Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures

La mayor solvatación del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad. En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolve...

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Autores:: Sandoval Castro, Juan Jose

Tipo de recurso:: Trabajo de grado de pregrado

Fecha de publicación:: 2018

Institución:: Universidad Cooperativa de Colombia

Repositorio:: Repositorio UCC

Idioma:

id	COOPER2_8bd6018f02a4c676c8ca4df4fde51c0b
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network_acronym_str	COOPER2
network_name_str	Repositorio UCC
repository_id_str
dc.title.spa.fl_str_mv	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
spellingShingle	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures Ethanol Solvatación preferencial Tricina Ethanol Preferential solvation Tricin
title_short	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_full	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_fullStr	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_full_unstemmed	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
title_sort	Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures
dc.creator.fl_str_mv	Sandoval Castro, Juan Jose
dc.contributor.advisor.none.fl_str_mv	Delgado, Daniel Ricardo
dc.contributor.author.none.fl_str_mv	Sandoval Castro, Juan Jose
dc.subject.spa.fl_str_mv	Ethanol Solvatación preferencial Tricina
topic	Ethanol Solvatación preferencial Tricina Ethanol Preferential solvation Tricin
dc.subject.other.spa.fl_str_mv	Ethanol Preferential solvation Tricin
description	La mayor solvatación del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad. En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolvente es más básico que el agua; el documento esta estructurado por una teoría y unos resultados basados en que la tricina es muy sensible a los efectos de solvatación específicos, por lo que el parámetro de solvatación preferencial, x1,3, es negativo en las mezclas ricas en agua, pero positivo en todas las otras composiciones a temperaturas desde 293,15 hasta 313,15 K. La solubilidad aumenta con la temperatura en todos los casos, lo que indica que en la disolución el proceso es endotérmico. La solubilidad más alta de tricina expresada como fracción molar se obtuvieron cerca de etanol a T = 313.15 K, mientras que los valores más bajos fueron encontrados en agua pura (2) a 293.15 K.
publishDate	2018
dc.date.issued.none.fl_str_mv	2018-12-04
dc.date.accessioned.none.fl_str_mv	2019-01-21T17:18:13Z
dc.date.available.none.fl_str_mv	2019-01-21T17:18:13Z
dc.type.none.fl_str_mv	Trabajo de grado - Pregrado
dc.type.coar.none.fl_str_mv	http://purl.org/coar/resource_type/c_7a1f
dc.type.driver.none.fl_str_mv	info:eu-repo/semantics/bachelorThesis
dc.type.version.none.fl_str_mv	info:eu-repo/semantics/acceptedVersion
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dc.identifier.uri.none.fl_str_mv	https://hdl.handle.net/20.500.12494/6641
dc.identifier.bibliographicCitation.spa.fl_str_mv	Sandoval Castro, Juan. S. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures (tesis de pregrado). Recuperado de: http://repository.ucc.edu.co/handle/ucc/6641
url	https://hdl.handle.net/20.500.12494/6641
identifier_str_mv	Sandoval Castro, Juan. S. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures (tesis de pregrado). Recuperado de: http://repository.ucc.edu.co/handle/ucc/6641
