicol in farmed rainbow trout in Iran, Food Agr. Immunol., 26, -429 (2015), doi: 10.1080/09540105.2014.950199.R.E. Cárdenas, L.E. Tinoco, D.M. Galindres, A. Beltrán, C.D. Oviedo, J. Osorio, Prediction of sulfadiazine solubility in some cosolvent mixtures using non-ideal solution models, Rev. Colomb. Cienc. Quím. Farm., 49, 822-842 (2020), doi: 15446/rcciquifa.v49n3.91347.M.A. Ruidiaz, D.R. Delgado, F. Martínez, Performance of the Jouyban-Acree and Yalkowsky-Roseman models for estimating the solubility of indomethacin in ethanol+ water mixtures, Rev. Acad. Colomb. Cienc. Exact. Fis. Nat., 35, 329- (2011).J.T. Rubino, S.H. Yalkowsky, Cosolvency and deviations from log-linear solubilization, Pharm. Res., 4, 231-236 (1987), doi: 10.1023/A:1016408211963.J.L. Gómez, G.A. Rodríguez, D.M. Cristancho, D.R. Delgado, A. Yurquina, F. Martínez, Extended Hildebrand Solubility Approach applied to nimodipine in PEG 400 + ethanol mixtures, Rev. Colomb. Cienc. Quim. Farm., 42, 103- (2013).Z.J. Cárdenas, D.M. Jiménez, D.R. Delgado, M.Á. Peña, F. Martínez, Extended Hildebrand solubility approach applied to some sulphonamides in propylene glycol + water mixtures, Phys. Chem. Liq., 53, 763-775 (2015), doi: 1080/00319104.2015.1048247.G.R. Rojas, A.F. Rivera, D.R. Delgado, Application of the Extended Hildebrand solubility approach applied to mitomycin C in ethanol+ water mixtures, Revista Ingeniería y Región, 13, 149-157 (2015), doi: 25054/22161325.716.D.M. Cristancho, D.R. Delgado, F. Martínez, Meloxicam solubility in ethanol+water mixtures according to the extended Hildebrand solubility approach, J. Solution Chem., 42, 1706-1716 (2013), doi: 10.1007/s10953-013- -y.A. Aydi, C.P. Ortiz, D.I. Caviedes-Rubio, C. Ayadi, S. Hbaieb, D.R. Delgado, Solution thermodynamics and preferential solvation of sulfamethazine in ethylene glycol + water mixtures, J. Taiwan Inst. Chem. Eng., 118, 68-77 (2021), doi: 10.1016/j.jtice.2020.12.031.J.W. Millard, F.A. Alvarez-Núñez, S.H. Yalkowsky, Solubilization by cosolvents: Establishing useful constants for the log-linear model, Int. J. Pharm., 245, 153- (2002), doi: 10.1016/S0378-5173(02)00334-4.Objetivo: aplicar los enfoques de los modelos de Solubilidad Extendido de Hildebrand (EHSA) y Yalkowsky Roseman (YR) para evaluar la solubilidad de sulfadiazina y sulfametazina en mezclas de etilenglicol + agua. Metodología: para los cálculos se utilizaron las solubilidades experimentales en equilibrio reportadas y algunas propiedades de fusión de estos fármacos. Resultados: en particular, se encontró un buen carácter predictivo de EHSA (con desviaciones medias inferiores al 3,0%) utilizando polinomios regulares en orden dos correlacionando el parámetro de interacción W con el parámetro de solubilidad de Hildebrand de mezclas de disolventes sin fármaco; sin embargo, los resultados obtenidos del modelo YR muestran desviaciones relativamente altas superiores al 50%.Aim: extended Hildebrand Solubility Approach (EHSA) and Yalkowsky Roseman (YR) were applied to evaluate the solubility of sulfadiazine, and sulfamethazine in ethylene glycol + water mixtures. Methodology: reported experimental equilibrium solubilities and some fusion properties of these drugs were used for the calculations. Results: a good predictive character of EHSA (with mean deviations lower than 3.0%) were found by using regular polynomials in order two correlating the interaction parameter W with the Hildebrand solubility parameter of solvent mixtures without drug; however, the results obtained from YR model show relatively high deviations greater than 50%.Introduction Theoretical Results and discussion