dc.relation.references.spa.fl_str_mv	H. Cai, M. Al-Fayez, R.G. Tunstall, S. Platton, P. Greaves, W.P. Steward, A.J. Gescher, The rice bran constituent tricin potently inhibits cyclooxygenase enzymes and interferes with intestinal carcinogenesis in ApcMin mice, Mol. Cancer Ther., 4, 1287-1292 (2005). T. Oyama, Y. Yasui, S. Sugie, M. Koketsu, K. Watanabe, T. Tanaka, Dietary tricin suppresses inflammation-related colon carcinogenesis in male Crj: CD-1 mice, Cancer Prev. Res., 2, 1031-1038 (2009). M. Li, Y. Pu, C.G. Yoo, A.J. Ragauskas, The occurrence of tricin and its deriva- tives in plants, Green Chem., 18, 1439-1454 (2016). V.A. Moscatelli, Química y farmacología de una planta medicinal argentina: Artemisia copa, Dominguezia, 31, 5-13 (2015). A. Moheb, M. Grondin, R.K. Ibrahim, R. Roy, F. Sarhan, Winter wheat hull (husk) is a valuable source for tricin, a potential selective cytotoxic agent, Food Chem., 138, 931-973 (2013). W. Lan, J. Rencoret, F. Lu, S.D. Karlen, B.G. Smith, P.J. Harris, J.C. del Rio, J. Ralph, Tricin-lignins: Occurrence and quantitation of tricin in relation to phy- logeny, Plant J., 88, 1046-1057 (2016). A. Jouyban, W.E. Acree, Mathematical derivation of the Jouyban-Acree model to represent solute solubility data in mixed solvents at various temperatures, J. Mol. Liq., 256, 541-547 (2018). N.A. Bowden, D. Méndez-Sevillano, J.P.M. Sanders, M.E. Bruins, Modelling the effects of ethanol on the solubility of the proteinogenic amino acids with the NRTL, Gude and Jouyban-Acree models, Fluid Phase Equilib., 459, 158-169 (2018). M.A. Kalam, A.A. Khan, A. Alshamsan, A. Haque, F. Shakeel; Solubility of a poorly soluble immunosuppressant in different pure solvents: Measurement, cor- relation, thermodynamics and molecular interactions, J. Mol. Liq., 249, 53-60 (2018). E. Rahimpour, M. Barzegar-Jalali, A. Shayanfar, A. Jouyban, Generally trained models to predict drug solubility in N-methyl-2-pyrrolidone + water mixtures at various temperatures, J. Mol. Liq., 254, 34-38 (2018). A. Fathi-Azarbayjani, M.A. Jalil-Vaez-Gharamaleki, A. Jouyban, Measurement and correlation of deferiprone solubility: Investigation of solubility parameter and application of van’t Hoff equation and Jouyban–Acree model, J. Mol. Liq.,215, 339-344 (2016). M.A. Ruidiaz, D.R. Delgado, C.P. Mora, A. Yurquina, F. Martínez, Estimation of the indomethacin solubility in ethanol + water mixtures by the extended Hildebrand solubility approach, Rev. Colomb. Cienc. Quím. Farm., 39, 79-95 (2010). Y. Cheng, Z. Wang, S. Ding, J. Li, Determination and correlation of the solubility of tricin in water and ethanol mixtures, J. Chem. Thermodyn., 89, 89-92 (2015). G. Chen, J. Chen, C. Cheng, Y. Cong, C. Du, H. Zhao, Solubility and pref- erential solvation of econazole nitrate in binary solvent mixtures of methanol, ethanol and 1,4-dioxane in water, J. Chem. Thermodyn., 111, 228-237 (2017). J. Chen, G. Chen, Y. Cong, C. Du, H. Zhao, Solubility modelling and prefer- ential solvation of paclobutrazol in co-solvent mixtures of (ethanol, n-propanol and 1,4-dioxane) + water, J. Chem. Thermodyn., 112, 249-258 (2017). A. Jouyban, W.E. Acree Jr., F. Martínez, Modeling the solubility and prefer- ential solvation of gallic acid in cosolvent + water mixtures, J. Mol. Liq., 224, 502-506 (2016). Y. Marcus, “Solvent Mixtures: Properties and Selective Solvation”, Marcel Dekker, Inc., New York, 2002. Y. Marcus, Preferential solvation of ibuprofen and naproxen in aqueous 1,2-pro- panediol, Acta Chim. Slov., 56, 40-44 (2009). Y. Marcus, On the preferential solvation of drugs and PAHs in binary solvent mixtures, J. Mol. Liq., 140, 61-67 (2008). D.I. Caviedes Rubio, R.G. Sotomayor, D.R. Delgado, Solvatación preferencial de la naringina en mezclas cosolventes etanol + agua mediante el método de las integrales inversas de Kirkwood-Buff, Rev. Colomb. Cienc. Quím. Farm., 44, 220- 235 (2015). D.R. Delgado, E.F. Vargas, F. Martínez, Preferential solvation of xylitol in etha- nol + water solvent mixtures according to the IKBI and QLQC methods, Rev. Colomb. Quím., 42, 59-66 (2013). D.R. Delgado, F. Martínez. Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib., 379,128-138 (2015). D.R. Delgado, M.A. Peña, F. Martínez, Preferential solvation of some sulfon- amides in propylene glycol + water solvent mixtures according to the IKBI and QLQC methods, J. Solution Chem., 43, 360-374 (2014). D.R. Delgado, M.Á. Peña, F. Martínez, Preferential solvation of acetaminophen in ethanol + water solvent mixtures according to the inverse Kirkwood-Buff inte- grals method, Rev. Colomb. Cienc. Quím. Farm., 42, 298-314 (2013). A.C. Gaviria-Castillo, J.D. Artunduaga-Tole, J.D. Rodríguez-Rubiano, J.A. Zúñiga-Andrade, D.R. Delgado, A. Jouyban, F. Martínez, Solution thermo- dynamics and preferential solvation of triclocarban in {1, 4-dioxane (1) + water (2)} mixtures at 298.15 K, Phys. Chem. Liq., Forthcoming 2018, doi: 10.1080/00319104.2017.1416613. J.A. Lasso, D.I. Caviedes, D.R. Delgado, Preferential solvation of 4-hydroxy- 2,5-dimethyl-3(2H)-furanone (DMHF) in ethanol + water mixtures according to IKBI and QLQC methods, Ingeniería y Región, 13, 139-147 (2015). A. Jouyban, S. Nozohouri, F. Martínez, Solubility of celecoxib in {2-propanol (1) + water (2)} mixtures at various temperatures: Experimental data and ther- modynamic analysis J. Mol. Liq., 254, 1-7 (2018). A.F.M. Barton, “Handbook of Solubility parameters and Other CohesionParameter”, 2nd edition, CRC Press, Inc., New York, 1991. R.F. Fedors, A method for estimating both the solubility parameters and molar volumes of liquids, Polym. Eng. Sci., 14, 147-154 (1974). D.M. Jimenez, Z.J. Cárdenas, D.R. Delgado, M.Á. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in 1,4-diox- ane + water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015). D.R. Delgado, A.R. Holguín, O.A. Almanza, F. Martínez, Y. Marcus, Solubility and preferential solvation of meloxicam in ethanol + water mixtures, Fluid Phase Equilib., 305, 88-95 (2011). D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib., 379, 128-138 (2014). D.R. Delgado, F. Martínez, Solubility and solution thermodynamics of sulfa- merazine and sulfamethazine in some ethanol + water mixtures, Fluid Phase Equilib., 360, 88-96 (2013). E.A. Ahumada, D.R. Delgado, F. Martínez. Solution thermodynamics of acet- aminophen in some PEG 400 + water mixtures, Fluid Phase Equilib., 332, 120- 127 (2012). D.R. Delgado, F. Martínez. Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013). D.R. Delgado, F. Martínez. Solubility and solution thermodynamics of some sul- fonamides in 1-propanol + water mixtures, J. Solution Chem., 43, 836-852 (2014). E.A. Cantillo, D.R. Delgado, F. Martínez, Solution thermodynamics of indo- methacin in ethanol + propylene glycol mixtures, J. Mol. Liq., 181, 62-67 (2013). D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014). D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, F. Martínez, A. Jouyban, Preferen- tial solvation of methocarbamol in aqueous binary cosolvent mixtures at 298.15 K, Phys. Chem. Liq., 52, 726-737 (2014). J. Jiménez, J. Manrique, F. Martínez, Effect of temperature on some volumetric properties for ethanol+ water mixtures, Rev. Colomb. Cienc. Quím. Farm., 33, 145-155 (2004). M.J. Kamlet, R.W. Taft, The solvatochromic comparison method. I. The beta- scale of solvent hydrogen-bond acceptor (HBA) basicities, J. Am. Chem. Soc., 98, 377-383 (1976). R.W. Taft, M.J. Kamlet, The solvatochromic comparison method. II. The alpha- scale of solvent hydrogen-bond donor (hba) acidities, J. Am. Chem. Soc., 98, 2886-2894 (1976). F. Martínez, A. Jouyban, W.E. Acree Jr., Further numerical analysis on the solu- bility of ibrutinib in ethanol + water mixtures at different temperatures, J. Mol. Liq., 218, 35-38 (2016). A. Jouyban, F. Martínez, W.E. Acree Jr., Comments on “Solubility and solution thermodynamics of 2,3,4,5-tetrabromothiophene in (ethanol + trichlorometh- ane) binary solvent mixtures”, Fluid Phase Equilib., 421, 88-92 (2016).
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spelling	Delgado, Daniel RicardoSandoval Castro, Juan Jose2019-01-21T17:18:13Z2019-01-21T17:18:13Z2018-12-04https://hdl.handle.net/20.500.12494/6641Sandoval Castro, Juan. S. (2018). Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures (tesis de pregrado). Recuperado de: http://repository.ucc.edu.co/handle/ucc/6641La mayor solvatación del fármaco por etanol se presenta en mezclas de proporción intermedia y en mezclas ricas en etanol, esto podría deberse principalmente a los efectos de la polaridad. En estas mezclas, el fármaco actuaría como ácido de Lewis con las moléculas de etanol, puesto que este codisolvente es más básico que el agua; el documento esta estructurado por una teoría y unos resultados basados en que la tricina es muy sensible a los efectos de solvatación específicos, por lo que el parámetro de solvatación preferencial, x1,3, es negativo en las mezclas ricas en agua, pero positivo en todas las otras composiciones a temperaturas desde 293,15 hasta 313,15 K. La solubilidad aumenta con la temperatura en todos los casos, lo que indica que en la disolución el proceso es endotérmico. La solubilidad más alta de tricina expresada como fracción molar se obtuvieron cerca de etanol a T = 313.15 K, mientras que los valores más bajos fueron encontrados en agua pura (2) a 293.15 K.The preferential solvation parameters of tricin in {ethanol (1) + water (2)} binary mixtures were obtained from their thermodynamic properties by means of the inverse Kirkwood-Buff integrals method. Tricin is very sensitive to specific solvation effects, so the preferential solvation parameter by ethanol (1), x1,3, is negative in the water-rich mixtures but positive in all the other compositions at temperatures from 293.15, to 313.15 K. It is conjecturable that in water-rich mixtures the hydrophobic hydration around the aromatic and methyl groups of the drug plays a relevant role in the solvation. The higher drug solvation by ethanol in mixtures of similar solvent proportions and in ethanol-rich mixtures could be due mainly to polarity effects. In these mixtures, the drug would be acting as Lewis acid with the ethanol molecules because this co-solvent is more basic than water.juan.sandovalc@campusucc.edu.coUniversidad Cooperativa de Colombia, Facultad de Ingenierías, Ingeniería Industrial, NeivaIngeniería IndustrialNeivaEthanolSolvatación preferencialTricinaEthanolPreferential solvationTricinPreferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperaturesTrabajo de grado - Pregradohttp://purl.org/coar/resource_type/c_7a1finfo:eu-repo/semantics/bachelorThesisinfo:eu-repo/semantics/acceptedVersionAtribucióninfo:eu-repo/semantics/openAccesshttp://purl.org/coar/access_right/c_abf2H. Cai, M. Al-Fayez, R.G. Tunstall, S. Platton, P. Greaves, W.P. Steward, A.J. Gescher, The rice bran constituent tricin potently inhibits cyclooxygenase enzymes and interferes with intestinal carcinogenesis in ApcMin mice, Mol. Cancer Ther., 4, 1287-1292 (2005).T. Oyama, Y. Yasui, S. Sugie, M. Koketsu, K. Watanabe, T. Tanaka, Dietary tricin suppresses inflammation-related colon carcinogenesis in male Crj: CD-1 mice, Cancer Prev. Res., 2, 1031-1038 (2009).M. Li, Y. Pu, C.G. Yoo, A.J. Ragauskas, The occurrence of tricin and its deriva- tives in plants, Green Chem., 18, 1439-1454 (2016).V.A. Moscatelli, Química y farmacología de una planta medicinal argentina: Artemisia copa, Dominguezia, 31, 5-13 (2015).A. Moheb, M. Grondin, R.K. Ibrahim, R. Roy, F. Sarhan, Winter wheat hull (husk) is a valuable source for tricin, a potential selective cytotoxic agent, Food Chem., 138, 931-973 (2013).W. Lan, J. Rencoret, F. Lu, S.D. Karlen, B.G. Smith, P.J. Harris, J.C. del Rio, J. Ralph, Tricin-lignins: Occurrence and quantitation of tricin in relation to phy- logeny, Plant J., 88, 1046-1057 (2016).A. Jouyban, W.E. Acree, Mathematical derivation of the Jouyban-Acree model to represent solute solubility data in mixed solvents at various temperatures, J. Mol. Liq., 256, 541-547 (2018).N.A. Bowden, D. Méndez-Sevillano, J.P.M. Sanders, M.E. Bruins, Modelling the effects of ethanol on the solubility of the proteinogenic amino acids with the NRTL, Gude and Jouyban-Acree models, Fluid Phase Equilib., 459, 158-169 (2018).M.A. Kalam, A.A. Khan, A. Alshamsan, A. Haque, F. Shakeel; Solubility of a poorly soluble immunosuppressant in different pure solvents: Measurement, cor- relation, thermodynamics and molecular interactions, J. Mol. Liq., 249, 53-60 (2018).E. Rahimpour, M. Barzegar-Jalali, A. Shayanfar, A. Jouyban, Generally trained models to predict drug solubility in N-methyl-2-pyrrolidone + water mixtures at various temperatures, J. Mol. Liq., 254, 34-38 (2018).A. Fathi-Azarbayjani, M.A. Jalil-Vaez-Gharamaleki, A. Jouyban, Measurement and correlation of deferiprone solubility: Investigation of solubility parameter and application of van’t Hoff equation and Jouyban–Acree model, J. Mol. Liq.,215, 339-344 (2016).M.A. Ruidiaz, D.R. Delgado, C.P. Mora, A. Yurquina, F. Martínez, Estimation of the indomethacin solubility in ethanol + water mixtures by the extended Hildebrand solubility approach, Rev. Colomb. Cienc. Quím. Farm., 39, 79-95 (2010).Y. Cheng, Z. Wang, S. Ding, J. Li, Determination and correlation of the solubility of tricin in water and