Conclusions Conflict of interests Referenceshttps://scienti.minciencias.gov.co/cvlac/visualizador/generarCurriculoCv.do?cod_rh=0001402116https://orcid.org/0000-0002-4835-9739https://scienti.minciencias.gov.co/gruplac/jsp/visualiza/visualizagr.jsp?nro=00000000004151danielr.delgado@campusucc.edu.cohttps://scholar.google.com/citations?user=OW0mejcAAAAJ&hl=es25Universidad Nacional de ColombiaUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Civil, NeivaIngeniería CivilNeivaVargas-Santana, M. S. ., Cruz-González, A. M., Cerquera, N. E. ., Escobar Rodriguez, A. S., Cardenas, R. E. ., Calderón-Losada, O. ., Ortiz, C. P. ., & Delgado, D. R. (2022). Método extendido de Hildebrand y modelo de Yalkowsky- Roseman en la estimación de la solubilidad de sulfadiazina y sulfametazina en algunas mezclas {etilenglicol (1) + agua (2)} a varias temperaturas. Revista Colombiana De Ciencias Químico-Farmacéuticas, 50(3). https://doi.org/10.15446/rcciquifa.v50n3.100240Revista Colombiana de Ciencias Químico-FarmacéuticasM.d.M. Muñoz, D.R. Delgado, M.Á. Peña, A. Jouyban, F. Martínez, Solubility and preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in propylene glycol + water mixtures at 298.15 K, J. Mol. Liq., 204, 132-136 (2015), doi: 10.1016/j.molliq.2015.01.047.D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021.A.M. Cruz-González, M.S. Vargas-Santana, C.P. Ortiz, N.E. Cerquera, D.R. Delgado, F. Martínez, A. Jouyban, W.E. Acree Jr., Solubility of sulfadiazine in (ethylene glycol + water) mixtures: Measurement, correlation, thermodynamics and preferential solvation, J. Mol. Liq., 323, 115058 (2021), doi: 10.1016/j. molliq.2020.115058.D.R. Delgado, O. Bahamón-Hernandez, N.E. Cerquera, C.P. Ortiz, F. Martínez, E. Rahimpour, A. Jouyban, W.E. Acree, Solubility of sulfadiazine in (acetonitrile + methanol) mixtures: Determination, correlation, dissolution thermodynamics and preferential solvation, J. Mol. Liq., 322, 114979 (2021), doi: 10.1016/j. molliq.2020.114979.M.M. Muñoz, F. Martinez, D.R. Delgado, A. Jouyban, W.E. Acree, Equilibrium solubility and apparent specific volume at saturation of sodium sulfadiazine in some aqueous cosolvent mixtures at 298.2 K, Phys. Chem. Liq., 59, 40-52 (2021), doi: 10.1080/00319104.2019.1675158.D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, M.T. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in ,4-dioxane+water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015), doi: 10.1016/j.fluid.2015.03.046.D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol+water mixtures at several temperatures, Fluid Phase Equilib., 379, -138 (2014), doi: 10.1016/j.fluid.2014.07.013.D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014), doi: 10.1016/j.molliq.2013.12.021.D.R. Delgado, F. Martínez, Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013), doi: 10.1016/j. molliq.2013.06.011.Sulfadiazinesulfamethazineextended Hildebrand model2 o mas bases de datosSulfadiazinasulfametazinaExtended Hildebrand modelExtended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperaturesArtículohttp://purl.org/coar/resource_type/c_6501http://purl.org/coar/resource_type/c_2df8fbb1http://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articlehttp://purl.org/redcol/resource_type/ARTinfo:eu-repo/semantics/publishedVersionAtribución – Sin 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

Extended Hildebrand solubility approach and Yalkowsky-Roseman model for estimating the solubility of sulfadiazine and sulfamethazine in some {ethylene glycol (1) + water (2)} mixtures at several temperatures

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