ethanol mixtures, J. Chem. Thermodyn., 89, 89-92 (2015).G. Chen, J. Chen, C. Cheng, Y. Cong, C. Du, H. Zhao, Solubility and pref- erential solvation of econazole nitrate in binary solvent mixtures of methanol, ethanol and 1,4-dioxane in water, J. Chem. Thermodyn., 111, 228-237 (2017).J. Chen, G. Chen, Y. Cong, C. Du, H. Zhao, Solubility modelling and prefer- ential solvation of paclobutrazol in co-solvent mixtures of (ethanol, n-propanol and 1,4-dioxane) + water, J. Chem. Thermodyn., 112, 249-258 (2017).A. Jouyban, W.E. Acree Jr., F. Martínez, Modeling the solubility and prefer- ential solvation of gallic acid in cosolvent + water mixtures, J. Mol. Liq., 224, 502-506 (2016).Y. Marcus, “Solvent Mixtures: Properties and Selective Solvation”, Marcel Dekker, Inc., New York, 2002.Y. Marcus, Preferential solvation of ibuprofen and naproxen in aqueous 1,2-pro- panediol, Acta Chim. Slov., 56, 40-44 (2009).Y. Marcus, On the preferential solvation of drugs and PAHs in binary solvent mixtures, J. Mol. Liq., 140, 61-67 (2008).D.I. Caviedes Rubio, R.G. Sotomayor, D.R. Delgado, Solvatación preferencial de la naringina en mezclas cosolventes etanol + agua mediante el método de las integrales inversas de Kirkwood-Buff, Rev. Colomb. Cienc. Quím. Farm., 44, 220- 235 (2015).D.R. Delgado, E.F. Vargas, F. Martínez, Preferential solvation of xylitol in etha- nol + water solvent mixtures according to the IKBI and QLQC methods, Rev. Colomb. Quím., 42, 59-66 (2013).D.R. Delgado, F. Martínez. Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib., 379,128-138 (2015).D.R. Delgado, M.A. Peña, F. Martínez, Preferential solvation of some sulfon- amides in propylene glycol + water solvent mixtures according to the IKBI and QLQC methods, J. Solution Chem., 43, 360-374 (2014).D.R. Delgado, M.Á. Peña, F. Martínez, Preferential solvation of acetaminophen in ethanol + water solvent mixtures according to the inverse Kirkwood-Buff inte- grals method, Rev. Colomb. Cienc. Quím. Farm., 42, 298-314 (2013).A.C. Gaviria-Castillo, J.D. Artunduaga-Tole, J.D. Rodríguez-Rubiano, J.A. Zúñiga-Andrade, D.R. Delgado, A. Jouyban, F. Martínez, Solution thermo- dynamics and preferential solvation of triclocarban in {1, 4-dioxane (1) + water (2)} mixtures at 298.15 K, Phys. Chem. Liq., Forthcoming 2018, doi: 10.1080/00319104.2017.1416613.J.A. Lasso, D.I. Caviedes, D.R. Delgado, Preferential solvation of 4-hydroxy- 2,5-dimethyl-3(2H)-furanone (DMHF) in ethanol + water mixtures according to IKBI and QLQC methods, Ingeniería y Región, 13, 139-147 (2015).A. Jouyban, S. Nozohouri, F. Martínez, Solubility of celecoxib in {2-propanol (1) + water (2)} mixtures at various temperatures: Experimental data and ther- modynamic analysis J. Mol. Liq., 254, 1-7 (2018).A.F.M. Barton, “Handbook of Solubility parameters and Other CohesionParameter”, 2nd edition, CRC Press, Inc., New York, 1991.R.F. Fedors, A method for estimating both the solubility parameters and molar volumes of liquids, Polym. Eng. Sci., 14, 147-154 (1974).D.M. Jimenez, Z.J. Cárdenas, D.R. Delgado, M.Á. Peña, F. Martínez, Solubility temperature dependence and preferential solvation of sulfadiazine in 1,4-diox- ane + water co-solvent mixtures, Fluid Phase Equilib., 397, 26-36 (2015).D.R. Delgado, A.R. Holguín, O.A. Almanza, F. Martínez, Y. Marcus, Solubility and preferential solvation of meloxicam in ethanol + water mixtures, Fluid Phase Equilib., 305, 88-95 (2011).D.R. Delgado, F. Martínez, Solubility and preferential solvation of sulfadiazine in methanol + water mixtures at several temperatures, Fluid Phase Equilib., 379, 128-138 (2014).D.R. Delgado, F. Martínez, Solubility and solution thermodynamics of sulfa- merazine and sulfamethazine in some ethanol + water mixtures, Fluid Phase Equilib., 360, 88-96 (2013).E.A. Ahumada, D.R. Delgado, F. Martínez. Solution thermodynamics of acet- aminophen in some PEG 400 + water mixtures, Fluid Phase Equilib., 332, 120- 127 (2012).D.R. Delgado, F. Martínez. Solution thermodynamics of sulfadiazine in some ethanol + water mixtures, J. Mol. Liq., 187, 99-105 (2013).D.R. Delgado, F. Martínez. Solubility and solution thermodynamics of some sul- fonamides in 1-propanol + water mixtures, J. Solution Chem., 43, 836-852 (2014).E.A. Cantillo, D.R. Delgado, F. Martínez, Solution thermodynamics of indo- methacin in ethanol + propylene glycol mixtures, J. Mol. Liq., 181, 62-67 (2013).D.R. Delgado, F. Martínez, Preferential solvation of sulfadiazine, sulfamerazine and sulfamethazine in ethanol + water solvent mixtures according to the IKBI method, J. Mol. Liq., 193, 152-159 (2014).D.M. Jiménez, Z.J. Cárdenas, D.R. Delgado, F. Martínez, A. Jouyban, Preferen- tial solvation of methocarbamol in aqueous binary cosolvent mixtures at 298.15 K, Phys. Chem. Liq., 52, 726-737 (2014).J. Jiménez, J. Manrique, F. Martínez, Effect of temperature on some volumetric properties for ethanol+ water mixtures, Rev. Colomb. Cienc. Quím. Farm., 33, 145-155 (2004).M.J. Kamlet, R.W. Taft, The solvatochromic comparison method. I. The beta- scale of solvent hydrogen-bond acceptor (HBA) basicities, J. Am. Chem. Soc., 98, 377-383 (1976).R.W. Taft, M.J. Kamlet, The solvatochromic comparison method. II. The alpha- scale of solvent hydrogen-bond donor (hba) acidities, J. Am. Chem. Soc., 98, 2886-2894 (1976).F. Martínez, A. Jouyban, W.E. Acree Jr., Further numerical analysis on the solu- bility of ibrutinib in ethanol + water mixtures at different temperatures, J. Mol. Liq., 218, 35-38 (2016).A. Jouyban, F. Martínez, W.E. Acree Jr., Comments on “Solubility and solution thermodynamics of 2,3,4,5-tetrabromothiophene in (ethanol + trichlorometh- ane) binary solvent mixtures”, Fluid Phase Equilib., 421, 88-92 (2016).PublicationORIGINAL2018_preferential_solvation_tricin.pdf2018_preferential_solvation_tricin.pdfTrabajo de gradoapplication/pdf831178https://repository.ucc.edu.co/bitstreams/e597e40b-bf14-48e5-b2a2-55881bb47922/downloada8a086806b99d5cd91c58aae109fbfadMD532018_preferential_solvation_tricin_formatolicenciauso.pdf2018_preferential_solvation_tricin_formatolicenciauso.pdfLicencia de usoapplication/pdf234210https://repository.ucc.edu.co/bitstreams/f0163b87-24d9-4c65-9382-c8dc56d9afba/download08c7ee415d4bd4619585eea40d46923aMD54LICENSElicense.txtlicense.txttext/plain; charset=utf-84334https://repository.ucc.edu.co/bitstreams/052225f4-49be-407d-88b1-437bebdfd312/download3bce4f7ab09dfc588f126e1e36e98a45MD55TEXT2018_preferential_solvation_tricin.pdf.txt2018_preferential_solvation_tricin.pdf.txtExtracted 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Preferential solvation of tricin in {ethanol (1) + water (2)} mixtures at several temperatures

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